We report direct encapsulation of a sustainable solvent system in silica microcapsules via a sol-gel reaction of silica precursor for potential application of thermoplastic self healing polymeric system. The silica microcapsules were realized by hydrolysis and condensation of tetraethyl orthosilicate (TEOS) using aqueous glycerol microemulsion as template. The pre-hydrolysis of TEOS was found to be useful to obtain isolated free flowing silica microcapsules. Furthermore, the effects of different parameters viz. temperature, rotor speed, the solvent/TEOS ratio on the synthesis of silica microcapsules are studied. A novel micro compression technique to study mechanical properties of the silica microcapsules is reported. The silica microcapsules reported were found to have better mechanical properties compared to incumbent Urea-Formaldehyde (UF) based organic microcapsules. (C) 2011 Elsevier Ltd. All rights reserved.