Synthesis, characterization and conducting behavior of heavy metal sensitive polyaniline/zirconium (IV) tungstoiodophosphate nanocomposite

Asif Ali Khan; Leena Paquiza

Journal of Industrial and Engineering Chemistry, Vol.22, 208-216, February, 2015

DOI10.1016/j.jiec.2014.07.012 Export Citation

Synthesis, characterization and conducting behavior of heavy metal sensitive polyaniline/zirconium (IV) tungstoiodophosphate nanocomposite

Asif Ali Khan^†, and Leena Paquiza

Analytical and Polymer Research Laboratory, Department of Applied Chemistry, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh 202002, India

E-mail:

Preparation, characterization, and evaluation of conducting nature of nano-ordered material has been done by sol?gel mixing of an electrical conducting polymer polyaniline into the matrices of inorganic precipitate zirconium tungstoiodophosphate. The physico-chemical property was determined using TGA?DTA, FTIR, X-ray, and SEM studies. The results of physical properties were found progressive in terms of their specific properties. Electrical conductivity determined by four-in-line probe method shows semi-conducting range, i.e., 10?3?10?2 S cm?1. Sensitivity and selectivity was explored by its adsorption efficiency towards heavy metal ions. Proposed material was selective for copper, a heavy toxic metal ion indicating its utility in decreasing pollution load.

Keywords:Zirconium tungstoiodophosphate;Polyaniline;Hybrid composites;Heavy metal ions;DC electrical conductivity

[References]

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Louis E, Macdiarmid AG, Chiang CK, Hegger AJ, J. Chem. Soc. Chem. Commun., 16, 578 (1977)
Carpi F, Mazzoldi A, Smart Mater. Struct., 15, 279 (2006)
Spinks GM, Mottaghitalab V, Bahrami-Saniani M, Whitten PG, Wallace GG, Adv. Mater., 18(5), 637 (2006)
Yang CH, Chih YK, Wu WC, Chen CH, Electrochem. Solid State Lett., 9(1), C5 (2006)
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Fang J, Lv M, Chen C, Chi X, Yang Y, Zhang Z, J. Mater. Chem., 21, 11340 (2011)
Markku J, Int. J. Electrochem. Sci., 7, 11696 (2012)
Zhang K, Chan H, Wu J, J. Mater. Chem., 22, 80 (2012)
Guizard C, Bac A, Barboiu M, Hovnanian N, Sep. Purif. Technol., 25(1-3), 167 (2001)
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Ding J, Zhang S, Kong J, Biosens. Bioelectron., 21, 2184 (2006)
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Koene BE, Nazar LE, J. Electrochem. Soc., 143, 181 (1996)
Shouji E, Buttry DA, Langmuir, 15(3), 669 (1999)
Gomez-Romero P, J. Electrochem. Soc., 146, 29 (1999)
Huguenin F, Gambardella MTD, Torresi RM, de Torresi SI, Buttry DA, J. Electrochem. Soc., 147(7), 2437 (2000)
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Paquiza L, Khan A, J. Mater. Sci., 45, 3610 (2012)
Khan A, Habiba U, Paquiza L, Ahmad S, J. Ad. Res., 341 (2011)
Khan AA, Paquiza L, Desalination, 272(1-3), 278 (2011)
Ali Khan A, Alam MM, Mohammad IF, J. Electroanal. Chem., 572(1), 67 (2004)
Khan A, Inamuddin, Talanta, 72, 699 (2007)
Siddiqui WA, Khan SA, Inamuddin, Colloids Surf. A: Physicochem. Eng. Asp., 295, 193 (2007)
Khan WA, Siddiqui AA, Khan, Talanta, 71, 841 (2007)
Inamuddin X, React. Funct. Polym., 66, 1649 (2006)
Stejskal J, Kratochvil P, Helmstedt M, Langmuir, 12(14), 3389 (1996)
J. Chem. Soc.-Faraday Trans., 25, 320 (1925)
J. Am. Chem. Soc., 51, 1010 (1929)
Torracca E, Conte A, J. Inorg. Nucl. Chem., 28, 607 (1966)
Ahmed S, Bull. Mater. Sci., 30, 43 (2007)
Wan MX, Li JC, J. Polym. Sci. A: Polym. Chem., 36(15), 2799 (1998)
Wan MX, Li M, Li JC, Liu ZX, J. Appl. Polym. Sci., 53(2), 131 (1994)
Chemical Applications of Infrared Spectroscopy, Academic Press, New York, 1963p. 250.
Amsterdam (1963) 315.
Wu CG, Degroot DC, Marcy HO, Schindler JL, Kannewurf CR, Bakas T, Papaefthymiou V, Hirpo W, Yesinowski JP, Liu YJ, Kanatzidis MG, J. Am. Chem. Soc., 117(36), 9229 (1995)
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Zuo F, Angelopoulos M, MacDiarmid AG, Epstein AJ, Phys. Rev. B, 36, 3475 (1987)

[Referenced By]

[1] Epstein AJ, Conducting Polymers Science and Technology, Second Brazilian Polymer Conference, Plenum Publishing Corp, Brazil, 1993.

