유기 템플레이트 배제하의 ZSM-5 결정화에 따른 영향인자

김화중; 임창환; 이승애; 이명철; 정찬이

Journal of the Korean Industrial and Engineering Chemistry, Vol.4, No.4, 776-784, December, 1993

Export Citation

유기 템플레이트 배제하의 ZSM-5 결정화에 따른 영향인자

Influencing Factors on the Crystallizations of ZSM-5 in the Absence of Organic Template

김화중, 임창환, 이승애, 이명철, 정찬이

초록

유기 템플레이트인 TPA⁺ 이온의 배제 하에 pentasil 계열의 제올라이트인 ZSM-5를 210℃에서 합성하였다. 본 연구에서 얻어진 결론에 의하면 유기 템플레이트가 사용되지 않는 합성조건 하에서는 기존의 방법으로는 합성이 되지 않는 것을 알 수 있었다. 결과에 의하면 유기 템플레이트 배제 하에서 ZSM-5의 결정화 반응에 적합한 조성영역은 매우 좁고 Na₂O/SiO₂ 및 SiO₂/Al₂O₃ 몰비 조절에 세심한 주의를 요해야 하는 것을 보여주고 있다. 이외에도 ZSM-5 결정화 반응에 미치는 혼합방법, 숙성 및 반응시간의 영향이 매우 큰 것을 알 수 있었다.

A pentasil zeolite, ZSM-5 was synthesized in the absence of organic template, TPA⁺ ion at 210℃. It was realized that a conventional method can not be applied to the synthesis system where organic templates are not used. The results indicated that the compositional range for the crystallization of ZSM-5 is very narrow, requiring very careful controls in the Na₂O/SiO₂ and SiO₂/Al₂O₃ ratios. In addition, the results showed that the effects of mixing method, aging and reaction time on the crystallization of ZSM-5 were extraordinarily significant.

[References]

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Hagawara H, Kiyozumi Y, Kurita M, Shimada H, Suzuki K, Shi S, Nishijima A, Todo S, Chem. Lett., 1653 (1981)
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Mostowicz R, Sand LB, Zeolites, 3, 57 (1982)
Avell KJ, Masters AF, Wilshier KG, Zeolites, 2, 299 (1982)
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[1] Argauer RJ, Landolt GR, U.S. Patent, 3,702,886 (1972)

[2] Grose RW, Flanigen EM, U.S. Patent, 4,061,724 (1977)

[3] Flanigen EM, Bennet JM, Grose RW, Cohon JP, Patton RL, Kirchner RM, RandSmith JV, Nature, 271, 512 (1978)

[4] Perline BP, U.S. Patent, 4,100,262 (1978)

[5] Erdem A, Sand LB, J. Catal., 60, 241 (1979)

[6] Sand LB, Pure Appl. Chem., 52, 2105 (1980)

[7] Derouane EG, Detremmerie S, Gabelica Z, Blom N, Appl. Catal., 1, 202 (1981)

[8] Berrer RM, Zeolites, 1, 130 (1981)

[9] Nakamoto M, Takahasi H, Chem. Lett., 169 (1981)

[10] Hagawara H, Kiyozumi Y, Kurita M, Shimada H, Suzuki K, Shi S, Nishijima A, Todo S, Chem. Lett., 1653 (1981)

[11] Ballmoos RV, Nature, 289, 782 (1981)

[12] Mostowicz R, Sand LB, Zeolites, 3, 57 (1982)

[13] Avell KJ, Masters AF, Wilshier KG, Zeolites, 2, 299 (1982)

[14] Derouane EG, Nagy JB, Gabelica Z, Blom N, Zeolites, 2, 299 (1982)

[15] 과학신문 제 517호, 3월호 (1993)

[16] Flanigen EM, Adv. Chem. Soc., 121, 119 (1973)

[17] Rollmann LD, "Inorganic Compounds with Unusual Properties," Eds. R.B. King, Vol. II, 387, ACS, New York (1979)

[18] Gabelica Z, Derouane EG, Blom N, Appl. Catal., 5, 109 (1983)

