고분자 첨가법에 의해 SnO2가 도핑된 TiO2 분말의 합성 및 광촉매 특성

정미원; 곽윤정; Miewon Jung; Yunjung Kwak

Journal of the Korean Industrial and Engineering Chemistry, Vol.17, No.5, 561-564, October, 2006

Export Citation

고분자 첨가법에 의해 SnO2가 도핑된 TiO2 분말의 합성 및 광촉매 특성

Synthesis and Photoactivity of SnO2 - Doped Anatase - Type TiO2 Powder Via Polymerization - Complex Route

정미원^†, 곽윤정

성신여자대학교 화학과

Miewon Jung^†, and Yunjung Kwak

Department of Chemistry, Sungshin Women’s University, Seoul, 136-742, Korea

E-mail:

초록

SnO2가 도핑된 아나타제형의 TiO2 분말을 tin (IV) bis (acetylacetonate) dichloride와 titanium diisopropoxide bis (acetyl- acetonate)를 출발물질로, polyethylene glycol (PEG)을 첨가하여 합성하였다. 반응과정에 대한 구조변화를 FT-IR로 추적하였고, 입자의 모양과 형태 및 결정의 구조는 FE-SEM과 XRD 분석기로 관찰하였다. 합성된 분말의 광촉매 효과는 환경오염물질로 indigo carmine (IC)을 선택하여 UV-visible 스펙트라로 관찰하였다.

SnO2-doped anatase type TiO2 powder was prepared by the polymerization complex route from tin(IV) bis (acetylacetonate) dichloride, titanium diisopropoxide bis (acetylacetonate) and polyethylene glycol (PEG) as a complexing agent. The structural changes of reaction mixture were monitored by fourier transform infarared (FT-IR) spectroscopy. The microstructure and morphology of gel powder were studied by field-emission scanning electron microscopy (FE-SEM) and X-ray diffractometry (XRD). The photocatalytic activity of these powders with the anatase structure was investigated by using indigo carmine solution.

Keywords:TiO2-SnO2;PEG;XRD;FE-SEM;photoactivity

[References]

Yu JC, Zhang L, Ho W, J. Photochem. Photobio., A148, 263 (2002)
Lichtenberger J, Amiridis MD, Catal., 223, 296 (2004)
Das D, Mishra HK, Dalai AK, J. Mol. Catal. A-Chem., A189, 271 (2002)
Yu JC, Tang HY, Wong SP, J. Photochem. Photobiol. A-Chem., 153, 211 (2002)
Li B, Wang X, Li L, Mater. Chem. Phys., 78, 187 (2002)
Hwang HJ, Moon JH, Maeda K, J. Am. Ceram. Soc., 83, 2852 (2000)
Jung M, Lee J, Kim H, J. Korean Ind. Eng. Chem., 16(1), 150 (2005)
Zhang J, Gao L, J. Solid State Chem., 177, 1425 (2004)
Chhor K, Bocquet JF, Pommier C, Mater. Chem. Phys., 32, 249 (1992)
Eppler RA, J. Am. Ceram. Soc., 70, C64 (1987)
Cullity BD, Elements of X-Ray Diffraction, p. 276 Adison- Wesley, Philippines (1978)
Vautier M, Guillard C, Herrmann JM, J. Catal., 201(1), 46 (2001)
Djaoued Y, Badilescu S, Ashrit PV, Robichaud J, J. Sol-Gel Sci. Technol., 24, 255 (2002)

[Referenced By]

[1] Yu JC, Zhang L, Ho W, J. Photochem. Photobio., A148, 263 (2002)

[2] Lichtenberger J, Amiridis MD, Catal., 223, 296 (2004)

[3] Das D, Mishra HK, Dalai AK, J. Mol. Catal. A-Chem., A189, 271 (2002)

[4] Yu JC, Tang HY, Wong SP, J. Photochem. Photobiol. A-Chem., 153, 211 (2002)

[5] Li B, Wang X, Li L, Mater. Chem. Phys., 78, 187 (2002)

[6] Hwang HJ, Moon JH, Maeda K, J. Am. Ceram. Soc., 83, 2852 (2000)

[7] Jung M, Lee J, Kim H, J. Korean Ind. Eng. Chem., 16(1), 150 (2005)

[8] Zhang J, Gao L, J. Solid State Chem., 177, 1425 (2004)

[9] Chhor K, Bocquet JF, Pommier C, Mater. Chem. Phys., 32, 249 (1992)

[10] Eppler RA, J. Am. Ceram. Soc., 70, C64 (1987)

[11] Cullity BD, Elements of X-Ray Diffraction, p. 276 Adison- Wesley, Philippines (1978)

[12] Vautier M, Guillard C, Herrmann JM, J. Catal., 201(1), 46 (2001)

[13] Djaoued Y, Badilescu S, Ashrit PV, Robichaud J, J. Sol-Gel Sci. Technol., 24, 255 (2002)