Determination of calcium carbonate and styrene-butadiene latex content in the coating layer of coated paper

Huan Zhao; Qingxi Hou; Yimei Hong; Wei Liu; Yang Li; Fang Tong

Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 1571-1576, July, 2014

DOI10.1016/j.jiec.2013.07.049 Export Citation

Determination of calcium carbonate and styrene-butadiene latex content in the coating layer of coated paper

Huan Zhao, Qingxi Hou^†, Yimei Hong^†, Wei Liu, Yang Li, and Fang Tong

Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science & Technology, Tianjin 300457, China

E-mail:,

The surface infrared spectra of coated paper with different levels of calcium carbonate and SB-latex in the coating layer were measured using ATR-FTIR. The relations between different levels of CaCO3 and SBlatex and their respective characteristic peak areas were then established. The results show that the general regression neural network (GRNN) model can be used to estimate the CaCO3 and SB-latex contents in coatings of coated papers. The maximum errors for calcium carbonate and SB-latex were only 3.32% and 3.39%, respectively, and occurred under conditions that are at the extreme of what might be encountered in an actual production facility.

Keywords:Coated paper;Styrene-butadiene latex;Attenuated total reflectance;Fourier transform infrared spectroscopy;Characteristic absorption peak

[References]

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Peraniemi S, Smolander K, Hakamaki A, Mustalahti H, Karttunen K, Papier, 47, 116 (1993)
Hong CZ, Ruan XG, Zeng SX, Chin. Pulp Paper, 11, 44 (1992)
Acholla F, Brown JT, Rohm RM, Company H, TAPPI J., 12, 5 (2009)
King ST, Shand AS, TAPPI J., 57, 51 (1974)
Dolmatova L, Ruckebusch C, Dupuy N, Huvenne JP, Legrand P, Chemometrics Intelligent Laboratory Systems, 36, 125 (1997)
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Hans KMC, Mueller S, Sigrist MW, Drug Test. Anal., 4, 420 (2012)
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Hawkins SA, Park B, Poole GH, Gottwald T, Windham WR, Lawrence KC, Appl. Spectrosc., 64, 100 (2010)
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Wang B, Yang HB, Wu YP, Chin. Synthetic Rubber Industry, 35, 2 (2012)
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Specht DF, IEEE Trans. Neural Networks, 2, 568 (1991)
Yu JM, Li M, Shu F, Proceeding of the CSU-EPSA, 21, 104 (2009)
Comp. Simulation, 20, 67 (2003)
Wang FL, Song Y, Comput. Simulation, 29, 184 (2012)
Zhao WL, Concrete, 2, 46 (2011)
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[Referenced By]

[1] Adams JM, Clay Clay Min., 28, 509 (1993)

[2] Dupuy N, Ruckebush C, Duponchel L, Beurdeley-Saudou P, Amram B, Huvenne JP, Legrand P, Anal. Chim. Acta, 335, 79 (1996)

[3] Kim-Habermehl LH, Roper III JA, Dewildt D, Jones S, Tappi 1999 Coating Conference Proceedings, TAPPI Press, Atlanta, 1999p. 1.

[4] Lai YM, Zhou YH, Luo X, Zhu XJ, Liu DH, Wu H, Ren RH, Paper Sci. Technol., 26, 20 (2007)

[5] Fujiwara H, Kline JE, TAPPI J., 70, 97 (1987)

[6] Brown SD, Bear RS, Blank TB, Anal. Chem., 64, 22R (1992)

[7] Sithole BB, Anal. Chem., 67, 87R (1995)

[8] Perkampus HH, Encyclopedia of Spectroscopy, VCH, New York, 1990.

[9] Stroem G, Carlsson G, Kiar M, Nord. Pulp Paper Res J, 8, 105 (1993)

[10] Peraniemi S, Smolander K, Hakamaki A, Mustalahti H, Karttunen K, Papier, 47, 116 (1993)

[11] Hong CZ, Ruan XG, Zeng SX, Chin. Pulp Paper, 11, 44 (1992)

[12] Acholla F, Brown JT, Rohm RM, Company H, TAPPI J., 12, 5 (2009)

[13] King ST, Shand AS, TAPPI J., 57, 51 (1974)

[14] Dolmatova L, Ruckebusch C, Dupuy N, Huvenne JP, Legrand P, Chemometrics Intelligent Laboratory Systems, 36, 125 (1997)

[15] Wong SF, Fourier Transform Infrared Spectroscopy, Electronic Industry Press, Beijing, 2005.

[16] Hans KMC, Mueller S, Sigrist MW, Drug Test. Anal., 4, 420 (2012)

[17] Kadamne JV, Castrodale CL, Proctor A, J. Agric. Food Chem., 59, 2190 (2011)

[18] Hawkins SA, Park B, Poole GH, Gottwald T, Windham WR, Lawrence KC, Appl. Spectrosc., 64, 100 (2010)

[19] Otto A, Korte EH, Microchimica Acta, 95, 141 (1988)

[20] Wang B, Yang HB, Wu YP, Chin. Synthetic Rubber Industry, 35, 2 (2012)

[21] Feisi technological product research center (Ed.), Neural Network and MATLAB7 Realization, Electronic Industry Press, Beijing, 2005, p. 89.

[22] Specht DF, IEEE Trans. Neural Networks, 2, 568 (1991)

[23] Yu JM, Li M, Shu F, Proceeding of the CSU-EPSA, 21, 104 (2009)

[24] Comp. Simulation, 20, 67 (2003)

[25] Wang FL, Song Y, Comput. Simulation, 29, 184 (2012)

[26] Zhao WL, Concrete, 2, 46 (2011)

[27] Vikman K, Sipi K, J. Imaging Sci. Technol., 47, 139 (2003)

[28] Huang HY, Yin QH, Grad J, Sun YAT-SEN University, China (Natural Sciences Medicine) 32 (2011) 20.

[29] 2000.2001 Tappi Test Methods, Tappi Press, Atlanta, 2002.

[30] Zhou ZZ, Farnood R, in: Proceedings of the 90st PAPTAC Annual Meeting, Montreal, Pulp and paper technological association of Canada (PAPTAC), (2004), p. 177.

[31] Feng JM, The Application of Infrared Spectroscopy in the Analysis of Trace Evidence, Chemical Industry Press, Beijing, 2010.

[32] Yu PF, Lu YM, Wei LP, Liang YJ, Su XB, Kong LZ, Lan ZB, Hubei Agricultural Sci., 50, 2135 (2011)