Determination of trace level carbonate ion in Mg-Al layered double hydroxide: Its significance on the anion exchange behaviour

Jui Chakraborty; Somoshree Sengupta; Sudip Dasgupta; Manjusha Chakraborty; Swapankumar Ghosh; Sudipta Mallik; Kamal Lal Das; Debabrata Basu

Journal of Industrial and Engineering Chemistry, Vol.18, No.6, 2211-2216, November, 2012

DOI10.1016/j.jiec.2012.06.020 Export Citation

Determination of trace level carbonate ion in Mg-Al layered double hydroxide: Its significance on the anion exchange behaviour

Jui Chakraborty^†, Somoshree Sengupta, Sudip Dasgupta¹, Manjusha Chakraborty, Swapankumar Ghosh^{2, †}, Sudipta Mallik³, Kamal Lal Das, and Debabrata Basu

Central Glass & Ceramic Research Institute, CSIR, 196 Raja S.C. Mullick Road, Kolkata 700 032, India
¹National Institute of Technology, Rourkela 769 008, Orissa, India
²National Institute for Interdisciplinary Science & Technology, CSIR, Trivandrum 695 019, India
³Metrohm India Ltd., P-224, C.I.T. Road, Scheme-VII (M), Kolkata 700 054, India

E-mail:,

The presence of trace level (<1 ppm) carbonate ion in the interlayer space of MgAl-LDH has been estimated by ion chromatography technique using a novel inverse chemical suppression method using 0.5 mM H2SO4 as mobile phase and 25 mM LiCl as regenerating solution. The presence of carbonate ion in the LDH structure was found to affect the anion exchange capacity of MgAl-LDH. This has been illustrated by carrying out anion exchange of nitrate ion in the MgAl-LDH structure with chloride ion. The importance of this simple but accurate technique for the carbonate ion estimation is demonstrated and reported in this communication.

Keywords:Layered double hydroxides;Anionic clay;Anion exchange;Intercalation;Carbonate estimation;Ion chromatography

[References]

Chakraborty M, Dasgupta S, Soundrapandian C, Chakraborty J, Ghosh S, Mitra MK, Basu D, Journal of Solid State Chemistry., 184, 2439 (2011)
Kakiuchi N, Nishimura T, Inoue M, Uemura S, Bulletin of the Chemical Society of Japan., 74, 165 (2001)
Friedrich HB, Govender M, Makhoba X, Ngcobo TD, Onani MO, Chemical Communications., 2922 (2003)
Li BX, He J, Evans DG, Duan X, Applied Clay Science., 27, 199 (2004)
Xu ZP, Niebert M, Porazik K, Walker TL, Cooper HM, Middelberg APJ, Gray PP, Bartlett PF, Lu GQ, Journal of Controlled Release., 130, 86 (2008)
Miyata S, Clays and Clay Minerals., 31, 305 (1983)
Meyn M, Beneke K, Lagaly G, Inorganic Chemistry., 29, 5201 (1990)
Velu S, Ramkumar V, Narayanan A, Swamy CS, J. Mater. Sci., 32(4), 957 (1997)
Bergaya F, Theng BKG, Lagally G, Handbook of Clay Science, Elsevier, Amsterdam (2006)
Kloprogge JT, Wharton D, Hickey L, Frost RL, AmericanMineralogist., 87, 623 (2002)
Parker LM, Milestone NB, Newman RH, Ind. Eng. Chem. Res., 34(4), 1196 (1995)
Wu HY, Jiao QZ, Zhao Y, Huang SL, Li XF, Liu HB, Zhou MJ, Materials Characterization., 61, 227 (2010)
Zhang H, Zhang FZ, Ren LL, Evans DG, Duan X, Mater. Chem. Phys., 85(1), 207 (2004)
Sharma U, Tyagi B, Jasra RV, Ind. Eng. Chem. Res., 47(23), 9588 (2008)
Weiss J, Ionenchromatographie, second ed., Auflage, Verlag Chemie, Weinheim (1991)
Haddad PR, Jackson PE, Ion Chromatography . Principles and Applications, first ed., Elsevier Verlag, Amsterdam (1990)
Eith C, Kolb M, Rumi A, Seubert A, Practical Ion Chromatography: An Introduction, second ed., Metrohm Ltd., Switzerland (2007)
Alsudani HML, Al-Bayati RI, Barbooti MM, African Journal of Pure and Applied Chemistry., 3, 165 (2009)
Carlson A, Kowalski V, Concordia College Journal of Analytical Chemistry., 1, 9 (2010)
Mermet JM, Otto M, Widmer HM, Analytical Chemistry, first ed., Wiley-VCH, Weinheim, New York (1994)
Zhang H, Guo SH, Zou K, Duan X, Mater. Res. Bull., 44(5), 1062 (2009)
Palmer SJ, Nguyen T, Frost RL, Journal of Raman Specroscopy., 38, 1602 (2007)
Chai H, Lin YJ, Evans DG, Li DQ, Ind. Eng. Chem. Res., 47(9), 2855 (2008)
Xia SJ, Ni ZM, Xu Q, Hu BX, Hu J, Journal of Solid State Chemistry., 181, 2610 (2008)
Li F, Zhang FH, Evans DG, Forano C, Duan X, Thermochim. Acta, 424(1-2), 15 (2004)

