PEDOT:PSS nanocomposite via partial intercalation of monomer into colloidal graphite prepared by in-situ polymerization

Seonho Hwang; No Il Park; Young Ju Choi; Seong Min Lee; Sang Yun Han; Dae-won Chung; Seunghyun Lee

Journal of Industrial and Engineering Chemistry, Vol.76, 116-121, August, 2019

DOI10.1016/j.jiec.2019.02.018 Export Citation

PEDOT:PSS nanocomposite via partial intercalation of monomer into colloidal graphite prepared by in-situ polymerization

Seonho Hwang, No Il Park, Young Ju Choi¹, Seong Min Lee¹, Sang Yun Han², Dae-won Chung^†, and Seunghyun Lee^{2, †}

Department of Polymer Engineering, College of Engineering, University of Suwon, Suwon, 18323, Republic of Korea
¹EverChemTech Co., Ltd., 38, Cheongwonsandan 7-gil, Mado-myeon, Hwaseong-si, 18543, Gyeonggi-do, Republic of Korea
²Department of Nanochemistry, Gachon University, Seongnam-Si, Republic of Korea

E-mail:,

We report a synthetic route to fabricate graphite-poly (3,4-ethylenedioxythiophene):poly (4-styrenesulfonate) (PEDOT:PSS) nanocomposite (GP) by partially intercalating aqueous oxidative 3,4-ethylenedioxythiophene (EDOT) monomers into colloidal graphite layers. The colloidal graphite was dispersed in EDOT solution by ultrasonication prior to in situ polymerization process, and the resulting materials were well dispersed in EDOT even after 48?h. It is assumed that graphite was surrounded by EDOT monomers on its surface or the monomers were partially intercalated in the edge side of colloidal graphite layers. The nanocomposites (GP) represents good stability of aqueous suspension and their structural and electrical properties were evaluated. This study provides a facile and potential method to develop nanocomposites based on water-soluble conducting polymers.

Keywords:PEDOT:PSS;EDOT;Colloidal graphite;Nanocomposite;In-situ polymerization;Partial intercalation

[References]

Groenendaal BL, Jonas F, Freitag D, Pielartzik H, Reynolds JR, Adv. Mater., 12(7), 481 (2000)
Liu R, Lee SB, J. Am. Chem. Soc., 130(10), 2942 (2008)
Liu R, Duay J, Lee SB, ACS Nano, 4, 4299 (2010)
Pack KI, Jeong CK, Kim NK, Lee KJ, Nano Convergence, 3, 12 (2016)
Kirchmeyer S, Reuter K, J. Mater. Chem., 15, 2077 (2005)
Hong WJ, Xu YX, Lu GW, Li C, Shi GQ, Electrochem. Commun., 10, 1555 (2008)
Yoo DH, Kim JH, Kim JH, Nano Res., 7, 717 (2014)
Xu YF, Wang Y, Liang JJ, Huang Y, Ma YF, Wan XJ, Chen YS, Nano Res., 2, 343 (2009)
Han YQ, Shen MX, Wu Y, Zhu JJ, Ding B, Tong H, Zhang XG, Synth. Met., 172, 21 (2013)
Trang LKH, Tung TT, Kim TY, Yang WS, Kim HK, Suh KS, Polym. Int., 61, 93 (2012)
Lee SB, Lee SM, Park NI, Lee SH, Chung DW, Synth. Met., 201, 61 (2015)
Dikin DA, Stankovich S, Zimney EJ, Piner RD, Dommett GHB, Evmenenko G, Nguyen ST, Ruoff RS, Nature, 448, 457 (2007)
Liu YZ, Li YF, Yang YG, Wen YF, Wang MZ, J. Nanosci. Nanotechnol., 11, 10082 (2011)
Kim TY, Tung TT, Lee TH, Kim JE, Suh KS, Chem. Asian J., 5, 256 (2010)
Fabretto M, Zuber K, Hall C, Murphy P, Griesser HJ, J. Mater. Chem., 19, 7871 (2009)
Ouyang J, Xu QF, Chu CW, Yang Y, Li G, Shinar J, Polymer, 45(25), 8443 (2004)
Garreau S, Louarn G, Buisson JP, Froyer G, Lefrant S, Macromolecules, 32(20), 6807 (1999)
Osterholm A, Lindfors T, Kauppila J, Damlin P, Kvarnstrom C, Electrochim. Acta, 83, 463 (2012)
Lindfors T, Boeva ZA, Latonen RM, RSC Adv., 4, 25279 (2014)
Farah AA, Rutledge SA, Schaarschmidt A, Lai R, Freedman JP, Helmy AS, J. Appl. Phys., 112, 113709 (2012)
Singh V, Arora S, Arora M, Sharma V, Tandon RP, Semicond. Sci. Technol., 29, 45020 (2014)
Chen CH, Torrents A, Kulinsky L, Nelson RD, Madou MJ, Valdevit L, LaRue JC, Synth. Met., 161, 2259 (2011)
Joe SH, Lee YK, Yang JW, Jung WG, Kim JY, Synth. Met., 162, 1279 (2012)
Zhou H, Yao W, Li G, Wang J, Lu Y, Carbon, 59, 495 (2013)

