화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.74, 41-54, June, 2019
Hybrid graphene oxide decoration and water-based polymers for mild steel surface protection in saline environment
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Nitrogen, sulfur and phosphorous atoms were chemically introduced to graphene oxide nanostructure (NSP-GO) to construct a corrosion inhibitor for mild steel in a 3.5 wt% NaCl solution. The anticorrosive effects of NSP-GO on two synthesized water-soluble polymeric compounds, melamine formaldehyde (MF) and urea formaldehyde (UF), were investigated in the saline environment. With NSP-GO, the inhibition efficiency of 93% (for UF) and 95% (MF) reached to -100% for both composites at 500 ppm concentration. The heteroatoms of decorated GO sheets act like anchors to pull GO sheets towards the metal surface and make MF and UF polymers films as full protectors.
  1. Berry V, Carbon, 62, 1 (2013)
  2. Hernaez M, et al., Sensors, 17, 155 (2017)
  3. Likhanova NV, et al., Int. J. Electrochem. Sci., 6(10), 4514 (2011)
  4. Bourazmi H, et al., J. Mater. Environ. Sci., 9(3), 1058 (2018)
  5. Xing X, Wang J, Li Q, Hu W, Yuan J, Colloids Surf., 553, 295 (2018)
  6. Zeino A, et al., J. Mol. Liq., 250, 50 (2018)
  7. Yang L, et al., Corrosion Sci., 130, 85 (2018)
  8. Li XY, Bandyopadhyay P, Nguyen TT, Park OK, Lee JH, J. Membr. Sci., 547, 80 (2018)
  9. Pourhashem S, Vaezi MR, Rashidi A, Surf. Coat. Technol., 311, 282 (2017)
  10. Lu H, et al., ACS Appl. Mater. Interfaces, 9(4), 4034 (2017)
  11. Yang ZQ, Wang LD, Sun W, Li SJ, Zhu TZ, Liu W, Liu GC, Appl. Surf. Sci., 401, 146 (2017)
  12. Ramezanzadeh B, et al., J. Phys. Chem. C 121 (37) 20433.20450 (2017).
  13. Gupta RK, et al., RSC Adv., 7(62), 39063 (2017)
  14. Gupta RK, et al., Mater. Chem. Phys., 198, 369 (2017)
  15. Pourhashem S, et al., Prog. Org. Coat., 111, 47 (2017)
  16. Chen J, et al., Colloid Polym. Sci., 295(10), 1951 (2017)
  17. Aneja KS, et al., Flat Chem., 1, 11 (2017)
  18. Upadhyayula VK, et al., ACS Sustain. Chem. Eng., 5(3), 2656 (2017)
  19. Pourhashem S, et al., Surf. Coat. Technol., 317, 1 (2017)
  20. Hayatdavoudi H, Rahsepar M, J. Alloy. Compd., 727, 1148 (2017)
  21. Li D, Muller MB, Gilje S, Kaner RB, Wallace GG, Nat. Nanotechnol., 3(2), 101 (2008)
  22. Georgakilas V, Tiwari JN, Kemp KC, Perrnan JA, Bourlinos AB, Kim KS, Zboril R, Chem. Rev., 116(9), 5464 (2016)
  23. Gao W, Graphene Oxide, 61 (2015).
  24. Olajire AA, J. Mol. Liq., 248, 775 (2017)
  25. Tourabi M, et al., Prot. Met. Phys. Chem., 53(3), 548 (2017)
  26. Liao LL, et al., Corrosion Sci., 124, 167 (2017)
  27. Efil K, Obot I, Prot. Met. Phys. Chem., 53(6), 1139 (2017)
  28. Ghazoui A, et al., J. Alloy. Compd., 693, 510 (2017)
  29. Farahi A, et al., J. Alloy. Compd., 723, 1032 (2017)
  30. Sharifi Z, Pakshir M, Mohamadi S, J. Mater. Eng. Perform., 24(2), 664 (2015)
  31. Avci G, Chem. Phys., 112(1), 234 (2008)
  32. Yong-Ning W, et al., Biomed. Environ. Sci., 22(2), 95 (2009)
  33. Elayyachy M, Elkodadi M, Aouniti A, Ramdani A, Hammouti B, Malek F, Elidrissi A, Mater. Chem. Phys., 93(2-3), 281 (2005)
