화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.46, 35-43, February, 2017
DOI10.1016/j.jiec.2016.09.031  Export Citation
Characterization and absorption studies of cationic dye on multi walled carbon nanotube-carbon ceramic composite
Tayebeh Esfandiyari, Navid Nasirizadeh1, †, Mohammad Hassan Ehrampoosh, and Masoumeh Tabatabaee2
  • Department of Environmental Health Engineering, Shahid Sadoughi University of Medical Sciences, Yazd, Iran
  • 1Young Researchers and Elite Club, Yazd Branch, Islamic Azad University, Yazd, Iran
  • 2Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran
E-mail:
The multi walled carbon nanotube.carbon ceramic composite (MWCNT-CCC) was synthesized by sol gel technique, as a promising strategy for the preparation of nanocomposites and used as adsorbents for removal of Basic Yellow 28 dye from aqueous solution. The physicochemical properties of MWCNT-CC composites was characterized using different techniques such as FESEM, EDX, XRD, and BET. The effects of operating parameters such as pH, contact time, initial dye concentration and amount of the adsorbents were investigated by response surface methodology (RSM). Optimum adsorption (85%) was achieved at pH 8.0, dye concentrations 15.0 mg/L, and 1.5 g/L adsorbent at 80 min. The adsorption process can be well described by the pseudo second order kinetic model. The experimental data of isotherm followed the Freundlich isotherm model. Moreover, the thermodynamic parameters calculated from the temperature-dependent isotherms indicated that the adsorption reaction was an endothermic and spontaneous process. All results indicate that the MWCNT-CCC is a promising adsorbent for the efficient removal of basic dye from wastewater.
Keywords:Adsorbent;Nanocomposite;Sol gel technique;Carbon ceramic composite
  1. Dehghani MH, Najafpoor AA, Azam K, Desalination, 250(1), 82 (2010)
  2. Cheng J, Shi L, Lu J, J. Ind. Eng. Chem., 36, 206 (2016)
  3. Patra S, Roy E, Madhuri R, Sharma PK, J. Ind. Eng. Chem., 33, 226 (2016)
  4. Mahmoodi NM, J. Ind. Eng. Chem., 20(4), 2050 (2014)
  5. Karimi L, Zohoori S, Yazdanshenas ME, J. Saudi Chem. Soc., 18, 581 (2014)
  6. Dalvand A, Nabizadeh R, Ganjali MR, Khoobi M, Nazmara S, Mahvi AH, J. Magn. Magn. Mater., 404, 179 (2016)
  7. Morshedi D, Mohammadi Z, Boojar MMA, Aliakbari F, Colloids Surf. B: Biointerfaces, 112, 245 (2013)
  8. Mohammed GR, Zewail TM, El-Tawail YA, Desalin. Water Treat., 52, 6684 (2014)
  9. Zheng YP, Yao GH, Cheng QB, Yu SC, Liu MH, Gao CJ, Desalination, 328, 42 (2013)
  10. Radi A, Nasirizadeh N, Rohani-Moghadam M, Dehghani M, Ultrason. Sonochem., 27, 609 (2015)
  11. Dil EA, Ghaedi M, Ghaedi AM, Asfaram A, Goudarzi A, Hajati S, Soylak M, Agarwal S, Gupta VK, J. Ind. Eng. Chem., 34, 186 (2016)
  12. Salem MA, Elsharkawy RG, Hablas MF, Eur. Polym. J., 75, 577 (2016)
  13. Motlagh MM, Hassanzadeh-Tabrizi SA, Saffar-Teluri A, J. Sol-Gel Sci. Technol., 73, 9 (2014)
  14. Ahmed MJ, J. Environ. Chem. Eng., 4, 89 (2016)
  15. Kocadagistan B, Kocadagistan E, Desalin. Water Treat., 57, 3168 (2016)
