Li4Ti5O12 anode Powders were prepared by post-treatment of the precursor powders obtained by spray pyrolysis at various preparation conditions. The precursor powders had fine size, narrow size distribution, dense inner structure and homogeneous composition when the flow rate of the carrier gas and the preparation temperature were 101 min(-1) and 800 degrees C. The spherical shapes of the precursor powders obtained at the Optimum preparation conditions maintained after post-treatment at a temperature of 800 degrees C. The mean sizes of the Li4Ti5O12 powders were controlled by changing the concentrations of the spray solution. The initial discharge capacities and cycle properties of the Li4Ti5O12 powders were strongly affected by the preparation temperatures of the precursor powders. The optimum preparation temperature of the precursor powders was 800 degrees C when the flow rate of the carrier gas was 101 min(-1). The discharge capacities and cycle properties of the Li4Ti5O12 powders were not affected by flow rates of the carrier gas. The Li4Ti5O12 powders had good cycle properties irrespective of the concentrations of the spray solution. However, the Li4Ti5O12 powders obtained from the spray solutions with high concentration above 0.5 M had high discharge capacities than those obtained from the spray solutions with low concentration below 0.1 M. (C) 2008 Elsevier B.V. All rights reserved.