화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2003년 가을 (10/10 ~ 10/11, 부경대학교)
권호 28권 2호, p.209
발표분야 고분자 합성
제목 Synthesis of Dibenzofulvene(DBF) and its Anionic Copolymerization
초록 It has been well-known that 1,1-diphenylethylene(DPE) is a representative vinyl compound that does not produce homopolymer by organolithium-initated polymerization. Dibenzofulvene(DBF) exhibiting analogous structure to that of DPE may be polymerized by organolithium as the anionic initiator. The resulting polymer will show an electroluminescence property. Dibenzofulvene(DBF) was synthesized from 9-hydroxymethylfluorene by following the reaction procedures described in the literature. The well defined poly(DBF) and copolymer consisting of DBF and styrene were synthesized by anionic polymerization. In this presentation, we will discuss the results for the synthesis of poly(DBF) and poly(styrene-co-DBF) synthesized by organolithium-initiated polymerization.
저자 이선배1, 박준형1, 최규진1, 김지희1, 김광웅1, 김정안1, 홍순만1, 곽순종1, 진정일2
소속 1한국과학기술(연), 2고려대
키워드 dibenzofulvene; DBF; anionic polymerization
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