화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 3019-3024, September, 2014
DOI10.1016/j.jiec.2013.11.037  Export Citation
Diversity-oriented synthesis of quinazoline derivatives using zirconium tetrakis(dodecylsulfate) [Zr(DS)4] as a reusable Lewis acid-surfactant-combined catalyst in tap water
Hamid Reza Safaei†, Mohsen Shekouhy1, Shima Khademi, Vahid Rahmanian2, and Maryam Safaei2
  • Department of Applied Chemistry, Faculty of Science, Shiraz Branch, Islamic Azad University, P.O. Box 71993-5 Sadra new city, Shiraz, Iran
  • 1Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, Iran
  • 2Department of Industrial Polymer Engineering, Shiraz Branch, Islamic Azad University, Sadra new city, Shiraz, Iran
E-mail:
A highly efficient and environmentally benign procedure for the synthesis of quinazoline derivatives via the condensation of carbonyl compounds with 2-aminobenzamide using zirconium tetrakis(dodecyl-sulfate) [Zr(DS)4] as a highly efficient, reusable Lewis acid-surfactant-combined catalyst is described. A broad range of substrates including aldehydes and ketones are successfully condensed with 2-aminobenzamide and all reactions are completed in short times and the products are obtained in good to excellent yields. The catalyst could be recycled and reused several times without any loss of efficiency. Moreover, presented procedure has been applied successfully for the synthesis of spiro-quinazolinones and fused ring-quinazolinone derivatives.
Keywords:Quinozaline;Zirconium tetrakis(dodecylsulfate);2-Aminobenzamide;Reusable catalyst;Tap water;Lewis acid-surfactant combined catalyst
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