Apatite silicates have recently been reported as promising electrolyte materials for intermediate temperature solid oxide fuel cells (IT-SOFCs). In this work, a series of apatite-type compounds La9.67Si6-xAlxO26.5-x/2 (LSAO) with x=0-2 are synthesized by the sol-gel process at calcining temperature of 800-900 degrees C. Thermal expansion coefficient, relative density and electrical conductivity of these samples with different Al doped contents are investigated. A symmetrical cell, which is composed of La9.67Si5AlO26 electrolyte and (La0.74Bi0.10Sr0.16)MnO3+delta (LBSM) cathode, is fabricated and electrochemically characterized. LBSM cathode shows a good electrochemical performance, which proves LBSM to be a promising candidate cathode for LSAO-based electrolyte. (C) 2011 Elsevier B.V. All rights reserved.