Enhanced activity of MCM-48 based tin catalyst for synthesis of 3-methylbut-3-en-1-ol by adjusting the mesochannel environment

Zhaoyang Fei; Shenglan Ai; Zhe Zhou; Xian Chen; Jihai Tang; Mifen Cui; Xu Qiao

Journal of Industrial and Engineering Chemistry, Vol.20, No.6, 4146-4151, November, 2014

DOI10.1016/j.jiec.2014.01.013 Export Citation

Enhanced activity of MCM-48 based tin catalyst for synthesis of 3-methylbut-3-en-1-ol by adjusting the mesochannel environment

Zhaoyang Fei^{1, 2, †}, Shenglan Ai^{1, 2}, Zhe Zhou^{1, 2}, Xian Chen², Jihai Tang², Mifen Cui², and Xu Qiao^{1, 2, †}

¹State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 210009, China
²College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 210009, China

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In the present work, tin incorporated MCM-48 catalysts were prepared by different strategies and applied in the synthesis of MB-AC and MBOH. The performance of the catalysts is strongly affected by mesochannel environment and acid texture. The organic-graft method (Sn-G-MCM-48) can modify the mesochannel environment and enhance the acid intensity and concentration (0.28 mmol/gcat), resulting in the improvement of the catalytic activity to the target reactions. The total yield of MB-AC and MBOH is as much as 68.4% over Sn-G-MCM-48 under mild conditions.

Keywords:Mesoporous materials;Prins reaction;Support catalyst;Tin;MCM-48

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[2] Hoelderich WF, Catal. Today, 62(1), 115 (2000)

[3] Jyothi TM, Kaliya ML, Landau MV, Angew. Chem.-Int. Edit., 40, 2881 (2001)

[4] Arundale E, Mikelska LA, Chem. Rev., 51, 505 (1952)

[5] Yoshinori Y, Yoshiro Y, US Patent 4,028,424, 1977.

[6] Hu XC, Chuah GK, Jaenicke S, Appl. Catal. A: Gen., 217(1-2), 1 (2001)

[7] Liu HC, Liu JQ, Guo QW, Li LD, Li HG, Wen X, Xiao FK, Zhao N, Wei W, Sun YH, J. Fuel Chem. Technol., 41, 1146 (2013)

[8] Liu JQ, Li LD, Wen X, Peng WC, Xiao FK, Wei W, Sun YH, Fine Chem., 28, 293 (2011)

[9] Dumitriu E, On DT, Kaliaguine S, J. Catal., 170(1), 150 (1997)

[10] Dumitriu E, Hulea V, Fechete I, Catrinescu C, Auroux A, Lacaze JF, Guimon C, Appl. Catal. A: Gen., 181(1), 15 (1999)

[11] Ji M, Li XF, Wang JH, Zhu JM, Zhou LM, Catal. Today, 173(1), 28 (2011)

[12] Qiao X, Chen X, Liu Q, Zhou Z, Fei ZY, Cui MF, Tang JH, CN Patent 201310195680.2, 2013.

[13] Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710 (1992)

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[17] Mbaraka IK, Shanks BH, J. Catal., 229(2), 365 (2005)

[18] Ni L, Lv Y, Yang P, Cao Y, Chem. Commun., 2171 (2009)

[19] Karimi B, Zareyee D, Org. Lett., 10, 3989 (2008)

[20] Zhu J, Liu RB, Xu J, Meng CG, J. Mater. Sci., 46(22), 7223 (2011)

[21] Schumacher K, Ravikovitch PI, Du Chesne A, Neimark AV, Unger KK, Langmuir, 16(10), 4648 (2000)

[22] Xu J, Luan ZH, He HY, Zhou WZ, Kevan L, Chem. Mater., 10, 3690 (1988)

[23] Salasiah E, Wong KL, Microporous Mesoporous Mater., 101, 256 (2007)

[24] Busca G, in: Fierro JLG (Ed.), Metal Oxides, Chemistry and Applications, CRCTaylor & Francis, Boca Raton, FL, 2006, p. 247.

[25] Zhang JF, Zhao YL, Pan M, Feng XZ, Ji WJ, Au CT, ACS Catal., 1, 32 (2011)

[26] Selvaraj M, Kawi S, J. Mater. Chem., 17, 3610 (2007)

[27] Brunauer S, Deming LS, Deming WS, Teller E, J. Am. Chem. Soc., 62, 1723 (1940)