[Related Articles]

[1] Groenendaal BL, Jonas F, Freitag D, Pielartzik H, Reynolds JR, Adv. Mater., 12(7), 481 (2000)

[2] Liu R, Lee SB, J. Am. Chem. Soc., 130(10), 2942 (2008)

[3] Liu R, Duay J, Lee SB, ACS Nano, 4, 4299 (2010)

[4] Pack KI, Jeong CK, Kim NK, Lee KJ, Nano Convergence, 3, 12 (2016)

[5] Kirchmeyer S, Reuter K, J. Mater. Chem., 15, 2077 (2005)

[6] Hong WJ, Xu YX, Lu GW, Li C, Shi GQ, Electrochem. Commun., 10, 1555 (2008)

[7] Yoo DH, Kim JH, Kim JH, Nano Res., 7, 717 (2014)

[8] Xu YF, Wang Y, Liang JJ, Huang Y, Ma YF, Wan XJ, Chen YS, Nano Res., 2, 343 (2009)

[9] Han YQ, Shen MX, Wu Y, Zhu JJ, Ding B, Tong H, Zhang XG, Synth. Met., 172, 21 (2013)

[10] Trang LKH, Tung TT, Kim TY, Yang WS, Kim HK, Suh KS, Polym. Int., 61, 93 (2012)

[11] Lee SB, Lee SM, Park NI, Lee SH, Chung DW, Synth. Met., 201, 61 (2015)

[12] Dikin DA, Stankovich S, Zimney EJ, Piner RD, Dommett GHB, Evmenenko G, Nguyen ST, Ruoff RS, Nature, 448, 457 (2007)

[13] Liu YZ, Li YF, Yang YG, Wen YF, Wang MZ, J. Nanosci. Nanotechnol., 11, 10082 (2011)

[14] Kim TY, Tung TT, Lee TH, Kim JE, Suh KS, Chem. Asian J., 5, 256 (2010)

[15] Fabretto M, Zuber K, Hall C, Murphy P, Griesser HJ, J. Mater. Chem., 19, 7871 (2009)

[16] Ouyang J, Xu QF, Chu CW, Yang Y, Li G, Shinar J, Polymer, 45(25), 8443 (2004)

[17] Garreau S, Louarn G, Buisson JP, Froyer G, Lefrant S, Macromolecules, 32(20), 6807 (1999)

[18] Osterholm A, Lindfors T, Kauppila J, Damlin P, Kvarnstrom C, Electrochim. Acta, 83, 463 (2012)

[19] Lindfors T, Boeva ZA, Latonen RM, RSC Adv., 4, 25279 (2014)

[20] Farah AA, Rutledge SA, Schaarschmidt A, Lai R, Freedman JP, Helmy AS, J. Appl. Phys., 112, 113709 (2012)

[21] Singh V, Arora S, Arora M, Sharma V, Tandon RP, Semicond. Sci. Technol., 29, 45020 (2014)

[22] Chen CH, Torrents A, Kulinsky L, Nelson RD, Madou MJ, Valdevit L, LaRue JC, Synth. Met., 161, 2259 (2011)

[23] Joe SH, Lee YK, Yang JW, Jung WG, Kim JY, Synth. Met., 162, 1279 (2012)

[24] Zhou H, Yao W, Li G, Wang J, Lu Y, Carbon, 59, 495 (2013)