화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.95, 16-27, March, 2021
DOI10.1016/j.jiec.2020.12.027  Export Citation
Progress in Adsorption-Enhanced Hydrogenation of CO2 on Layered Double Hydroxide (LDH) Derived Catalysts
Xin Fang, Chuang Chen, He Jia, Yingnan Li, Jian Liu, Yisong Wang, Yanli Song, Tao Du†, and Liying Liu
  • State Environmental Protection Key Laboratory of Eco-Industry, School of Metallurgy, Northeastern University, Shenyang 110819, People’s Republic of China
E-mail:
It is acknowledged as a promising strategy to reduce excessive CO2 emissions by catalytic conversion to value-added chemicals, in which layered double hydroxide (LDH) derived catalysts play essential roles. In the present review, latest progresses were summarized to gain insights on this issue. LDH-derived catalysts can be prepared via various methods and possess favorable characteristics of reversible topotactic transformation for further development. Compared to conventional catalysts, they show specific advantages in specific surface area, metal element dispersion and active site distribution. Despite of distinguished LDH-derived catalysts applied in CO2 reduction reactions to methane, methanol, hydrocarbons, etc., state-of-art LDH-derived catalysts consisted of catalyst-adsorbent synergistic system are recently constructed to employ the surface CO2 adsorption boundary layer to increase the CO2 partial pressure near active sites for hydrogenation. The overall catalytic performance is thus promoted dramatically. Accordingly, the strategy of adsorption-enhanced hydrogenation is expected to facilitate the industrialization of CO2 hydrogenation and is instructive for catalyst design in future.
Keywords:LDH-derived catalysts;CO2 utilization;catalytic conversion;adsorption-enhanced hydrogenation
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