Immobilization of [Bmim+Tf2N-] hydrophobic ionic liquid on nano-silica-amine sorbent for implementation in solid phase extraction and removal of lead

Hassan M. Al-bishri; Tarek M. Abdel-Fattah; Mohamed E. Mahmoud

Journal of Industrial and Engineering Chemistry, Vol.18, No.4, 1252-1257, July, 2012

DOI10.1016/j.jiec.2012.01.018 Export Citation

Immobilization of [Bmim+Tf2N-] hydrophobic ionic liquid on nano-silica-amine sorbent for implementation in solid phase extraction and removal of lead

Hassan M. Al-bishri¹, Tarek M. Abdel-Fattah^{2, 3}, and Mohamed E. Mahmoud^{4, †}

¹Faculty of Science, Chemistry Department, King Abdullaziz University, P.O. Box 80205, Jeddah 21589, Saudi Arabia
²Applied Research Center, Jefferson National Lab, Newport News, VA 23606, USA
³Department of Molecular Biology and Chemistry, Christopher Newport University, Newport News, VA 23606, USA
⁴Faculty of Sciences, Chemistry Department, Alexandria University, P.O. Box 426, Ibrahimia 21321, Alexandria, Egypt

E-mail:

A method is described for highly efficient adsorptive removal of lead with a maximum metal capacity value of 1.300 mmol g^(-1) by using physically immobilized [Bmim+Tf2N-] on the surface of nano-silicaamine sorbent. Lead sorption was found to be highly dependent and controlled by several experimental factors. The effect of sorbent dose played a significant role by yielding the maximum lead adsorption capacity when 100 mg sorbent was used. The effect of lead concentration was examined by various adsorption isotherms. The potential applications for removal of Pb(II) were studied and the percentage recovery values were 99.0-100.0 ± 2.0-5.0%.

Keywords:Hydrophobic IL;Nano-silica;Lead;Solid phase extraction;Removal

[References]

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Ozcan AS, Gok O, Ozcan A, J. Hazard. Mater., 161(1), 499 (2009)
Harrison RM, Pollution Causes Effects and Control, 3rd ed., The Royal Society of Chemistry, London (1996)
World Health Organization, Guidelines for Drinking Water, WHO, Geneva (1993)
Heil DM, Samani Z, Hanson AT, Rudd B, Water Air Soil Pollut., 13, 77 (1999)
Zhang K, Cheung WH, Valix M, Chemosphere., 60, 1129 (2005)
Danish M, Hashim R, Rafatullah M, Sulaiman O, Ahmad A, Govind A, Clean-Soil Air Water., 39, 392 (2011)
Solener M, Tunali S, Ozcanc AS, Ozean A, Gedikbey T, Desalination, 223(1-3), 308 (2008)
Kang KC, Ju JH, Kim SS, Baik MH, Rhee SW, J. Ind. Eng. Chem., 17(3), 565 (2011)
Lee JY, Kwon TS, Baek K, Yang JW, J. Ind. Eng. Chem., 15(3), 354 (2009)
Shin EW, Choi HS, Nguyen-Phan TD, Chung JS, Kim EJ, J. Ind. Eng. Chem., 14(4), 510 (2008)
Jeon C, Kim JH, J. Ind. Eng. Chem., 15(6), 910 (2009)
Yan WL, Bai R, Water Res., 39, 688 (2005)
Song XL, Liu HY, Cheng L, Qu YX, Desalination, 255(1-3), 78 (2010)
Lalhruaitluanga H, Jayaram K, Prasad MNV, Kumar KK, J. Hazard. Mater., 175(1-3), 311 (2010)
Ozacar M, Sengil IA, Turkmenler H, Chem. Eng. J., 143(1-3), 32 (2008)
Mahmoud ME, Haggag SS, Chem. Eng. J., 171(1), 181 (2011)
Mahmoud ME, Hafez OF, Osman MM, Elmelegy E, Sep. Sci. Technol., 45(9), 1302 (2010)
Mahmoud ME, El-Essawi MM, Kholeif SA, Fathalla EMI, Anal. Chim. Acta., 525, 123 (2004)
Mahmoud ME, Kenawy IMM, Soliman EM, Hafez MA, Akl MAA Lashein RRA, Anal. Sci., 24, 381 (2008)
Manzoori JL, Amjadi M, Abulhassani J, Anal. Chim. Acta., 644, 48 (2009)
Martinis EM, Bert?n P, Altamirano JC, Hakala U, Wuilloud RG, Talanta., 80, 2034 (2010)
Bai H, Zhou Q, Xie G, Xiao J, Talanta., 80, 1638 (2010)
Heitzman H, Young BA, Rausch DJ, Rickert P, Stepinski DC, Dietz ML, Talanta., 69, 527 (2006)
Visser AE, Swatloski RP, Reichert WM, Mayton R, Sheff S, Wierzbicki A, Davis JH, Rogers RD Jr.,, Chem. Commun., 135 (2001)
Abdel-Fattah TM, Mahmoud ME, Chem. Eng. J., 172(1), 177 (2011)
Mahmoud ME, Al-Bishri HM, Chem. Eng. J., 166(1), 157 (2011)
Mahmoud ME, Desalination, 266(1-3), 119 (2011)
Soliman EM, Mahmoud ME, Ahmed SA, Talanta., 54, 243 (2001)
Huddleston JG, Visser AE, Reichert WM, Willauer HD, Broker GA, Rogers RD, Green Chem., 3, 156 (2001)
Mahmoud ME, Haggag SS, Hegazi AH, J. Colloid Interface Sci., 300(1), 94 (2006)
Benguella B, Benaissa H, Water Res., 36, 2463 (2002)
Limousin G, Gaudet JP, Charlet L, Szenknect S, Barthe` s V, Krimissa M, Appl. Geochem., 22, 249 (2007)
Yokozeki A, Kasprzak DJ, Shiflett MB, Phys. Chem. Chem. Phys., 9, 5018 (2007)
Hofft O, Bahr S, Kempter V, Langmuir, 24(20), 11562 (2008)