[19] Wadlinger RL, Kerr GT, Rosinski EJ, U.S. Patent, 3,308,069 (1967)

[20] Barrer RM, Denny PJ, J. Chem. Soc., 971 (1961)

[21] Barrer RM, Denny PJ, Flanigen EM, U.S. Patent, 3,306,922 (1967)

[22] Dwyer YN, Jenkins EE, U.S. Patent, 3,941,871 (1976)

[23] Chen YN, Miale NJ, Readan JW, U.S. Patent, 4,112,156 (1978)

[24] Chu P, Woodbury NJ, U.S. Patent, 3,709,979 (1973)

[25] Kalkarmi SB, Shitalkar VB, Katasthane AN, Borade RB, Datunasamg P, Zeolites, 2, 133 (1982)

[26] Borade RB, Chandrankar AJ, Kulkarni SB, Ind. J. Technol., 21, 358 (1983)

[27] Rubin MK, Rosinski EJ, Plank CP, U.S. Patent, 4,151,189 (1979)

[28] Rollmann LD, Valyocsik EW, U.S. Patent, 4,108,881 (1978)

[29] Rollmann LD, Valyocsik EW, U.S. Patent, 4,139,600 (1979)

[30] Marosi L, Schwarzmann M, Stabenow J, European Patent, Appl., 49,386 (1982)

[31] Whittam TV, European Patent, Appl., 54,886 (1982)

[32] Casci JL, Lowe BM, Whittam TV, European Patent, Appl., 42,225 (1981)

[33] Plank CJ, Rosinski EJ, Rubin MK, U.S. Patent, 4,175,114 (1979)

[34] Postand MFM, Nanne JM, UK Patent, 2,018,232 (1979)

[35] Marosi L, Schlimper H, European Patent, Appl., 41,621 (1981)

[36] Iwayama K, Kamano T, Tada K, Inoue T, European Patent, Appl., 57,016 (1982)

[37] Araya A, Lowe BM, Zeolites, 6, 111 (1986)

[38] Valyocsik EW, Rollmann LD, Zeolites, 5, 123 (1985)

[39] Araya A, Lowe BM, J. Chem. Soc.-Chem. Commun., 1455 (1987)

[40] Chen NY, Lucki SJ, Garwood WE, U.S. Patent, 3,700,585 (1972)

[41] Grose RW, Flanigen EM, U.S. Patent, 4,257,885 (1981)

[42] Nastro A, Colella C, Aiello R, "Studiesin Surface Science and Catalysis 24-Zeolites: Synthesis, Structure, Technology and Application," 39-46, Elsevier, Amsterdam (1985)

[43] Berak JM, Mostowics R, "Studiesin Surface Science and Catalysis 24-Zeolites: Synthesis, Structure, Technology and Application," 47-54, Elsevier, Amsterdam (1985)

[44] Jacops PA, "Synthesis of High-Silica Alumino-Silicate Zeolite, Stud. Surf. Sci. Catal.," 33, Elsevier, Amsterdam (1987)

[45] Dai FY, Suzuki M, Takahashi H, Saito Y, "Zeolite Synthesis," Eds. M.L. Occelliand H.E. Robson, No. 398, Chapter 18, ACS Symp. Ser. (1989)

[46] Schwieger W, Bergk KH, Freude D, Hunger M, Pfeifer H, "Zeolite Synthesis," Eds. M.L. Occelliand H.E. Robson, No. 398, Chapter 18, ACS Symp. Ser. (1989)

[47] Sato T, Ruch R, "Stabilization of Colloidal Dispersion," Academic Press, New York (1983)

[48] Napper DH, "Polymeric Stabilization of Colloidal Dispersion," Academic Press, New York (1983)

[49] Tianyou S, Ruren X, Liyun L, Zhaohui Y, "The Templating Effect during the Formation of ZSM-5 Type Zeolite," Seventh Int'l. Conf. on Zeolites, Tokyo, 201 (1986)

[50] Barrer RM, "Hydrothermal Chemistry of Zeolites," P108, Academic Press, London (1982)