화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.35, 63-74, March, 2016
High-performance removal of toxic phenol by single-walled and multi-walled carbon nanotubes: Kinetics, adsorption, mechanism and optimization studies
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The adsorption capabilities of two nano-sized adsorbents: multi-walled carbon nanotubes (MWCNTs) and single-walled carbon nanotubes (SWCNTs) were investigated for the removal of toxic phenol. The maximum adsorption capacities of MWCNTs and SWCNTs were determined as 64.60 and 50.51 mg/g, respectively. Adsorption kinetics followed the pseudo-second order model for both adsorbents. The optimum conditions using SWCNTs and MWCNTs were pH 6.57 and 4.65, phenol concentration 50 and 50 mg/L, dose 1.97 and 2 g/L and contact time 36 and 56 min, respectively. The results indicated that MWCNTs and SWCNTs were proven as high-performance adsorbents for toxic phenol removal from wastewater.
  1. hmaruzzaman M, Adv. Colloid Interface Sci., 143, 48 (2008)
  2. Ahmaruzzaman M, Gayatri SL, J. Chem. Eng. Data, 56(7), 3004 (2011)
  3. Huang JH, Jin XY, Deng SG, Chem. Eng. J., 192, 192 (2012)
  4. Ispas CR, Ravalli MT, Steere A, Andreescu S, Water Res., 44, 1961 (2010)
  5. Guan ZR, Liu L, He LL, Yang S, J. Hazard. Mater., 196, 270 (2011)
  6. Yan JH, Du CM, Li XD, Sun XD, Ni MI, Cen KF, Cheron B, Plasma Sources Sci. Technol., 14, 637 (2005)
  7. Abdelwahab O, Amin NK, El-Ashtoukhy ESZ, J. Hazard. Mater., 163(2-3), 711 (2009)
  8. Kumar A, Kumar S, Kumar S, Biochem. Eng. J., 22, 151 (2005)
  9. Lin SH, Juang RS, J. Environ. Manage., 90, 1336 (2009)
  10. Fierro V, Torne-Fernandez V, Montane D, Celzard A, Microporous Mesoporous Mater., 111, 276 (2008)
  11. Huang J, Wang X, Jin Q, Liu Y, Wang Y, J. Environ. Manage., 84, 229 (2007)
  12. Lin KL, Pan JY, Chen YW, Cheng RM, Xu XC, J. Hazard. Mater., 161(1), 231 (2009)
  13. Hameed BH, Rahman AA, J. Hazard. Mater., 160(2-3), 576 (2008)
  14. Banat F, Al-Bashir B, Al-Asheh S, Hayajneh O, Environ. Pollut., 107, 391 (2000)
  15. Jiang JQ, Cooper C, Ouki S, Chemosphere, 47, 711 (2002)
  16. Dursun G, Cicek H, Dursun AY, J. Hazard. Mater., 125(1-3), 175 (2005)
  17. Albadarin AB, Yang ZY, Mangwandi C, Glocheux Y, Walker G, Ahmad MNM, Chem. Eng. Res. Des., 92(7), 1354 (2014)
  18. Soylak M, Unsal YE, Food Chem. Toxicol., 48, 1511 (2010)
  19. Dehghani MH, Taher MM, Bajpai AK, Heibati B, Tyagi I, Asif M, Agarwal S, Gupta VK, Chem. Eng. J., 279, 344 (2015)
  20. Bayazit SS, Kerkez O, Chem. Eng. Res. Des., 92(11), 2725 (2014)
  21. Sarkar B, Xi Y, Megharaj M, Naidu R, Appl. Clay Sci., 51, 370 (2011)
  22. Heibati B, Rodriguez-Couto S, Al-Ghouti MA, Asif M, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 208, 99 (2015)
  23. Lagergren S, Handlingar, 24, 1 (1898)
  24. Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
  25. Langmuir I, Amer J, Chem. Soc., 40, 1361 (1918)
  26. Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
  27. Redlich O, Peterson DL, J. Phys. Chem., 63, 1024 (1959)
  28. Jossens L, Prausnitz JM, Fritz W, Schlunder EU, Myers AL, Chem. Eng. Sci., 33, 1097 (1978)
  29. Bhatnagar A, Kumar E, Sillanpaa M, Chem. Eng. J., 163(3), 317 (2010)
