천연제올라이트의 상규명 및 아모니아 제거 특성

김화중; 유재철; 이명철; 이기정

Journal of the Korean Industrial and Engineering Chemistry, Vol.7, No.1, 43-50, February, 1996

Export Citation

천연제올라이트의 상규명 및 아모니아 제거 특성

A Study on the Phase Identification and Ion-Exchange Behavior of NH₄⁺ at Natural Zeolite

김화중, 유재철, 이명철, 이기정

초록

Clinoptilolite 계열의 국내산 천연제올라이트에 대한 상규명과 암모늄 이온 제거능력에 대해 연구하였다. 영일만 지역에 매장되어 있는 국내산 천연제올라이트는 XRD와 FT-IR 분석에 의해 열적으로 불안정한 heulandite임이 증명되었다. 또한 K⁺ 이온으로 이온교환된 heulandite가 가장 높은 열적 안정성을 보였다. 그러나 암모늄이온의 제거능력에 있어서는 이온교환하지 않은 제올라이트가 가장 우수한 제거능력을 보였다.

A series of domestic natural zeolites were investigated to identify the phase and to study the capability of NH₄⁺-ion removal from solution system. It was proved that the natural zeolite from Young-II bay area was thermally unstable zeolite, heulandite by XRD and FT-IR analyses. In addition, the heulandite exchanged by K⁺ ion showed the highest thermal stability upon heat-treatments. However, the best capability of removing NH₄⁺ -ion from the solution system was the non-exchanged zeolite.

[References]

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Dyer A, An Introduction to Zeolite Molecular Sieves, John Wiley and Sons (1989)
Czaran E, Meszaros-Kis A, Domokos E, Papp J, Acta Chim. Hung, 125, 201 (1988)
Uyama H, Kanzaki Y, Matsumoto O, Mater. Res. Bull., 22, 157 (1987)
Loizidou M, Townsend RP, J. Chem. Soc.-Dalton Trans., 1911 (1987)
Semmens MJ, Martin WP, Water Res., 22, 537 (1988)
Callahan CM, J. Inorg. Nucl. Chem., 28, 2743 (1966)
Vokacova M, Matejka Z, Eliasek J, Acta Hydrochem. Hydrobiol., 14, 605 (1986)
Renschler CL, Arnold C, J. Mater. Sci. Lett., 5, 1169 (1986)
Carrondo MJT, Perry R, Lester JN, J. Wat. Pollut. Control. Fed., 52, 2796 (1980)
Holman WF, Hopping WD, J. Wet. Pollut. Control. Fed., 52, 2887 (1980)
King JE, Hopping WD, Holman WF, J. Wet. Pollut. Control. Fed., 52, 2875 (1980)
Ishii M, Kaji K, Gypsum Lime, 186, 8 (1986)
Ames LL, J. Am. Miner., 45, 689 (1960)
Ames LL, J. Am. Miner., 46, 1120 (1961)
Ames LL, J. Am. Miner., 48, 868 (1961)
Mercer BW, Ames LL, Report USAEC, HW, 78, 461 (1963)
Breger IA, Chandler JC, Zubovic P, Am. Mineral., 55, 825 (1970)
Bray LA, Fullam HT, Adv. Chem. Ser., 101, 450 (1971)
Koon JH, Kaufman WJ, U.S. Report for the EPA (1971)
Ciambelli P, Corbo P, Porcelli C, Rimoli A, Zeolites, 5, 184 (1985)
Milligan WO, Weiser HB, J. Phys. Chem., 41, 1029 (1937)
Mumpton FA, Am. Mineral., 45, 351 (1960)
Barrer RM, Vaughan DEW, Surf. Sci., 14, 77 (1969)
Breger IA, Chandler JC, Zubovic P, Am. Mineral., 55, 825 (1970)
Kim WJ, Lee JI, J. Korean Ind. Eng. Chem., 4(3), 488 (1993)
이재익, 건국대학교 공과대학 공업화학과 석사학위논문, 24 (1993)

[1] Breck DW, "Zeolite Molecular Sieves," John Wiley & Sons (1974)

[2] Dyer A, An Introduction to Zeolite Molecular Sieves, John Wiley and Sons (1989)

[3] Czaran E, Meszaros-Kis A, Domokos E, Papp J, Acta Chim. Hung, 125, 201 (1988)

[4] Uyama H, Kanzaki Y, Matsumoto O, Mater. Res. Bull., 22, 157 (1987)

[5] Loizidou M, Townsend RP, J. Chem. Soc.-Dalton Trans., 1911 (1987)

[6] Semmens MJ, Martin WP, Water Res., 22, 537 (1988)

[7] Callahan CM, J. Inorg. Nucl. Chem., 28, 2743 (1966)

[8] Vokacova M, Matejka Z, Eliasek J, Acta Hydrochem. Hydrobiol., 14, 605 (1986)

[9] Renschler CL, Arnold C, J. Mater. Sci. Lett., 5, 1169 (1986)

[10] Carrondo MJT, Perry R, Lester JN, J. Wat. Pollut. Control. Fed., 52, 2796 (1980)

[11] Holman WF, Hopping WD, J. Wet. Pollut. Control. Fed., 52, 2887 (1980)

[12] King JE, Hopping WD, Holman WF, J. Wet. Pollut. Control. Fed., 52, 2875 (1980)

[13] Ishii M, Kaji K, Gypsum Lime, 186, 8 (1986)

[14] Ames LL, J. Am. Miner., 45, 689 (1960)

[15] Ames LL, J. Am. Miner., 46, 1120 (1961)

[16] Ames LL, J. Am. Miner., 48, 868 (1961)

[17] Mercer BW, Ames LL, Report USAEC, HW, 78, 461 (1963)

[18] Breger IA, Chandler JC, Zubovic P, Am. Mineral., 55, 825 (1970)

[19] Bray LA, Fullam HT, Adv. Chem. Ser., 101, 450 (1971)

[20] Koon JH, Kaufman WJ, U.S. Report for the EPA (1971)

[21] Ciambelli P, Corbo P, Porcelli C, Rimoli A, Zeolites, 5, 184 (1985)

[22] Milligan WO, Weiser HB, J. Phys. Chem., 41, 1029 (1937)

[23] Mumpton FA, Am. Mineral., 45, 351 (1960)

[24] Barrer RM, Vaughan DEW, Surf. Sci., 14, 77 (1969)

[25] Breger IA, Chandler JC, Zubovic P, Am. Mineral., 55, 825 (1970)

[26] Kim WJ, Lee JI, J. Korean Ind. Eng. Chem., 4(3), 488 (1993)

[27] 이재익, 건국대학교 공과대학 공업화학과 석사학위논문, 24 (1993)