화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 1566-1570, July, 2014
DOI10.1016/j.jiec.2013.07.048  Export Citation
Application of impregnation combustion method for fabrication of nanostructure CuO/ZnO composite oxide: XRD, FESEM, DRS and FTIR study
Mohammad Hossein Habibi†, and Bahareh Karimi
  • Nanotechnology Laboratory, Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Islamic Republic of Iran
E-mail:
Nanostructured CuO/ZnO composite oxide was prepared by a novel impregnation combustion method using copper nitrate and zinc oxide tetrapod. The X-ray diffraction patterns revealed that CuO/ZnO composite oxide was formed. The effects of different impregnation combustion parameters on the properties of composite were studied by field-emission scanning electron microscope (FESEM), powder X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR) and UV-vis diffuse reflectance spectrum (DRS). The synthesis of ZnO-CuO nanocomposites through impregnation of a zinc oxide tetrapod with copper nitrate aqueous sodium carbonate solutions is reported. During thermal treatment the samples evolve toward the formation of nanocrystalline ZnO particles (zincite phase) dispersed onto tenorite, CuO annealed at 450 ℃. XRD patterns of the precursors calcined at 450 ℃ showed the formation of the zincite-tenorite phases. Field emission scanning electron microscopy (FESEM) exhibited loosely agglomerated hexagonal particles with uniform morphology having a size around 50 nm.
Keywords:Impregnation technique;CuO/ZnO;Zincite;Tenorite
  1. Sathishkumar P, Sweena R, Wu JJ, Anandan S, Chem. Eng. J., 171(1), 136 (2011)
  2. Habibi MH, Sheibani R, J. Ind. Eng. Chem., 19(1), 161 (2013)
  3. Chen CZ, Zhou ZW, J. Funct. Mater., 35(1), 97 (2004)
  4. Habibi MH, Askari E, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.01.003 (2013)
  5. Habibi MH, Habibi AH, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.04.025 (2013)
  6. Habibi MH, Mikhak M, Zendehdel M, Habibi MH, Int. J. Electrochem. Sci., 7, 6787 (2012)
  7. Di Paola A, Palmisano L, Augugliaro V, Catal. Today, 58(2-3), 141 (2000)
  8. Bessekhouad Y, Robert D, Weber JV, J. Photochem. Photobiol. A-Chem., 163, 569 (2004)
  9. Hernandez A, Maya L, Mora ES, Sanchez EM, J. Sol-Gel Sci. Technol., 42, 71 (2007)
  10. Irimpan L, Krishnan B, Nampoori VPN, Radhakrishnan P, J. Colloid Interface Sci., 324(1-2), 99 (2008)
  11. Zhang D, Transit. Met. Chem., 35, 689 (2010)
  12. Zhang DF, Zeng FB, Appl. Surf. Sci., 257(3), 867 (2010)
  13. Zhang ZH, Yuan Y, Fang YJ, Liang LH, Ding HC, Jin LT, Talanta, 73, 523 (2007)
  14. Wang C, Wang XM, Xu BQ, Zhao JC, Mai BX, Peng PA, Sheng G, Fu J, J. Photochem. Photobiol. A-Chem., 168, 47 (2004)
  15. Sakthivel S, Geissen SU, Bahnemann DW, Murugesan V, Vogelpohl A, J. Photochem. Photobiol. A-Chem., 148, 283 (2002)
  16. Li D, Haneda H, J. Photochem. Photobiol. A-Chem., 160, 203 (2003)
  17. Heo JH, Ryu H, Lee WJ, J. Ind. Eng. Chem, http://dx.doi.org/10.1016/j.jiec.2013.02.001 (2013)
  18. Habibi MH, Askari E, J. Therm. Anal. Calorim., 111, 227 (2013)
  19. Cannas C, Casu M, Musinu A, Lai A, Piccaluga G, J. Mater. Chem., 9, 1765 (1999)
  20. Habibi MH, Askari E, J. Adv. Oxid. Technol., 14, 190 (2011)
