Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 3283-3291, September, 2014
Binding nature of polystyrene and PVC 50:50% with CP and NP 50:50% ion exchangeable, mechanically and thermally stable membrane
E-mail:
Organic polymers with inorganic materials make a flexible and thermally stable composite ion
exchangeable membrane. Such composite was effectively prepared by a sol-gel process. Polymers focus the binding as well as flexibility where as inorganic materials provide the ion exchange property, thermal stability and performance. TEM/SEM-supported EDS, XRD, FTIR and TGA/DTA characterization were used to show the structural configuration and thermal property. Through these above studies it is clear that the membrane has smooth, porous, cracks free and breakage free surface and it was found to be cation-selective nature. To show the theoretical value of ionic potential Teorell-Meyer-Sievers method was used which helps to obtain other parameters of composite membrane.
Keywords:Polystyrene and PVC;TEM/SEM-supported EDS;Teorell-Meyer-Sievers method;Ion exchange and thermal stability;Charge density
- Pandey P, Chauhan RS, Prog. Polym. Sci, 26, 853 (2001)
- Moya AA, Electrochim. Acta, 90, 1 (2013)
- Lau WJ, Ismai AF, IPCBEE, 17 (2011)
- McGinnis RL, Elimelech M, Desalination, 207(1-3), 370 (2007)
- Chung T, Jiang LY, Li Y, Kulprathipanja S, Prog. Polym. Sci, 32, 483 (2007)
- Okumus E, Gurkan T, Yilmaz L, Sep. Sci. Technol., 29(18), 2451 (1994)
- Arfin T, Rafiuddin, J. Electroanal. Chem., 636, 113 (2009)
- Khan AA, Inamuddin, Alam MM, React. Funct. Polym., 63(2), 119 (2005)
- Al-Othman ZA, Inamuddin, Naushad M, Chem. Eng. J., 166(2), 639 (2011)
- Klaysom C, Moon SH, Ladewig BP, Lu GQM, Wang LZ, J. Membr. Sci., 371(1-2), 37 (2011)
- Uematsu I, Jimbo T, Tanioka A, J. Colloid Interface Sci., 245(2), 319 (2002)
- Chou TJ, Tanioka A, J. Colloid Interface Sci., 212(2), 293 (1999)
- Nagarale RK, Shahi VK, Thampy SK, Rangarajan R, React. Funct. Polym., 61(1), 131 (2004)
- Gohil GS, Nagarale RK, Binsu VV, Shahi VK, J. Colloid Interface Sci., 298(2), 845 (2006)
- Tripathi BP, Shahi VK, Prog. Polym. Sci, 36, 945 (2011)
- Siddiqi FA, Beg MN, Singh SP, J. Polym. Sci., 15, 959 (1979)
- Jadav GL, Singh PS, J. Membr. Sci., 328(1-2), 257 (2009)
- Khan MMA, Rafiuddin, Desalination, 272(1-3), 306 (2011)
- Zou H, Wu SS, Shen J, Chem. Rev., 108(9), 3893 (2008)
- Kickelbick G, Synthesis, Characterization, and Applications, Wiley-VCH, Weinheim, Germany, 2007p. 1.
- Suendo V, Minagawa M, Tanioka A, J. Electroanal. Chem., 520(1-2), 29 (2002)
- Hassan MM, Ahmed AS, Chaman M, Khan W, Naqvi AH, Azam A, Mater. Res. Bull., 47(12), 3952 (2012)
- Ishrat U, Rafiuddin, Desalination, 286, 8 (2012)
- ASTM D543-95, Standard Particles for Evaluating the Resistance of Plastics to Chemical Reagents, Standard 27, 1998.
- Nakamoto K, Infrared and Raman Spectra of Inorganic and Coordinate Compounds, Wiley-Interscience, New York, 1986.
- Zhang X, Shiyou X, Gaorong H, Mater. Lett., 63, 1761 (2009)
- Shahi VK, Trivedi GS, Thampy SK, Rangarajan R, J. Colloid Interface Sci., 262(2), 566 (2003)
- Khan MMA, Rafiuddin, Inamuddin, J. Ind. Eng. Chem., 18(4), 1391 (2012)
- Jabeen F, Rafiuddin, J. Porous Mat., 16, 257 (2009)
- Matsumoto H, Tanioka A, Murata T, Higa M, Horiuchi K, J. Phys. Chem. B, 102(25), 5011 (1998)
- Higa M, Tanioka A, Kira A, J. Membr. Sci., 140(2), 213 (1998)
- Nabi SA, Naushad M, Inamuddin, J. Hazard. Mater., 142(1-2), 404 (2007)