  16. Ribeiro C, Scheufele FB, Espinoza-Quinones FR, Modenes AN, da Silva MGC, Vieira MGA, Borba CE, Colloids Surf. A: Physicochem. Eng. Asp., 482, 693 (2015)
  17. Sankar MK, Kumar KM, Ranganathan BV, Int. J. Environ. Sci. Technol., 12, 2957 (2015)
  18. Leng LJ, Yuan XZ, Zeng GM, Shao JG, Chen XH, Wu ZB, Wang H, Peng X, Fuel, 155, 77 (2015)
  19. Zhao GY, Liu LJ, Li JR, Liu Q, J. Alloy. Compd., 664, 169 (2016)
  20. Tian J, Tian P, Pang H, Ning G, Bogale RF, Cheng H, Shen S, Microporous Mesoporous Mater., 223, 27 (2016)
  21. Singh SA, Vemparala B, Madras G, J. Environ. Chem. Eng., 3, 2684 (2015)
  22. Almasian A, Olya ME, Mahmoodi NM, Fibers Polym., 16, 1925 (2015)
  23. Hassani A, Khataee A, Karaca S, Karaca M, Kiransan M, J. Environ. Chem. Eng., 3, 2738 (2015)
  24. Masjedi-Arani M, Salavati-Niasari M, Ultrason. Sonochem., 29, 226 (2016)
  25. Bai X, Yu L, Hua ZL, Tang ZQ, Zhang JN, Mater. Chem. Phys., 163, 407 (2015)
  26. Huang JY, Zheng YX, Luo LB, Feng Y, Zhang CL, Wang X, Liu XY, J. Hazard. Mater., 306, 210 (2016)
  27. Deng JH, Zhang XR, Zeng GM, Gong JL, Niu QY, Liang J, Chem. Eng. J., 226, 189 (2013)
  28. Kim J, Oh S, Kwak SY, Chem. Eng. J., 281, 541 (2015)
  29. Ma H, Li JB, Liu WW, Miao M, Cheng BJ, Zhu SW, Bioresour. Technol., 90, 13 (2015)
  30. Wang H, Gao HH, Chen MX, Xu XY, Wang XF, Pan C, Gao JP, Appl. Surf. Sci., 360, 840 (2016)
  31. Jose M, Kumari M, Karunakaran R, Shukla S, J. Sol-Gel Sci. Technol., 75, 541 (2015)
  32. Liu H, You L, Ye X, Li W, Wu Z, J. Sol-Gel Sci. Technol., 45, 279 (2008)
  33. Singh V, Pandey S, Singh SK, Sanghi R, J. Sol-Gel Sci. Technol., 47, 58 (2008)
  34. Chen FY, Wu QP, Lu QF, Xu YL, Yu Y, Sep. Purif. Technol., 151, 225 (2015)
  35. Nasirizadeh N, Dehghani M, Yazdanshenas ME, J. Sol-Gel Sci. Technol., 73, 14 (2015)
  36. Hosseini S, Khan MA, Malekbala MR, Cheah W, Choong TSY, Chem. Eng. J., 171(3), 1124 (2011)
  37. Helfferich F, Ion exchange, McGraw-Hill, New York, 1962, pp. 357.
  38. Olgun A, Atar N, J. Hazard. Mater., 161(1), 148 (2009)
  39. Eatemadifar A, Dehghanizadeh H, Nasirizadeh N, Moghadam MR, Fibers Polym., 15, 254 (2014)
  40. Nazari A, Mirjalili M, Nasirizadeh N, Torabian S, J. Ind. Eng. Chem., 21, 1068 (2015)
  41. Pehlivan E, Yanik BH, Ahmetli G, Pehlivan M, Bioresour. Technol., 99(9), 3520 (2008)
  42. Gupta VK, Pathania D, Kothiyal NC, Sharma G, J. Mol. Liq., 190, 139 (2014)
  43. Kannan N, Indian J. Environ. Prot., 11, 514 (1991)
  44. Liu Y, Li JJ, Yang Y, Li BP, Appl. Surf. Sci., 351, 831 (2015)
  45. Pirkarami A, Olya ME, Najafi F, J. Ind. Eng. Chem., 21, 387 (2015)
  46. Shaker MA, Yakout AA, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 154, 145 (2016)
  47. Travlou NA, Kyzas GZ, Lazaridis NK, Deliyanni EA, Chem. Eng. J., 217, 256 (2013)
  48. Rahimi R, Kerdari H, Rabbani M, Shafiee M, Desalination, 280(1-3), 412 (2011)
  49. Ai LH, Zhang CY, Liao F, Wang Y, Li M, Meng LY, Jiang J, J. Hazard. Mater., 198, 282 (2011)
  50. Ayad MM, El-Nasr AA, Stejskal J, J. Ind. Eng. Chem., 18(6), 1964 (2012)