Cryptand 21 합성수지를 이용한 금속 이온의 흡착 및 분리에 관한 연구

박성규; 김준태

Journal of the Korean Industrial and Engineering Chemistry, Vol.6, No.6, 1004-1011, December, 1995

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Cryptand 21 합성수지를 이용한 금속 이온의 흡착 및 분리에 관한 연구

A Study on the Adsorption and Separation of Metal Ions Utilizing Cryptand 21 Synthetic Resin

박성규, 김준태

초록

1%, 2%, 및 20% 다리결합도의 를로로메틸화된 1,4-디비닐벤젠에 cryptand 21 거대고리 리간드를 치환반응으로 결합시키고, 이들 수지로부터 흡착에 미치는 pH, 수지의 다리결합도 그리고 금속 이온 농도의 영향에 대하여 조사하였다. 금속 이온들은 pH 3 이하에서는 잘 흡작되지 않았으나 pH 4 이상에서는 큰 흡착률을 보였으며 금속 이온들의 흡착 평균시간은 약 2시간 이었다. 한편, 에탄을 매질에거의 흡착선택성은 UO₂₊ > Ni₂₊ > Ce₃₊이었으며 1% 다리결합도의 수지를 충진시킨 컬럼에 흡착시킨 후 용리액으로 pH 2.5 HNO₃을 사용하여 개별 분리가 가능하였다.

Resins with cryptand 21 macrocyclic ligand attached to chloromethylated styrene-1,4-divinylbenzene by substitution reaction were prepared and the effect of pH, metal concentration and cross-linkage of the matrix on the adsorption for UO₂²⁺ , Ni²⁺ and Ce³⁺ was investigated. The metal ion was not adsorbed on the resins pH range below 3 and above pH 4, fast adsorption behavior was showed. The resin selectivity determined in ethanol matrix was in increasing order UO₂²⁺ > Ni²⁺ >Ce³⁺. In addition, these metal ion could be separated on the column packed with 1% crosslinked resin by pH 2.5 HNO₃ as an eluent.

[References]

Pederson CJ, J. Am. Chem. Soc., 89, 7017 (1967)
Amstrong LG, Lindoy LF, Inorg. Chem., 14, 1322 (1975)
Glimsley PG, Lindoy LF, Hanith CL, Smith RJ, Baker J, Aust. J. Chem., 30, 2095 (1977)
Bender LM, Komyama M, Cyclodextrin Chemistry, Springer-Verlag (1979)
Edmund M, Choy D, Evans F, Cussler EI, J. Am. Chem. Soc., 96, 7085 (1974)
Gram DJ, Gram JM, Science, 183, 803 (1974)
Christensen JJ, Hill JO, Izatt RM, Science, 174, 459 (1971)
Pedersen CJ, Frensdroff HK, Angrew. Chem., 74, 16 (1972)
Frensdorff HK, J. Am. Chem. Soc., 93, 4684 (1971)
Sadakane A, Iwachido T, Toei K, Bull. Chem. Soc. Jpn., 48, 60 (1975)
Mitchell JW, Shanks L, Anal. Chem., 47, 642 (1975)
Hiraoka M, "Studies in Organic Chemistry 12, Crown Compounds, Their Characteristics and Applications," Elsevier Scientific Pub. Amsterdam (1982)
Jepson BE, Dewitt RJ, Inorg. Nucl. Chem., 38, 1175 (1976)
Sousa LR, Marson JM, J. Am. Chem. Soc., 99, 307 (1977)
Szczepaniak W, Juskowiak B, Anal. Chim. Acta, 140, 261 (1982)
King RB, Huckley PR, J. Am. Chem. Soc., 96, 3118 (1973)
Igawa M, Saito K, Tsukamoto J, Tanaka M, Anal. Chem., 53, 1942 (1981)
Arnaud-Neu F, Spies B, Schwing-Weill MJ, Helv. Chim. Acta, 60, 2633 (1977)
Luboch E, Cygan A, Biernat JF, Inorg. Chim. Acta, 68, 201 (1983)
Almasio MC, Arnaud-Neu F, Schwing-Weill MJ, Helv. Chim. Acta, 66, 1296 (1983)
Brugman WJ, Kraak JC, J. Chromatogr. A, 205, 170 (1981)
Kimura T, Ishimoral T, Hamada T, Anal. Chem., 54, 1129 (1982)
Delphin WH, Horwitz EP, Anal. Chem., 50, 843 (1978)
Blasius E, Janzen KP, Keller M, Lander H, Nguyen T, Scholten G, Talanta, 27, 107 (1980)
Blasius E, Janzen KP, Adrian W, Klein W, Luxenburger HK, Mernke E, Nguyen VB, Nguyen T, Rausch R, Stockemer J, Toussaint A, Talanta, 27, 127 (1980)
Tabushi I, Kato H, Kuroda H, Preprints of 26th Annual Meeting of Society of Polymer Science, Japan, 257 (1977)
Tabushi I, Kato H, Kuroda H, Taniguchi Y, J. Chem. Soc., 26 (1977)
Igawa M, Ito I, Tanaka M, Bunseki K, 29, 580 (1980)
Blasius E, Adrian W, Janzen KP, Klautke G, J. Chromatogr., 96, 89 (1974)
Blasius E, Janzen KP, Pure Appl. Chem., 54, 2115 (1982)
Morse LD, Grundner WT, Calmon C, U.S. Patent, 3,627,708 (1971)
Lindoy LF, Inorg. Chem., 19, 3360 (1980)
Adam KR, J. Am. Chem. Soc., 105, 4645 (1983)

