Based on the conventional interconnect La0.7Ca0.3CrO3-delta, a novel ceramic interconnect for intermediate temperature solid oxide fuel cells was developed. In the air, the electrical conductivities of La0.7Ca0.3CrO3-delta + 5%Ce0.8Sm0.2O1.9 at 600, 700 and 800 degrees C were 96.7, 146.3 and 687.8 S cm(-1), respectively, which increased significantly as compared with La0.7Ca0.3CrO3-delta under the same conditions. Similarly, in pure hydrogen, La0.7Ca0.3CrO3-delta + 3%Ce0.8SM0.2O1.9 possessed the maximal electrical conductivities which were 4.2, 5.3 and 7.1 S cm(-1), respectively at 600, 700 and 800 degrees C. The crystal structures Of La0.7Ca0.3CrO3-delta, La0.7Ca0.3CrO3-delta + 5%Ce0.8SM0.2O1.9 and La0.7Ca0.3CrO3-delta + 10%Ce-0.8 Sm0.2O1.9 were single phase with hexagonal symmetry, cubic phase plus some doped ceria impurity and orthorhombic phase plus some doped ceria impurity, respectively. The difference between the crystal structures may account for the difference between the electrical conductivities. The electrical conductivities and sinterability, of La0.7Ca0.3CrO3-delta were increased by introducing Ce0.8Sm0.2O1.9, whereas the other properties were not influenced. (C) 2008 Elsevier Ltd. All rights reserved.