화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2022년 봄 (04/20 ~ 04/23, 제주국제컨벤션센터)
권호 28권 1호, p.827
발표분야 [주제 4] 탄소중립(CCUS)
제목 Biogas upgrading process using MDEA/AMP & MEA/AMP blended amines
초록 This paper reports the newly measured experimental data for CO2 solubility in a blended aqueous solution of and methyldiethanolamine (MDEA) / 2-amino-2-methyl propanol amine (AMP) and monoethanol amine (MEA) / AMP at different amine mixing ratios (Amine1:Amine2:H2O = 9:21:70, 15:15:70, and 21:9:70 wt%) and working temperatures (323.15-383.15 K). Aspen plus solubility data was regress to experimental data through aspen plus and MATLAB interworking. The importance of electrolyte pair parameters in e-NRTL was identified through gross sensitivity analysis by Monte Carlo simulation. For computational efficiency, only a minimum number of parameters were used in the simulation. Using the above mentioned model, the partial pressures of CO2 in the gas phase, mole fractions of all components in the liquid phase, cyclic capacities of CO2 according to the absorption/desorption temperature and the blending ratio of mixed amines were estimated. And biogas upgrading process was optimized by multi-objective optimization used Genetic algorithm.
저자 문지훈1, devkota sijan1, 신범주1, 강태하1, 이웅2, 김경민3, 문종호1
소속 1충북대, 2kist, 3강릉원주
키워드 분리기술(Separation Technology)
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