[Referenced By]

[1] Adriano DC, Trace Elements in the Terrestrial Environment, in: Springer.Verlag, New York (1986)

[2] Ozcan AS, Gok O, Ozcan A, J. Hazard. Mater., 161(1), 499 (2009)

[3] Harrison RM, Pollution Causes Effects and Control, 3rd ed., The Royal Society of Chemistry, London (1996)

[4] World Health Organization, Guidelines for Drinking Water, WHO, Geneva (1993)

[5] Heil DM, Samani Z, Hanson AT, Rudd B, Water Air Soil Pollut., 13, 77 (1999)

[6] Zhang K, Cheung WH, Valix M, Chemosphere., 60, 1129 (2005)

[7] Danish M, Hashim R, Rafatullah M, Sulaiman O, Ahmad A, Govind A, Clean-Soil Air Water., 39, 392 (2011)

[8] Solener M, Tunali S, Ozcanc AS, Ozean A, Gedikbey T, Desalination, 223(1-3), 308 (2008)

[9] Kang KC, Ju JH, Kim SS, Baik MH, Rhee SW, J. Ind. Eng. Chem., 17(3), 565 (2011)

[10] Lee JY, Kwon TS, Baek K, Yang JW, J. Ind. Eng. Chem., 15(3), 354 (2009)

[11] Shin EW, Choi HS, Nguyen-Phan TD, Chung JS, Kim EJ, J. Ind. Eng. Chem., 14(4), 510 (2008)

[12] Jeon C, Kim JH, J. Ind. Eng. Chem., 15(6), 910 (2009)

[13] Yan WL, Bai R, Water Res., 39, 688 (2005)

[14] Song XL, Liu HY, Cheng L, Qu YX, Desalination, 255(1-3), 78 (2010)

[15] Lalhruaitluanga H, Jayaram K, Prasad MNV, Kumar KK, J. Hazard. Mater., 175(1-3), 311 (2010)

[16] Ozacar M, Sengil IA, Turkmenler H, Chem. Eng. J., 143(1-3), 32 (2008)

[17] Mahmoud ME, Haggag SS, Chem. Eng. J., 171(1), 181 (2011)

[18] Mahmoud ME, Hafez OF, Osman MM, Elmelegy E, Sep. Sci. Technol., 45(9), 1302 (2010)

[19] Mahmoud ME, El-Essawi MM, Kholeif SA, Fathalla EMI, Anal. Chim. Acta., 525, 123 (2004)

[20] Mahmoud ME, Kenawy IMM, Soliman EM, Hafez MA, Akl MAA Lashein RRA, Anal. Sci., 24, 381 (2008)

[21] Manzoori JL, Amjadi M, Abulhassani J, Anal. Chim. Acta., 644, 48 (2009)

[22] Martinis EM, Bert?n P, Altamirano JC, Hakala U, Wuilloud RG, Talanta., 80, 2034 (2010)

[23] Bai H, Zhou Q, Xie G, Xiao J, Talanta., 80, 1638 (2010)

[24] Heitzman H, Young BA, Rausch DJ, Rickert P, Stepinski DC, Dietz ML, Talanta., 69, 527 (2006)

[25] Visser AE, Swatloski RP, Reichert WM, Mayton R, Sheff S, Wierzbicki A, Davis JH, Rogers RD Jr.,, Chem. Commun., 135 (2001)

[26] Abdel-Fattah TM, Mahmoud ME, Chem. Eng. J., 172(1), 177 (2011)

[27] Mahmoud ME, Al-Bishri HM, Chem. Eng. J., 166(1), 157 (2011)

[28] Mahmoud ME, Desalination, 266(1-3), 119 (2011)

[29] Soliman EM, Mahmoud ME, Ahmed SA, Talanta., 54, 243 (2001)

[30] Huddleston JG, Visser AE, Reichert WM, Willauer HD, Broker GA, Rogers RD, Green Chem., 3, 156 (2001)

[31] Mahmoud ME, Haggag SS, Hegazi AH, J. Colloid Interface Sci., 300(1), 94 (2006)

[32] Benguella B, Benaissa H, Water Res., 36, 2463 (2002)

[33] Limousin G, Gaudet JP, Charlet L, Szenknect S, Barthe` s V, Krimissa M, Appl. Geochem., 22, 249 (2007)

[34] Yokozeki A, Kasprzak DJ, Shiflett MB, Phys. Chem. Chem. Phys., 9, 5018 (2007)

[35] Hofft O, Bahr S, Kempter V, Langmuir, 24(20), 11562 (2008)