화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.105, 414-426, January, 2022
DOI10.1016/j.jiec.2021.09.042  Export Citation
Design of non-faradaic EDLC from plasticized MC based polymer electrolyte with an energy density close to lead-acid batteries
Shujahadeen B. Aziz1, 2, †, Rebar T. Abdulwahid1, 3, Mohd F. Z. Kadir4, Hewa O. Ghareeb5, Tansir Ahamad6, 7, and Saad M. Alshehri6
  • 1Hameed Majid Advanced Polymeric Materials Research Lab., Physics Department, College of Science, University of Sulaimani, Qlyasan Street, Sulaimani 46001, Kurdistan Regional Government, Iraq
  • 2Department of Civil Engineering, College of Engineering, Komar University of Science and Technology, Sulaimani 46001, Kurdistan Regional Government, Iraq
  • 3Department of Physics, College of Education, University of Sulaimani, Old Campus, Sulaimani 46001, Iraq
  • 4Centre for Foundation Studies in Science, University of Malaya, Kuala Lumpur 50603, Malaysia
  • 5Department of Chemistry, College of Science, University of Sulaimani, Qlyasan Street, Sulaimani 46001, Kurdistan Regional Government, Iraq
  • 6Department of Chemistry, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
  • 7Department of Materials Science, Korea University, Seoul 02841, Republic of Korea
E-mail:
The investigation of biodegradable polymer electrolyte for energy device applications is of great importance as a suitable alternative to the conventional electrolytes. This paper explores the employment of plasticized methylcellulose (MC)-based polymer electrolytes for energy storage EDLC device application with an energy density (46.29 Wh kg-1) close enough to lead-acid batteries. The results have shown that the inclusion of plasticizer can enhance the ionic conductivity to 1.17 x 10-3 S cm-1. It was found that the prepared polymer electrolyte was stable up to 2.1 V, which is sufficient to be employed as electrolyte and separator in fabrication of electrical double layer capacitor (EDLC). Both te and ti values have been quantified from the TNM measurements, where the ti values for the electrolytes containing 32 wt.% and 40 wt. % of glycerol plasticizer have been found as 0.963 and 0.802, respectively. The performance of the assembled EDLC was assessed using both cyclic voltammetry (CV) and charge-discharging responses. The absence of redox peaks is evidenced from the CV. The value of initial specific capacitance (Cspe) of the fabricated EDLC is 411.52 F g-1. The results achieved in this study can be considered as a breakthrough in EDLC devices.
Keywords:Plasticized electrolyte;MC;NaI;EEC modeling;Transport properties;EDLC device
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