Thin Solid Films, Vol.517, No.5, 1624-1629, 2009
The influence of dispersing and stabilizing of indium tin oxide nanoparticles upon the characteristic properties of thin films
Stable suspensions of indium tin oxide nanoparticles were prepared by dispersing for 1 h in ethanol and stabilizing with 2-[2-(2-Methoxyethoxy)ethoxy]acetic acid. Particle size, morphology. and structure were characterized by a combination of dynamic light scattering, high resolution transmission electron microscopy, and X-ray diffraction. Spin coating of the stable suspensions resulted in densely packed films with a high transparency. Dispersing times exceeding 1 h led to a significant "overdispersing" effect, i.e. an increasing aggregate size of the suspensions was observed. Zeta-potential, pH, and X-ray photoelectron spectroscopy measurements were conducted to achieve a detailed understanding of the effect of "overdispersing". With an increasing time of dispersion, i.e. with a decreasing stability of the suspensions, the thin films fabricated by spin coating displayed an increasing pore size distribution and surface roughness. In addition a strong decrease in transmittance and in conductivity was observed. (C) 2008 Elsevier B.V. All rights reserved.
Keywords:Indium tin oxide;ITO;Nanoparticles;Dispersion;Stability;Thin films;Morphology;Transmittance;Conductivity