양극산화와 열수처리한 니오비움 금속의 표면특성

원대회; 김영순; 윤동주; 이민호; 배태성; Dae-Hee Won; Young-Soon Kim; Dong-Joo Yoon; Min-Ho Lee; Tae-Sung Bae

Korean Journal of Materials Research, Vol.15, No.2, 134-138, February, 2005

DOI10.3740/MRSK.2005.15.2.134 Export Citation

양극산화와 열수처리한 니오비움 금속의 표면특성

Surface Characterization of Anodized and Hydrothermal Treated Niobium Metal

원대회, 김영순¹, 윤동주², 이민호 ³, 배태성 ^{3, †}

투엠 생체재료연구소
¹전북대학교 공과대학 화학공학과 박막실험실
²순천대학교 산학협력중심대학 육성사업단
³전북대학교 치과대학 치과생체재료학교실 및 구강생체과학연구소

Dae-Hee Won, Young-Soon Kim¹, Dong-Joo Yoon², Min-Ho Lee³, and Tae-Sung Bae^{3, †}

Biomaterials Institute 2M, Co., Chonbuk National University, Jeonju, Jeonbuk, 561-756, Korea
¹The Film Technology Lab, School of Chemical Engineering, Chonbuk National University, Jeonju, Jeongbuk, 561-756, Korea
²Fostering Project Corps of Industrial-Academic Cooperation Centered University, Sunchon National University, Sunchon, Jennam, 540-742, Korea
³Dept. of Dental Biomaterials and Institute of Oral Bioscience, School of Dentistry, Chonbuk National University, Jeonju, Jeongbuk, 561-756, Korea

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This study was performed to investigate the surface properties of electrochemically oxidized pure niobium by anodic oxide and hydrothermal treatment technique. Niobium specimens of 10mm×10mm×1.0mm in dimension were polished sequentially from #600,#800,#1000 emery paper. The surface of pure niobium sperimens was anodized in an electrolytic solution that was dissolved calcium and phosphate in water. The electrolytic voltage was set in the range of 250 V and the current density was 10mA/cm 2 . The specimen was hydrothermal treated in high-pressure steam at 300 ? C for 2 hours using an autoclave. And all specimens were immersed in the in the Hanks' solution nth pH 7.4 at 37 ? C for 30 days. The surface of specimen was characterized by surface roughness, scanning electron microscope(SEM), energy dispersion X-ray analysis(EDX), X-ray photoemission spectroscopy(XPS) test. The value of surface roughness was the highest in the anodized sample and 0.41±0.04μm . The results of the SEM observation show that oxide layers of the multi porosity in the anodized sample were piled up on another, and hydroxyapatite crystal was precipitate from the surface of the hydrothermal treated sample. In the XPS analysis, O, Nb, C peak and small amounts of N peak were found in the polished specimens while Ca and P peak in addition to O, Nb, C and peak were observed in the hydrothermal treated sample.

Keywords:anodized;hydrothermal treated;niobium;XPS

[References]

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Kodama T, J Stomatol Soc Jpn., 51, 263 (1989)
Semlitsch MF, Weber H, Streicher RM, Biomaterials., 13, 781 (1992)
Hamanaka H, Doi H, Kobayashi E, Nakano T, Yoneyama T, J Dent Mater, 17, 88 (1998)
Goodman SB, Davidson JA, Fomasier VL, Mishra AK, J Appl Biomater., 4, 331 (1993)
Wang BC, Lee TM, Chang E, Yang CY, J Biomed Mater Res., 27, 1315 (1993)
Hayashi K, lnadome T, Mashima T, Sugioka Y, J Biomed Mater Res., 27, 557 (1993)
Kokubo T, Mijaji F, Kim HM, Nakamura T, J. Am. Ceram. Soc., 79, 1127 (1996)
Yan WQ, Nakamura T, Kobayashi M, Kim HM, Mijaji F, J Biomed Mater Res., 37, 267 (1996)
Chung HW, Choi KH, Lee MH, Bae TS, J Korean Res Soc Dent Mater., 26, 269 (1999)
Hanawa T, Ukai H, Murakami K, J Electron Spectrosc., 63, 347 (1993)
Hanawa T, Ukai H, Murakami K, Asaoka K, Mater Trans JIM., 36, 438 (1995)
Ducheyne P, Van Raemdonck W, Heughebaert JC, Heughebaert M, Biomaterials., 7, 97 (1996)
Ban S, Maruno S, Biomaterials., 16, 977 (1995)
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Morimoto T, Naono H, Bull Chem Soc Jpn., 46, 2000 (1973)
Ishizawa H, Ogino M, J Biomed Mater Res., 29, 65 (1995)
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[Related Articles]