  34. Bentiss F, Lebrini M, Vezin H, Lagrenee M, Mater. Chem. Phys., 87(1), 18 (2004)
  35. Park BD, Riedl B, J. Appl. Polym. Sci., 77(4), 841 (2000)
  36. Tomita B, Hatono S, J. Appl. Polym. Sci., 16(10), 2509 (1978)
  37. Soulard C, Kamoun C, Pizzi A, J. Appl. Polym. Sci., 72(2), 277 (1999)
  38. Tohmura SI, Inoue A, Sahari SH, J. Wood Sci., 47(6), 451 (2001)
  39. Mahmood A, et al., Small, 14(49) (2018)
  40. Razmjooei F, et al., Carbon, 78, 257 (2014)
  41. Ma J, et al., Tribol. Int., 120, 233 (2018)
  42. Sun L, et al., RSC Adv., 2(10), 4498 (2012)
  43. Lee JW, Kob JM, Kim JD, Electrochim. Acta (85), 459 (2012).
  44. Zhang Y, et al., J. Mater. Chem., 22(14), 6575 (2012)
  45. Chang Y, et al., J. Power Sources (238), 492 (2013).
  46. Li M, et al., Carbon (86),197 (2015).
  47. Zhang H, Niu Y, Hu W, J. Colloid Interface Sci. (505), 32 (2017).
  48. Halstead WD, J. Appl. Chem., 20(4), 129 (1970)
  49. Rad AS, et al., J. Sulfur Chem., 37(2), 176 (2016)
  50. Li Y, et al., Carbon (99), 556 (2016).
  51. Karthika P, Rajalakshmi N, Dhathathreyan KS, J. Nanosci. Nanotechnol., 13(3), 1746 (2013)
  52. Magda A, et al., J. Serb. Chem. Soc., 75(7), 951 (2010)
  53. Bockris JM, Swinkels DAJ, J. Electrochem. Soc., 111(6), 736 (1964)
  54. Pei S, et al., Carbon, 48(15), 4466 (2010)
  55. Chen T, et al., Phys. Chem. Chem. Phys., 19(7), 5504 (2017)
  56. Flahaut D, et al., Fuel (202), 307 (2017).
  57. Wang C, et al., Carbon, 59, 537 (2013)
  58. Rosas JM, et al., Carbon, 50, 1523 (2012)
  59. Wu X, Radovic LR, Carbon, 44(1), 141 (2006)
  60. Zhang YJ, Mori T, Ye JH, Antonietti M, J. Am. Chem. Soc., 132(18), 6294 (2010)
  61. Ferreira ES, Giacomelli C, Giacomelli FC, Spinelli A, Mater. Chem. Phys., 83(1), 129 (2004)
  62. Ehsani A, Mahjani MG, Hosseini M, Safari R, Moshrefi R, Shiri HM, J. Colloid Interface Sci., 490, 444 (2017)
  63. El Hamdani N, Fdil R, Tourabi M, Jama C, Bentiss F, Appl. Surf. Sci., 357, 1294 (2015)
  64. El-Haddad MN, Fouda A, J. Mol. Liq., 209, 480 (2015)
  65. Trefalt G, Behrens SH, Borkovec M, Langmuir, 32(2), 380 (2015)
  66. Brown M, et al., Phys. Rev., 6(1) (2016)
  67. Kim YS, Kim JG, J. Ind. Eng. Chem., 70, 169 (2018)
  68. Ansari K, Quraishi M, Singh A, Corrosion Sci., 95, 62 (2015)
  69. Safak S, et al., Corrosion Sci., 54, 251 (2012)
  70. Kosari A, et al., Corrosion Sci., 78, 138 (2014)
  71. Sherif ESM, Appl. Surf. Sci., 292, 190 (2014)
  72. Ehsani A, Nasrollahzadeh M, Mahjani MG, Moshrefi R, Mostaanzadeh H, J. Ind. Eng. Chem., 20(6), 4363 (2014)
  73. Zadeh ARH, Danaee I, Maddahy MH, J. Mater. Sci. Technol., 29(9), 884 (2013)
  74. Hong S, et al., Corrosion Sci., 66, 308 (2013)
  75. Zhang HH, Pang XL, Zhou M, Liu C, Wei L, Gao KW, Appl. Surf. Sci., 356, 63 (2015)
  76. Barker R, et al., Corrosion, 71(1), 14 (2014)