화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.6, No.2, 59-71, March, 2000
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Design and Development of Titanium and Vanadium OXide Photocatalysts Incoroprated within Zeolite Cavities and their Photocatalytic Reactivities
Masakazu Anpo†, Hiromi Yamashita, Masaya Matsuoka, Dal-Ryung Park1, Yong-Gun Shul2, and Sang-Eon Park3
  • Department of Applied Chemistry, College of Engineering, Osaka Prefecture University, Gakuen-cho 1-1, Sakai, Osaka 599-8531, Japan
  • 1Division of Gas Utilization, KOGAS R&Center, Ansan City,, Kyunggi-Do 425-150, Korea
  • 2Department of Chemical Engineering, Yonsei University, Seoul 120-749, Korea
  • 3Korea Research Institute of Chemical Technology, Daeduck Science Town, Daejeon 305-606, Korea
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Titanium or vanadium oxide species incorporated within the framework of zeolites or mesoporous molecular sieves by an ion-exchange method or hydrothermal synthesis show high and unique photocatalytic activities for various reactions such as the decomposition of NO into N2 and O2 or the reaction of CO2 with H2O th produce CH4 and CH3OH. In situ photoluminescence, XAFS and ESR investigations revealed that titanium as well as vanadium oxide moieties exit in highly disopersed tetrahedral coordination states in the zeolite framework and the charge transfer exited state of these transition metal oxide species play a vital role in the photocatalytic reactions on these zeolite and molecular sieve catalysts. The unique physciochemical properties of porous materials such as pore size, channel structural dimensins, and distribution of ion-exchangeable sites are pore size, channel structural dimensions, and distribution of ion-exchangeable sites are shown to be important factors in controlling the dispersion and local structures of the metal oxides incorporated within such porous materials as well as the photocatalytic reactivites in various photocatalytic reactions.
Keywords:photocatalyst;titanium oxide;vanadium oxide;zeolites;mesoporous molecular sieves
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