  21. Habibi MH, Askari E, Synth. React. Inorg. Met.-Org. Chem., 43, 406 (2013)
  22. Habibi MH, Habibi AH, J. Therm. Anal. Calorim., http://dx.doi.org/10.1007/s10973-012-2830-4 (2013)
  23. Habibi MH, Askari E, Habibi M, Zendehdel M, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 104, 197 (2013)
  24. Habibi MH, Habibi AH, Zendehdel M, Habibi M, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 110, 226 (2013)
  25. Zhang WH, Shi JL, Wang LZ, Yan DS, Chem. Mater., 12, 1408 (2000)
  26. Lai CW, Sreekantan S, Electrochim. Acta, 87, 294 (2013)
  27. Nah YC, Paramasivam I, Schmuki P, ChemphysChem, 11, 2698 (2010)
  28. Yerga RMN, Galvan MCA, del Valle F, Villoria de la Mano JA, Fierro JLG, ChemSusChem, 2, 471 (2009)
  29. Bang JH, Kamat PV, Adv. Funct. Mater., 20(12), 1970 (2010)
  30. Zhang J, Bang JH, Tang C, Kamat PV, ACS Nano, 4, 387 (2010)
  31. Kim H, Kim J, Kim W, Choi W, J. Phys. Chem. C, 115, 9797 (2011)
  32. Costi R, Saunders AE, Banin U, Ang. Chem. Inter. Ed., 49, 2 (2010)
  33. Xiao MW, Wang LS, Huang XJ, Wu YD, Dang Z, J. Alloy. Compd., 470, 486 (2009)
  34. Hathway T, Rockafellow EM, Oh YC, Jenks WS, J. Photochem. Photobiol. A-Chem., 207, 197 (2009)
  35. Paramasiam I, Nah YC, Das C, Shrestha NK, Schmuki P, Chem. A Eur. J., 16, 8993 (2010)
  36. Wang J, Han YH, Feng MZ, Chen JZ, Li XJ, Zhang SQ, J. Mater. Sci., 46(2), 416 (2011)
  37. Kim DS, Yang JH, Balaji S, Cho HJ, Kim MK, Kang DU, Djaoued Y, Kwon YU, CrystEngComm, 11, 1621 (2009)
  38. Leghari SAK, Sajjad S, Chen F, Zhang JL, Chem. Eng. J., 166(3), 906 (2011)
  39. Sajjad AKL, Shamaila S, Tian BZ, Chen F, Zhang JL, J. Hazard. Mater., 177(1-3), 781 (2010)
  40. Couselo N, Einschlag FSG, Candal RJ, Jobbagy M, J. Phys. Chem. C, 112, 1094 (2008)
  41. Yang LX, Xiao Y, Liu SH, Li Y, Cai QY, Luo SL, Zeng GM, Appl. Catal. B: Environ., 94(1-2), 142 (2010)
  42. Smith W, Zhao YP, Catal. Commun., 10, 1117 (2009)
  43. Pan JH, Lee WI, Chem. Mater., 18, 847 (2006)
  44. Song YY, Gao ZD, Wang JH, Xia XH, Lynch R, Adv. Funct. Mater., 21(10), 1941 (2011)
  45. Liu ZL, Deng JC, Deng JJ, Li FF, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 150, 99 (2008)
  46. Zheng DF, Pol. J. Chem., 83, 2009 (2009)
  47. Eswaramoorthi I, Sundaramurthy V, Dalai AK, Appl. Catal. A: Gen., 313(1), 22 (2006)
  48. Yang HC, Chang FW, Roselin LS, J. Mol. Catal. A-Chem., 276(1-2), 184 (2007)
  49. Yoon DH, Yu JH, Choi GM, Sens. Actuators B-Chem., 46, 15 (1998)
  50. Hu Y, Zhou XH, Han Q, Cao QX, Huang YX, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 99, 41 (2003)
  51. Dai Y, Zhang Y, Li QK, Nan CW, Chem. Phys. Lett., 358(1-2), 83 (2002)
  52. Yan HQ, He RR, Pham J, Yang PD, Adv. Mater., 15(5), 402 (2003)
  53. Marcus CN, Firth S, Matsuura T, Paul AW, J. Phys. Conf. Ser., 26, 251 (2006)
  54. Li B, Wang Y, Superlattices Microstruct., 47, 615 (2010)
  55. Liu ZL, Deng JC, Deng JJ, Li FF, Sci. Eng. B, 150, 99 (2008)
  56. Wang JX, Sun XW, Yang Y, Akyaw KK, Huang XY, Yin JZ, Wei J, Demir HV, Nanotechnology, 22, 325704 (2011)
  57. Ahn KS, Deutsch T, Yan Y, Jiang CS, Perkins CL, Turner J, Jassim MA, J. Appl. Phys., 102, 023517 (2007)
  58. Sanchez E, Lopez T, Mater. Lett., 25, 271 (1995)
  59. Pankove JI, Optical Properties in Semiconductors, Prentice Hall, Englewood Cliffs, NJ, 1971.