Chemical Engineering Research & Design, Vol.91, No.11, 2134-2141, 2013
Dispersion of water into oil in a rotor-stator mixer. Part 2: Effect of phase fraction
In Part 1 (Rueger and Calabrese, 2013), we monitored dilute water-in-oil dispersions in a batch Silverson L4R rotor-stator mixer to establish breakage mechanisms and develop a mechanistic basis for correlation of equilibrium mean drop size. In this study (Part 2) we consider the effect of water phase fraction under similar processing conditions, thereby requiring consideration of coalescence. Most of the work on the effect of phase fraction in stirred vessels was done with a low-viscosity continuous phase in turbulent flow with inertial subrange scaling (d >eta). For that case drop size increases linearly with phase fraction, phi. In this study, viscous oils comprised the continuous phase, with water as the drop phase. The equilibrium DSD was measured in both laminar and turbulent flow conditions. The diameter of the largest drops was always less than the Kolmogorov microscale (d
Keywords:Liquid-liquid dispersion;Drop breakup;Drop coalescence;Rotor-stator mixer;High-shear;Drop size;Phase fraction