[1] Matsuno H, Yokoyma A, Miyao R, Sasoh F, Kawasaki T, Uo M, Ohkawa S, Sugawara T, Kondo S, Watari F, J.J.Dent. Mater, 18, 97 (1999)

[2] Kodama T, J Stomatol Soc Jpn., 51, 263 (1989)

[3] Semlitsch MF, Weber H, Streicher RM, Biomaterials., 13, 781 (1992)

[4] Hamanaka H, Doi H, Kobayashi E, Nakano T, Yoneyama T, J Dent Mater, 17, 88 (1998)

[5] Goodman SB, Davidson JA, Fomasier VL, Mishra AK, J Appl Biomater., 4, 331 (1993)

[6] Wang BC, Lee TM, Chang E, Yang CY, J Biomed Mater Res., 27, 1315 (1993)

[7] Hayashi K, lnadome T, Mashima T, Sugioka Y, J Biomed Mater Res., 27, 557 (1993)

[8] Kokubo T, Mijaji F, Kim HM, Nakamura T, J. Am. Ceram. Soc., 79, 1127 (1996)

[9] Yan WQ, Nakamura T, Kobayashi M, Kim HM, Mijaji F, J Biomed Mater Res., 37, 267 (1996)

[10] Chung HW, Choi KH, Lee MH, Bae TS, J Korean Res Soc Dent Mater., 26, 269 (1999)

[11] Hanawa T, Ukai H, Murakami K, J Electron Spectrosc., 63, 347 (1993)

[12] Hanawa T, Ukai H, Murakami K, Asaoka K, Mater Trans JIM., 36, 438 (1995)

[13] Ducheyne P, Van Raemdonck W, Heughebaert JC, Heughebaert M, Biomaterials., 7, 97 (1996)

[14] Ban S, Maruno S, Biomaterials., 16, 977 (1995)

[15] Walivaara B, Lundstrom I, Tengvall P, Clin Mater., 12, 141 (1993)

[16] Pan J, Thierry D, Leygraf C, J Biomed Mater Res., 30, 393 (1996)

[17] Tengvall P, Elwing H, Sjoqvist L, Lundstrom I, Bjursten LM, Biomaterials., 10, 118 (1989)

[18] Lee BH, Kim YD, Lee KH, Biomaterials., 24, 2257 (2003)

[19] Sodhi RNS, Weninger A, Davies JE, Sreenivas K, J. Vac. Sci. Technol. A, 9, 1329 (1991)

[20] Hazan R, Brener R, Oron U, Biomaterials., 14, 570 (1993)

[21] Kilpadi DV, Lemons JE, Liu J, Raikar GN, Weimer JJ, Vohra Y, Int J Oral Maxillofac Implants., 15, 219 (2000)

[22] Pypen CMJM, Jr Plenk H, Ebel MF, Svager R, Wernish J, J Mater Sci Mater Med., 8, 781 (1996)

[23] Keller JC, Stanford CM, Winghtman JP, Draughn RA, Zaharias R, J Biomed Mater Res., 28, 939 (1994)

[24] Buser D, Nydegger T, Oxaland T, J Biomed Mater Res., 45, 75 (1999)

[25] Kurze P, Krysmann W, Schneider HG, Cryst Res Technol., 21, 1630 (1986)

[26] Morimoto T, Naono H, Bull Chem Soc Jpn., 46, 2000 (1973)

[27] Ishizawa H, Ogino M, J Biomed Mater Res., 29, 65 (1995)

[28] Choi WH, Lee YS, Kim DH, Kwon YH, Bae TS, J Korean Res Soc Dent Mater., 30, 47 (2003)

[29] Olsson COA, Landolt D, Corro Sci., 46, 213 (2004)

[30] Wagner CD, Naumkim AV, Kraut-Vass A, Allison JW, Powell CJ, Jr. Rumble JR, NIST standard reference database, 20 (2000)