[Referenced By]

[1] Pederson CJ, J. Am. Chem. Soc., 89, 7017 (1967)

[2] Amstrong LG, Lindoy LF, Inorg. Chem., 14, 1322 (1975)

[3] Glimsley PG, Lindoy LF, Hanith CL, Smith RJ, Baker J, Aust. J. Chem., 30, 2095 (1977)

[4] Bender LM, Komyama M, Cyclodextrin Chemistry, Springer-Verlag (1979)

[5] Edmund M, Choy D, Evans F, Cussler EI, J. Am. Chem. Soc., 96, 7085 (1974)

[6] Gram DJ, Gram JM, Science, 183, 803 (1974)

[7] Christensen JJ, Hill JO, Izatt RM, Science, 174, 459 (1971)

[8] Pedersen CJ, Frensdroff HK, Angrew. Chem., 74, 16 (1972)

[9] Frensdorff HK, J. Am. Chem. Soc., 93, 4684 (1971)

[10] Sadakane A, Iwachido T, Toei K, Bull. Chem. Soc. Jpn., 48, 60 (1975)

[11] Mitchell JW, Shanks L, Anal. Chem., 47, 642 (1975)

[12] Hiraoka M, "Studies in Organic Chemistry 12, Crown Compounds, Their Characteristics and Applications," Elsevier Scientific Pub. Amsterdam (1982)

[13] Jepson BE, Dewitt RJ, Inorg. Nucl. Chem., 38, 1175 (1976)

[14] Sousa LR, Marson JM, J. Am. Chem. Soc., 99, 307 (1977)

[15] Szczepaniak W, Juskowiak B, Anal. Chim. Acta, 140, 261 (1982)

[16] King RB, Huckley PR, J. Am. Chem. Soc., 96, 3118 (1973)

[17] Igawa M, Saito K, Tsukamoto J, Tanaka M, Anal. Chem., 53, 1942 (1981)

[18] Arnaud-Neu F, Spies B, Schwing-Weill MJ, Helv. Chim. Acta, 60, 2633 (1977)

[19] Luboch E, Cygan A, Biernat JF, Inorg. Chim. Acta, 68, 201 (1983)

[20] Almasio MC, Arnaud-Neu F, Schwing-Weill MJ, Helv. Chim. Acta, 66, 1296 (1983)

[21] Brugman WJ, Kraak JC, J. Chromatogr. A, 205, 170 (1981)

[22] Kimura T, Ishimoral T, Hamada T, Anal. Chem., 54, 1129 (1982)

[23] Delphin WH, Horwitz EP, Anal. Chem., 50, 843 (1978)

[24] Blasius E, Janzen KP, Keller M, Lander H, Nguyen T, Scholten G, Talanta, 27, 107 (1980)

[25] Blasius E, Janzen KP, Adrian W, Klein W, Luxenburger HK, Mernke E, Nguyen VB, Nguyen T, Rausch R, Stockemer J, Toussaint A, Talanta, 27, 127 (1980)

[26] Tabushi I, Kato H, Kuroda H, Preprints of 26th Annual Meeting of Society of Polymer Science, Japan, 257 (1977)

[27] Tabushi I, Kato H, Kuroda H, Taniguchi Y, J. Chem. Soc., 26 (1977)

[28] Igawa M, Ito I, Tanaka M, Bunseki K, 29, 580 (1980)

[29] Blasius E, Adrian W, Janzen KP, Klautke G, J. Chromatogr., 96, 89 (1974)

[30] Blasius E, Janzen KP, Pure Appl. Chem., 54, 2115 (1982)

[31] Morse LD, Grundner WT, Calmon C, U.S. Patent, 3,627,708 (1971)

[32] Lindoy LF, Inorg. Chem., 19, 3360 (1980)

[33] Adam KR, J. Am. Chem. Soc., 105, 4645 (1983)