화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.42, No.4, 581-593, July, 2018
DOI10.7317/pk.2018.42.4.581  Export Citation
ATRP의 전자전달로 생성된 활성제를 이용한 산화그래핀의 표면기능화와 Poly(lactic acid)의 성능에 미치는 영향
Surface Functionalization of Graphene Oxide via Activators Regenerated by Electron Transfer for Atom Transfer Radical Polymerization and Its Effect on the Performance of Poly(lactic acid)
Lang Zheng, Weijun Zhen†
  • Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education and Xinjiang Uygur Autonomous Region Xinjiang University, Urumqi 830046
Lang Zheng, and Weijun Zhen†
  • Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education and Xinjiang Uygur Autonomous Region, Xinjiang University, Urumqi 830046, Korea
E-mail:
An improved Hummers method was used to prepare graphene oxide (GO). Then, the orthogonal experiment design methods were used to select the optimum conditions of preparation for graphene oxide-polymethyl methacrylate (GO-PMMA) via activators regenerated by electron transfer for atom transfer radical polymerization (AGET-ATRP). The optimum preparation conditions were determined by orthogonal tests. Furthermore, poly(lactic acid) (PLA)/GO-PMMA nanocomposites were prepared by melt blending to improve the comprehensive performance of PLA. Analysis results indicated that methyl methacrylate (MMA) was successfully grafted onto GO, and the addition of 0.3 wt% of GO-PMMA increased the tensile strength, elongation at break, and impact strength of PLA/GO-PMMA nanocomposites by 7.82, 40.66, and 50.62%, respectively, compared with PLA. Moreover, GO-PMMA eliminated the cold crystallization of PLA matrix and improved the crystallinity of PLA by 27.55%. In all, this study provided an effective and feasible method for improving the comprehensive performance of PLA.
Keywords:poly(lactic acid);graphene oxide;activators regenerated by electron transfer for atom transfer radical polymerization (AGET-ATRP);nanocomposites
  1. Craparo EF, Porsio B, Bondi ML, Giammona G, Cavallaro G, Polym. Degrad. Stabil., 119, 56 (2015)
  2. Zhang Y, Zhao Y, Pan H, Lang X, Yang H, Zhang H, Zhang H, Dong L, Polym. Korea, 40(3), 429 (2016)
  3. Tyler B, Gullotti D, Mangraviti A, Utsuki T, Brem H, Adv. Drug Deliv. Rev., 107, 163 (2016)
  4. Lantano C, Alfieri I, Cavazza A, Corradini C, Lorenzi A, Zucchetto N, Food Chem., 165, 342 (2014)
  5. Zhu X, Huang R, Zhong T, Wan A, Polym. Korea, 39(6), 889 (2015)
  6. Lunt J, Shafer AL, J. Ind. Text., 29, 191 (2000)
  7. Bang G, Kim SW, J. Ind. Eng. Chem., 18(3), 1063 (2012)
  8. Zhen W, Sun J, Polym. Korea, 38(3), 299 (2014)
  9. Zhang R, Wang YM, Wang KJ, Zheng GQ, Li Q, Shen CY, Polym. Bull., 70(1), 195 (2013)
  10. Mascheroni E, Guillard V, Nalin F, Mora L, Piergiovanni L, J. Food Eng., 98(3), 294 (2010)
  11. Abdalhay A, Hussein KH, Casettari L, Khalil KA, Hamdy AS, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 60, 143 (2016)
  12. Geyter ND, Morent R, Desmet T, Trentesaux M, Gengembre L, Dubruel P, Surf. Coat. Technol., 204, 3272 (2010)
  13. Xiang H, Mu Y, Hu C, Luo X, J. Nanomater, 2017, 10 (2017)
  14. Arjmandi R, Hassan A, Eichhorn SJ, Haafiz MKM, Zakaria Z, Tanjung FA, J. Mater. Sci., 50(8), 3118 (2015)
