Adsorption of industrial dyes by semi-IPN hydrogels of Acrylic copolymers and sodium alginate

Ruma Bhattacharyya; Samit Kumar Ray

Journal of Industrial and Engineering Chemistry, Vol.22, 92-102, February, 2015

DOI10.1016/j.jiec.2014.06.029 Export Citation

Adsorption of industrial dyes by semi-IPN hydrogels of Acrylic copolymers and sodium alginate

Ruma Bhattacharyya, and Samit Kumar Ray^†

Department of Polymer Science and Technology, University of Calcutta, 92, A.P.C Road, Kolkata-700009, India

E-mail:

Several hydrogels were synthesized from sodium alginate and copolymer of acrylic acid and acrylamide. These hydrogels were characterized by FTIR, XRD, DTA-TGA, swelling and diffusion characteristics. The hydrogel showing the best result for swelling was used for adsorption of Basic fuschin (BF) and Methyl violet (MV) dyes. The hydrogel showed high adsorption and removal% for these dyes for both low (2.5–25 mg/L) and high range (100–600 mg/L) of feed concentration. The dye adsorption data were fitted to different kinetics and adsorption isotherm models. The external mass transfer coefficient, diffusion coefficient and thermodynamic parameters of dye adsorption were also determined.

Keywords:Hydrogel;Synthesis;Swelling;Dye adsorption;Kinetics;Adsorption isotherms

[References]

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[Referenced By]

[1] Chang C, Duan B, Zhang JLC, Eur. Polym. J., 46, 92 (2010)

[2] Peppas NA, Hilt JZ, Khademhosseini A, Langer R, Adv. Mater., 18(11), 1345 (2006)

[3] Mandal B, Ray SK, Carbohydr. Polym., 98, 257 (2013)

[4] Hua SB, Wang AQ, Carbohydr. Polym., 75, 79 (2009)

[5] Lezehar M, Baslya JP, Baudua M, Boura O, Colloids Surf. A: Physicochem. Eng. Asp., 366, 88 (2010)

[6] Liu L, Wan YZ, Xie YD, Zhai R, Zhang B, Liu JD, Chem. Eng. J., 187, 210 (2012)

[7] Mahmoodi NM, Hayati B, Arami M, Bahrami H, Desalination, 275(1-3), 93 (2011)

[8] Isıklan N, Kursun F, Inal M, Carbohydr. Polym., 79, 665 (2010)

[9] Sæther HV, Holme HK, Maurstad G, Smidsrod O, Stokke BT, Carbohydr. Polym., 74, 813 (2008)

[10] Sperling LH, Plenum, New York, 1981.

[11] Rao KSVK, Naidu BVK, Subha MCS, Sairam M, Aminabhavi TM, Carbohydr. Polym., 66, 333 (2006)

[12] Wen C, Lu L, Li X, Macromol. Mater. Eng., 299, 504 (2014)

[13] Pescosolido L, Vermonden T, Malda J, Censi R, Dhert WJ, Alhaique F, Hennink WE, Matricardi, P, Acta Biomater, 7(4), 1627 (2011)

[14] Li ZQ, Shen JF, Ma HW, Lu X, Shi M, Li N, Ye MX, Polym. Bull., 68(4), 1153 (2012)

[15] Kulkarni RV, Sreedhara V, Mutalikb S, Setty CM, Sa B, Int. J. Biol. Macromol., 47, 520 (2010)

[16] Wang W, Wang A, Carbohydr. Polym., 80, 1028 (2010)

[17] Horia M, Nizam ED, Manal F, Abou T, Wahab A, El-Naggar M, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 266, 2607 (2008)

[18] Solpan D, Torun M, Guven G, J. Appl. Polym. Sci., 108(6), 3787 (2008)

[19] Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2 (2010)

[20] Hua S, Mac H, Xun LC, Yanga HB, Wanga A, Int. J. Biol. Macromol., 46, 517 (2010)

[21] Mandal S, Basu SK, Sa B, Carbohydr. Polym., 82, 867 (2010)

[22] Dong YC, Dong WJ, Cao YN, Han ZB, Ding ZZ, Catal. Today, 175(1), 346 (2011)

[23] Biswal DR, Singh RP, Carbohydr. Polym., 57, 379 (2004)

[24] Fang D, Liu Y, Jiang S, Nie J, Ma G, Carbohydr. Polym., 85, 276 (2011)

[25] Pongjanyakul T, Priprem A, Atkhachorn S, J. Control. Release, 107, 343 (2005)

[26] Samanta HS, Ray SK, Carbohydr. Polym., 99, 666 (2014)

[27] Pereira R, Carvalho A, Vaz DC, Gil MH, Mendesa A, Bartolo P, Int. J. Biol. Macromol., 52, 221 (2013)

[28] Ritger PL, Peppas NA, J. Control. Release, 5, 23 (1987)

[29] Mitta KL, Relevance to Adhesion Science and Technology, VSP, Utrecht, 2000.

[30] Bhattacharyya R, Ray SK, Poly. Eng. Sci., 53(11), 2439 (2013)

[31] Lagergren S, Kungliga Svenska Vetenskapsakademiens, Handlingar, 24, 1 (1898)

[32] Ho YS, McKay G, Trans. Inst. Chem. Eng., 76B, 183 (1998)

[33] Lazaridis NK, Kyzas GZ, Vassiliou AA, Bikiaris DN, Langmuir, 23(14), 7634 (2007)

[34] Hameed BH, El-Khaiary MI, J. Hazard. Mater., 159(2-3), 574 (2008)

[35] Bayramoglu G, Altintas B, Arica MY, Chem. Eng. J., 152(2-3), 339 (2009)

[36] Abramian L, El-Rassy H, Chem. Eng. J., 150(2-3), 403 (2009)

[37] Banat IM, Nigam P, Singh D, Marchant R, Bioresour. Technol., 58(3), 217 (1996)

[38] Wang Y, Zeng L, Ren X, Song H, Wang A, J. Environ. Sci., 221, 7 (2010)

[39] Gupta VK, Mittal A, Gajbe V, Mittal J, J. Colloid Interface Sci., 319(1), 30 (2008)

[40] Wang J, Wang H, Song Z, Kong D, Chen X, Yang Z, Colloids Surf. B: Biointerfaces, 80, 155 (2010)

[41] Solpan D, Duran S, Guven DOS, Radiat. Phys. Chem., 66, 117 (2003)

[42] Olpan DS, Lge ZK, Rad, 75, 120 (2006)