학회 |
한국화학공학회 |
학술대회 |
2022년 봄 (04/20 ~ 04/23, 제주국제컨벤션센터) |
권호 |
28권 1호, p.884 |
발표분야 |
[주제 4] 탄소중립(CCUS) |
제목 |
The Role of Phase in NiMgAl Mixed Oxide Catalysts for Methane Dry Reforming of CO2 |
초록 |
The effect of the spinel and periclase phase support on the dry reforming of methane was checked by a series of Ni/Mg/Al mixed oxide catalysts with different ratios of Mg/Al. The ratio of two phases periclase/spinel increases with the ratio of Mg/Al. The sample with the ratio Mg/Al = 1.5 has both phases spinel (Mg-rich) and periclases with the distribution of all Ni, Mg, Al in two phases, and these phases are defective with the small crystalline size. Compared to the samples composed of only the spinel phase or the periclase phase, the presence of both defective phases can enhance the reducibility and the basicity of the catalyst, which act a key role in activating the reaction. As the result, the sample with the ratio of Mg/Al = 1.5 has the highest activity with longer stability and better coke resistance. |
저자 |
Nguyen Phu Huy1, 김태협1, 김영찬1, 강기혁2, 조형태3, 김정환3, 노인수1
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소속 |
1서울과학기술대, 2한국화학(연), 3한국생산기술(연) |
키워드 |
촉매(Catalyst) |
E-Mail |
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원문파일 |
초록 보기 |