화학공학소재연구정보센터
Applied Chemistry, Vol.2, No.2, 660-663, October, 1998
Effcet of Additives on the Radiation Grafting of Methylmethacrylate onto Polypropylene
The effects of the molecular weight of polypropylene, nucleating agent and types of stabilizers on the grafting of methylmethacrylate onto polypropylene sheet were examined. The oxidation of polypropylene sheet surfaces exposed to air after irradiation was studied by measuring survey scan spectra with an X-ray photoelectron spectrometer(XPS). The 1,1-diphenyl-2-picrylhydrzyl(DPPH) techinque was utilized to evaluate the concentration of peroxide formed on the irradiated polypropylene sheet by counting the quantity of DPPH consumed by the reaction of peroxide radicals with DPPH. Plastics stabilizers caused a decrease in the concentration of peroxide in the polymer as well as trapped radicals. It was shown that the stabilizer in polypropylene markedly decreased the grafting of methylmethacrylate onto polypropylene.