[Referenced By]

[1] Chakraborty M, Dasgupta S, Soundrapandian C, Chakraborty J, Ghosh S, Mitra MK, Basu D, Journal of Solid State Chemistry., 184, 2439 (2011)

[2] Kakiuchi N, Nishimura T, Inoue M, Uemura S, Bulletin of the Chemical Society of Japan., 74, 165 (2001)

[3] Friedrich HB, Govender M, Makhoba X, Ngcobo TD, Onani MO, Chemical Communications., 2922 (2003)

[4] Li BX, He J, Evans DG, Duan X, Applied Clay Science., 27, 199 (2004)

[5] Xu ZP, Niebert M, Porazik K, Walker TL, Cooper HM, Middelberg APJ, Gray PP, Bartlett PF, Lu GQ, Journal of Controlled Release., 130, 86 (2008)

[6] Miyata S, Clays and Clay Minerals., 31, 305 (1983)

[7] Meyn M, Beneke K, Lagaly G, Inorganic Chemistry., 29, 5201 (1990)

[8] Velu S, Ramkumar V, Narayanan A, Swamy CS, J. Mater. Sci., 32(4), 957 (1997)

[9] Bergaya F, Theng BKG, Lagally G, Handbook of Clay Science, Elsevier, Amsterdam (2006)

[10] Kloprogge JT, Wharton D, Hickey L, Frost RL, AmericanMineralogist., 87, 623 (2002)

[11] Parker LM, Milestone NB, Newman RH, Ind. Eng. Chem. Res., 34(4), 1196 (1995)

[12] Wu HY, Jiao QZ, Zhao Y, Huang SL, Li XF, Liu HB, Zhou MJ, Materials Characterization., 61, 227 (2010)

[13] Zhang H, Zhang FZ, Ren LL, Evans DG, Duan X, Mater. Chem. Phys., 85(1), 207 (2004)

[14] Sharma U, Tyagi B, Jasra RV, Ind. Eng. Chem. Res., 47(23), 9588 (2008)

[15] Weiss J, Ionenchromatographie, second ed., Auflage, Verlag Chemie, Weinheim (1991)

[16] Haddad PR, Jackson PE, Ion Chromatography . Principles and Applications, first ed., Elsevier Verlag, Amsterdam (1990)

[17] Eith C, Kolb M, Rumi A, Seubert A, Practical Ion Chromatography: An Introduction, second ed., Metrohm Ltd., Switzerland (2007)

[18] Alsudani HML, Al-Bayati RI, Barbooti MM, African Journal of Pure and Applied Chemistry., 3, 165 (2009)

[19] Carlson A, Kowalski V, Concordia College Journal of Analytical Chemistry., 1, 9 (2010)

[20] Mermet JM, Otto M, Widmer HM, Analytical Chemistry, first ed., Wiley-VCH, Weinheim, New York (1994)

[21] Zhang H, Guo SH, Zou K, Duan X, Mater. Res. Bull., 44(5), 1062 (2009)

[22] Palmer SJ, Nguyen T, Frost RL, Journal of Raman Specroscopy., 38, 1602 (2007)

[23] Chai H, Lin YJ, Evans DG, Li DQ, Ind. Eng. Chem. Res., 47(9), 2855 (2008)

[24] Xia SJ, Ni ZM, Xu Q, Hu BX, Hu J, Journal of Solid State Chemistry., 181, 2610 (2008)

[25] Li F, Zhang FH, Evans DG, Forano C, Duan X, Thermochim. Acta, 424(1-2), 15 (2004)