Korean Journal of Chemical Engineering, Vol.30, No.8, 1631-1635, August, 2013
Regeneration dynamics of potassium-based sediment sorbents for CO2 capture
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Simulating regeneration tests of Potassium-Based sorbents that supported by Suzhou River Channel Sediment were carried out in order to obtain parameters of regeneration reaction. Potassium-based sediment sorbents have a better morphology with the surface area of 156.73 m2·g^(-1), the pore volume of 357.5×10^(-3) cm3·g^(-1) and the distribution of pore diameters about 2-20 nm. As a comparison, those of hexagonal potassium-based sorbents are only 2.83 m2g^(-1), 7.45×10^(-3)cm3g^(-1) and 1.72-5.4 nm, respectively. TGA analysis shows that the optimum final temperature of regeneration is 200 and the optimum loading is about 40%, with the best heating rate of 10 ℃·min^(-1). By the modified Coats-Redfern integral method, the activation energy of 40% KHCO3 sorbents is 102.43 kJ·mol^(-1). The results obtained can be used as basic data for designing and operating CO2 capture process.
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