| 학회 | 한국공업화학회 |
| 학술대회 | 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 | 20권 2호 |
| 발표분야 | 정밀화학_포스터 |
| 제목 | Modification of basic dyes with weakly coordinating bulky anions for improving their solubilities in organic solvents without color change |
| 초록 | Basic dyes are popularly used commercial dyes due to their advantage in optical property and price. Basic dyes show superior solubilities in water, but, they are rarely dissolved in organic solvents due to their ionic characteristics. To overcome this problem of basic dyes, we designed basic dyes with weakly coordinating anions (WCAs) that have no effect on the spectral properties of the dyes. Unmodified basic dyes generally show superior solubilities in polar protic solvents. However, the dyes with WCAs showed improved solubilities in polar aprotic solvents and non-polar solvents. The zeta potentials and XRD patterns were also measured to analyze the change of their molecular characteristics by the introduction of WCAs. The modification by WCAs had no effects on the optical performances of the dyes and the color filters. Namely, by the introduction of the WCAs, it is possible to increase the solubilities of basic dyes in organic solvents without any discoloration to them. |
| 저자 | 우성윤, 김재필, 김정윤 |
| 소속 | 서울대 |
| 키워드 | Weakly Coordinating Anions(WCA); dye; solubility |