[2] Graupner W, Synth. Met., 57, 3623 (1993)

[3] Louis E, Macdiarmid AG, Chiang CK, Hegger AJ, J. Chem. Soc. Chem. Commun., 16, 578 (1977)

[4] Carpi F, Mazzoldi A, Smart Mater. Struct., 15, 279 (2006)

[5] Spinks GM, Mottaghitalab V, Bahrami-Saniani M, Whitten PG, Wallace GG, Adv. Mater., 18(5), 637 (2006)

[6] Yang CH, Chih YK, Wu WC, Chen CH, Electrochem. Solid State Lett., 9(1), C5 (2006)

[7] Jung S, Chem. Matter, 17, 6381 (2006)

[8] Fang J, Lv M, Chen C, Chi X, Yang Y, Zhang Z, J. Mater. Chem., 21, 11340 (2011)

[9] Markku J, Int. J. Electrochem. Sci., 7, 11696 (2012)

[10] Zhang K, Chan H, Wu J, J. Mater. Chem., 22, 80 (2012)

[11] Guizard C, Bac A, Barboiu M, Hovnanian N, Sep. Purif. Technol., 25(1-3), 167 (2001)

[12] Harju L, Ivaska A, Anal. Chem., 78, 3019 (2006)

[13] Ding J, Zhang S, Kong J, Biosens. Bioelectron., 21, 2184 (2006)

[14] Chaudhari S, Patil PP, Electrochim. Acta, 53(2), 927 (2007)

[15] Martin CR, Science, 266(5193), 1961 (1994)

[16] Koene BE, Nazar LE, J. Electrochem. Soc., 143, 181 (1996)

[17] Shouji E, Buttry DA, Langmuir, 15(3), 669 (1999)

[18] Gomez-Romero P, J. Electrochem. Soc., 146, 29 (1999)

[19] Huguenin F, Gambardella MTD, Torresi RM, de Torresi SI, Buttry DA, J. Electrochem. Soc., 147(7), 2437 (2000)

[20] Li ZF, Ruckenstein E, Langmuir, 18(18), 6956 (2002)

[21] Paquiza L, J. Ind. Eng. Chem., (In press) (2014)

[22] Paquiza L, J. Appl. Polym. Sci., 3737 (2013)

[23] Paquiza L, Desalination, 272, 278 (2012)

[24] Paquiza L, Synth. Met., 161, 899 (2011)

[25] Paquiza L, Khan A, J. Mater. Sci., 45, 3610 (2012)

[26] Khan A, Habiba U, Paquiza L, Ahmad S, J. Ad. Res., 341 (2011)

[27] Khan AA, Paquiza L, Desalination, 272(1-3), 278 (2011)

[28] Ali Khan A, Alam MM, Mohammad IF, J. Electroanal. Chem., 572(1), 67 (2004)

[29] Khan A, Inamuddin, Talanta, 72, 699 (2007)

[30] Siddiqui WA, Khan SA, Inamuddin, Colloids Surf. A: Physicochem. Eng. Asp., 295, 193 (2007)

[31] Khan WA, Siddiqui AA, Khan, Talanta, 71, 841 (2007)

[32] Inamuddin X, React. Funct. Polym., 66, 1649 (2006)

[33] Stejskal J, Kratochvil P, Helmstedt M, Langmuir, 12(14), 3389 (1996)

[34] J. Chem. Soc.-Faraday Trans., 25, 320 (1925)

[35] J. Am. Chem. Soc., 51, 1010 (1929)

[36] Torracca E, Conte A, J. Inorg. Nucl. Chem., 28, 607 (1966)

[37] Ahmed S, Bull. Mater. Sci., 30, 43 (2007)

[38] Wan MX, Li JC, J. Polym. Sci. A: Polym. Chem., 36(15), 2799 (1998)

[39] Wan MX, Li M, Li JC, Liu ZX, J. Appl. Polym. Sci., 53(2), 131 (1994)

[40] Chemical Applications of Infrared Spectroscopy, Academic Press, New York, 1963p. 250.

[41] Amsterdam (1963) 315.

[42] Wu CG, Degroot DC, Marcy HO, Schindler JL, Kannewurf CR, Bakas T, Papaefthymiou V, Hirpo W, Yesinowski JP, Liu YJ, Kanatzidis MG, J. Am. Chem. Soc., 117(36), 9229 (1995)

[43] Leroux F, Koene BE, Nazar LF, J. Electrochem. Soc., 143(9), L181 (1996)

[44] Instruction Manual, Scientific Equipment and Services, Roorkee, India, 2000.

[45] Mohammad F, in: Nalwa HS (Ed.), Handbook of Advanced Electronic and Photonic Materials and Devices, Academic Press, New York, 2000, p. 321.

[46] Zuo F, Angelopoulos M, MacDiarmid AG, Epstein AJ, Phys. Rev. B, 36, 3475 (1987)