전도성 고분자 복합체 제조를 위한 신합성 연구(II):중합변수에 따른 전도성 고분자 복합체의 전도도 변화

손석희; 박영준; 김중현

Journal of the Korean Industrial and Engineering Chemistry, Vol.7, No.6, 1061-1068, December, 1996

Process for the Preparation of Conducting Polymer Composites (Ⅱ) The Effect of Polymerization Parameters on Conductivity

손석희, 박영준, 김중현

초록

본 연구는 다공성 입자에 전도성 단량체를 침투시켜서 전도성 고분자 복합체를 제조하는 연구로 다단계 seed 중합법을 이용하여 입자를 제조하고, 용매추출법으로 선형 고분자를 제거하는 방법으로 specific pore volume 및 specific surface area가 각기 다른 다공성 입자를 제조하였고, 이 다공성 입자를 모체 고분자로 하여 도핑제를 산화용액에 녹여 흡수시키고 건조한 뒤 전도성 단량체를 유기용매에 녹여 다공성 입자에 침투시킨 후 중합하여 전도성 복합체를 제조 하였다. 이때, 모체 고분자에 침투되는 전도성 단량체의 농도 및 유기용매와 산화제의 산화용매 등을 중합 변수로하여 이 변수들과 전도도와의 상관 관계를 살펴보았다.

The conducting polymer composites were prepared by imbibing the porous particle wish the FeC1₃ oxidant solution, drying the imbibed porous particle, and imbibing again with pyrrole solution for polymerization to take place in the pore of porous particles. The effect of synthesis conditions on the conductivity of composite polymers were investigated. It was found that the conductivity of composite polymers was dependant on the concentration of pyrrole monomer, nature of the oxidants and solvents used for the oxidant and pyrrole, which influence the degree of penetration/distribution of polyprrole in the composite and reaction of dopant with pyrrole.

[References]

Kanatzidis MG, Chem. Eng. News, Dec.(3), 36 (1990)
Skotheim TJ, "Handbook of Conducting Polymers," Marcel Dekker, N.Y. (1968)
Alcacer L, "Conducting Polymers: Special Applications," Reidal. D., N.Y. (1987)
Bredar JL, Accounts Chem. Res., 8, 309 (1985)
Linford RG, "Electrochemical Science and Technology of Polymers-1," Elsevier, N.Y. (1987)
Armes SP, Vincent B, J. Chem. Soc.-Chem. Commun., 288 (1987)
Candau F, "Scientific Methods for the Study of Polymer Colloids and Their Application," p. 486, Kluwer Academic Publishers (1988)
Cotts DB, REyes Z, "Electrically Conductive Organic Polymers for Advanced Applications," Noyes (1986)
Kulkarni VG, Synth. Met., 1009, 41 (1991)
Beoman M, Armes SP, Colloid Polym. Sci., 271, 70 (1993)
Beadle P, Armes SP, Macromolecules, 25, 2526 (1992)
Merkel MP, "Morphology of Core/Shell Latexes and Thier Mechanical Properties," Ph.D. Thesis, Lehigh Univ. (1986)
Okubo M, Shiozaki M, Colloid Polym. Sci., 222, 222 (1991)
Cheng CM, Micale FJ, J. Colloid Interface Sci., 222, 2 (1992)
Digir ML, Bhattacharyyn SN, Polymer, 35, 2 (1991)
Rukenstein E, Park JS, J. Appl. Polym. Sci., 42, 925 (1991)
Rukenstein E, Chen JH, J. Appl. Polym. Sci., 43, 1209 (1991)
El-Aasser MS, "Advances in Emulsion Polymerization and Latex Technology," Lehigh Univ. (1992)
Cheng CM, Micale FJ, J. Polym. Sci. A: Polym. Chem., 30, 235 (1992)
Cheng CM, Vanderhoff JW, J. Polym. Sci. A: Polym. Chem., 30, 245 (1992)
Montgomery HC, J. Appl. Polym. Sci., 43, 2971 (1971)
Logan BF, J. Appl. Polym. Sci., 42, 2975 (1971)
Schimmel T, "Conjugated Polymers," Ed. by Bredas, J.L., p. 53, Kluwer Academic Publishers (1991)
Salaneck WR, "Conjugated Polymers and RElated Materials," Oxford University Press (1991)
Chance RR, "Handbook of Conducting Polymers," Ed. by Skotheim, T.J., p. 825, Marcel Dekker, N.Y. (1986)
Lee JK, Lee SH, Lim TH, J. Korean Ind. Eng. Chem., 2(4), 393 (1991)
Oh SY, Koh BC, J. Korean Ind. Eng. Chem., 6(6), 1108 (1995)

[1] Kanatzidis MG, Chem. Eng. News, Dec.(3), 36 (1990)

[2] Skotheim TJ, "Handbook of Conducting Polymers," Marcel Dekker, N.Y. (1968)

[3] Alcacer L, "Conducting Polymers: Special Applications," Reidal. D., N.Y. (1987)

[4] Bredar JL, Accounts Chem. Res., 8, 309 (1985)

[5] Linford RG, "Electrochemical Science and Technology of Polymers-1," Elsevier, N.Y. (1987)

[6] Armes SP, Vincent B, J. Chem. Soc.-Chem. Commun., 288 (1987)

[7] Candau F, "Scientific Methods for the Study of Polymer Colloids and Their Application," p. 486, Kluwer Academic Publishers (1988)

[8] Cotts DB, REyes Z, "Electrically Conductive Organic Polymers for Advanced Applications," Noyes (1986)

[9] Kulkarni VG, Synth. Met., 1009, 41 (1991)

[10] Beoman M, Armes SP, Colloid Polym. Sci., 271, 70 (1993)

[11] Beadle P, Armes SP, Macromolecules, 25, 2526 (1992)

[12] Merkel MP, "Morphology of Core/Shell Latexes and Thier Mechanical Properties," Ph.D. Thesis, Lehigh Univ. (1986)

[13] Okubo M, Shiozaki M, Colloid Polym. Sci., 222, 222 (1991)

[14] Cheng CM, Micale FJ, J. Colloid Interface Sci., 222, 2 (1992)

[15] Digir ML, Bhattacharyyn SN, Polymer, 35, 2 (1991)

[16] Rukenstein E, Park JS, J. Appl. Polym. Sci., 42, 925 (1991)

[17] Rukenstein E, Chen JH, J. Appl. Polym. Sci., 43, 1209 (1991)

[18] El-Aasser MS, "Advances in Emulsion Polymerization and Latex Technology," Lehigh Univ. (1992)

[19] Cheng CM, Micale FJ, J. Polym. Sci. A: Polym. Chem., 30, 235 (1992)

[20] Cheng CM, Vanderhoff JW, J. Polym. Sci. A: Polym. Chem., 30, 245 (1992)

[21] Montgomery HC, J. Appl. Polym. Sci., 43, 2971 (1971)

[22] Logan BF, J. Appl. Polym. Sci., 42, 2975 (1971)

[23] Schimmel T, "Conjugated Polymers," Ed. by Bredas, J.L., p. 53, Kluwer Academic Publishers (1991)

[24] Salaneck WR, "Conjugated Polymers and RElated Materials," Oxford University Press (1991)

[25] Chance RR, "Handbook of Conducting Polymers," Ed. by Skotheim, T.J., p. 825, Marcel Dekker, N.Y. (1986)

[26] Lee JK, Lee SH, Lim TH, J. Korean Ind. Eng. Chem., 2(4), 393 (1991)

[27] Oh SY, Koh BC, J. Korean Ind. Eng. Chem., 6(6), 1108 (1995)