  15. Tverdokhlebov SI, Bolbasov EN, Shesterikov EV, Antonova LV, Golovkin AS, Matveeva VG, Petlin DG, Anissimov YG, Appl. Surf. Sci., 329, 32 (2015)
  16. Han HS, You JM, Jeong H, Jeon S, J. Nanosci. Nanotechnol., 14, 4050 (2014)
  17. Cao Y, Feng J, Wu P, Carbon, 48, 3834 (2010)
  18. Cai YH, Tang Y, Zhao LS, J. Appl. Polym. Sci., 132, 1 (2015)
  19. Chen Y, Zhang A, Ding L, Liu Y, Lu H, Composites Part B, 108, 386 (2017)
  20. Yang X, Zhao N, Xu FJ, Nanoscale, 6, 6141 (2014)
  21. Zhan X, Yan Y, Zhang Q, Chen F, J. Mater. Chem. A, 2, 9390 (2014)
  22. Perreault F, Tousley ME, Elimelech M, Environ. Sci. Technol. Lett., 1, 71 (2016)
  23. Kim B, Jeong J, Jung J, Kim BS, Jung K, Paik H, Polym. Korea, 38(5), 671 (2014)
  24. Kumar M, Chung JS, Hur SH, Nanoscale Res. Lett., 9, 345 (2014)
  25. Hummers WS, Offeman RE, J. Am. Chem. Soc., 80, 1339 (1958)
  26. Wu X, Leung DYC, Appl. Energy, 88(11), 3615 (2011)
  27. Zhong JF, Chai XS, Qin XL, Fu SY, Carbohydr. Polym., 86, 367 (2011)
  28. Chai XS, Zhong JF, Hu HC, J. Chromatogr. A, 1238, 128 (2012)
  29. Lee SH, Dreyer DR, An JH, Velamakanni A, Piner RD, Park S, Zhu YW, Kim SO, Bielawski CW, Ruoff RS, Macromol. Rapid Commun., 31(3), 281 (2010)
  30. Qi K, Sun Y, Duan H, Guo X, Corrosion Sci., 98, 500 (2015)
  31. Kotre T, Nuyken O, Weberskirch R, Macromol. Rapid Commun., 23, 871 (2015)
  32. Opaprakasit P, Opaprakasit M, Tangboriboonrat P, Appl. Spectrosc., 61, 1352 (2007)
  33. Goncalves G, Marques PAAP, Timmons AB, Bdkin I, Singh MK, Emami N, J. Mater. Chem., 20, 9927 (2010)
  34. Xu L, Yin B, Yan H, Ma A, Yang M, Rsc. Adv., 5, 82005 (2015)
  35. Wang HS, Qiu ZB, Thermochim. Acta, 527, 40 (2012)
  36. Lei L, Qiu JH, Sakai E, Chem. Eng. J., 209, 20 (2012)
  37. Bao C, Song L, Xing W, Yuan B, Wilkie CA, Huang J, J. Mater. Chem., 22, 6088 (2012)
  38. Shayan M, Azizi H, Ghasemi I, Karrabi M, Carbohydr. Polym., 124, 237 (2015)
  39. Wang L, Wang YN, Huang ZG, Weng YX, Mater. Des., 66, 7 (2015)
  40. Lu T, Liu S, Jiang M, Xu X, Wang Y, Wang Z, Composites Part B, 62, 191 (2014)
  41. Chieng B, Ibrahim N, Wan Y, Hussein M, Then Y, Loo Y, Polymer, 6, 2232 (2014)
  42. Jawaid M, Hassan A, Balakrishnan H, J. Compos. Mater., 48, 769 (2014)
  43. Huang HD, Ren PG, Xu JZ, Xu L, Zhong GJ, Hsiao BS, J. Membrane Sci., 464, 110 (2014)
  44. Xu ZH, Niu YH, Yang L, Xie WY, Li H, Gan ZH, Wang ZG, Polymer, 51(3), 730 (2010)
  45. Babanalbandi A, Hill D, Hunter D, Kettle L, Polym. Int., 48, 980 (2015)
  46. Henricks J, Boyum M, Zheng W, J. Therm. Anal. Calorim., 120, 1 (2015)
  47. Xu Y, Yu W, Zhou C, RSC Adv., 4, 55435 (2014)
  48. Fehri MK, Mugoni C, Cinelli P, Anguillesi I, Coltelli MB, Fiori S, Express. Polym. Lett., 10, 274 (2016)
  49. Salehiyan R, Yussuf AA, Akbari A, J. Elastom. Plast., 47, 69 (2015)
  50. Carbone MJ, Vanhalle M, Goderis B, Van Puyvelde P, J. Polym. Eng., 35, 169 (2015)
  51. Eslami H, Kamal MR, J. Appl. Polym. Sci., 129(5), 2418 (2013)
  52. Cooper-White JJ, Mackay ME, J. Polym. Sci. B: Polym. Phys., 37(15), 1803 (1999)
  53. Helle A, Hirsjarvi S, Peltonen L, Hirvonen J, Wiedmer SK, J. Chromatogr. A, 1178, 248 (2008)