  30. Mubarak NM, Sahu JN, Abdullah EC, Jayakumar NS, Ganesan P, J. Ind. Eng. Chem., 24, 24 (2015)
  31. Ehrampoush M, Ghanizadeh G, Ghaneian M, JEHSE, 8, 101 (2011)
  32. Sahu JN, Acharya J, Meikap BC, J. Hazard. Mater., 172(2-3), 818 (2009)
  33. Massalha N, Brenner A, Sheindorf C, Haimov Y, Sabbah I, Chem. Eng. J., 280, 283 (2015)
  34. Tahermansouri H, Dehghan Z, Kiani F, RSC Adv., 5, 44263 (2015)
  35. Heibati B, Rodriguez-Couto S, Amrane A, Rafatullah M, Hawari A, Al-Ghouti MA, J. Ind. Eng. Chem., 20(5), 2939 (2014)
  36. Lin D, Xing B, Environ. Sci. Technol., 42, 7254 (2008)
  37. Adinarayana K, Ellaiah P, J. Pharm. Pharm. Sci., 5, 271 (2002)
  38. Sen R, Swaminathan T, Biochem. Eng. J., 21, 141 (2004)
  39. Can MY, Kaya Y, Algur OF, Bioresour. Technol., 97(14), 1761 (2006)
  40. Yetilmezsoy K, Demirel S, Vanderbei RJ, J. Hazard. Mater., 171(1-3), 551 (2009)
  41. Mall ID, Srivastava VC, Agarwal NK, Mishra IM, Chemosphere, 61, 492 (2005)
  42. McKay G, Bino MJ, Chem. Eng. Res. Des., 63, 168 (1985)
  43. Hamza HA, Atieh MA, Laoui T, Sixteenth International Water Technology Conference, IWTC, vol 16, 2012.
  44. Veziri CM, Pilatos G, Karanikolos GN, Labropoulos A, Kordatos K, Kasselouri-Rigopoulou V, Kanellopoulos NK, Microporous Mesoporous Mater., 110, 41 (2008)
  45. Daifullah AAM, Girgis BS, Water Res., 32, 1169 (1998)
  46. Nevskaia DM, Santianes A, Munoz V, Gurrero-Ruiz A, Carbon, 37, 1065 (1999)
  47. Johns MM, Marshall WE, Toles CA, J. Chem. Technol. Biotechnol., 74(11), 1037 (1999)
  48. Al-Degs YS, El-Barghouthi MI, Khraisheh MA, Ahmad MN, Allen SJ, Sep. Sci. Technol., 39(1), 97 (2004)
  49. Hadi P, Yeung KY, Barford JP, An KJ, McKay G, JECE, 3, 1029 (2015)
  50. Kasaoka S, Sakata Y, Tanaka E, Naitoh R, Int. Chem. Eng., 29, 734 (1989)
  51. Tessmer H, Vidic RD, Uranowski LJ, Environ. Sci. Technol., 31, 1872 (1997)
  52. Li L, Quinlivan PA, Knappe DRU, Carbon, 40, 2085 (2002)
  53. Bembnowska A, Pelech R, Milchert E, J. Colloid Interface Sci., 265(2), 276 (2003)
  54. Attia AA, Girgis BS, Khedr SA, J. Chem. Technol. Biotechnol., 78(6), 611 (2003)
  55. Mui ELK, Cheung WH, Valix M, McKay G, J. Colloid Interface Sci., 347(2), 290 (2010)
  56. Shi J, Zeng J, Wu P, Ji X, Catal. Commun., 9, 1846 (2008)
  57. Yang RT, Adsorbents: Fundamentals and Applications, John Wiley & Sons, New York, 2003.
  58. Hameed BH, Rahman AA, J. Hazard. Mater., 160(2-3), 576 (2008)
  59. Vazquez I, Rodriguez-Iglesias J, Maranon E, Castrillon L, Alvarez M, J. Hazard. Mater., 147(1-2), 395 (2007)
  60. Kumar A, Kumar S, Kumar S, Gupta DV, J. Hazard. Mater., 147(1-2), 155 (2007)
  61. Ozkaya B, J. Hazard. Mater., 129(1-3), 158 (2006)
  62. Srivastava VC, Swamy MM, Mall ID, Prasad B, Mishra IM, Colloids Surf. A: Physicochem. Eng. Asp., 272, 89 (2006)
  63. Weber WJ, Morris JC, Advances in water pollution research, Proceedings of the First International Conference on Water Pollution Research, 2, 1962, p. 231.
  64. Allen S, McKay G, Khader K, Environ. Pollut., 56, 39 (1989)
  65. Ruthiraan M, Mubarak NM, Thines RK, Abdullah EC, Sahu JN, Jayakumar NS, Ganesan P, Korean J. Chem. Eng., 32(3), 446 (2015)
  66. Majhi S, Mohanty P, Dalai AK, Pant KK, Energy Technol., 1, 157 (2013)