Corrosion inhibition and adsorption behavior of new Schiff base surfactant on steel in acidic environment: Experimental and theoretical studies

S.A. Soliman; M.S. Metwally; S.R. Selim; M.A. Bedair; Mohamed A. Abbas

Journal of Industrial and Engineering Chemistry, Vol.20, No.6, 4311-4320, November, 2014

DOI10.1016/j.jiec.2014.01.038 Export Citation

Corrosion inhibition and adsorption behavior of new Schiff base surfactant on steel in acidic environment: Experimental and theoretical studies

S.A. Soliman, M.S. Metwally, S.R. Selim, M.A. Bedair^†, and Mohamed A. Abbas¹

Department of Chemistry, Faculty of Science (Men’s Campus), Al-Azhar University, Nasr City 11884, Cairo, Egypt
¹Egyptian Petroleum Research Institute (EPRI), Cairo, Egypt

E-mail:

Synthesis, adsorption and corrosion inhibiting effect of new Schiff base surfactant named 4-hydroxy-3-(3-phenyl-allylideneamino)-benzene sulphonic acid2-[2-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethyl ether (abbreviated as PAAB) on mild steel in 1.0 M HCl were investigated using weight loss, and potentiodynamic polarization techniques. The results revealed that this compound inhibited the corrosion reaction in HCl environment. The results indicated that this inhibitor was adsorbed on the metal/solution interface. Theoretical study of the adsorption behavior of this compound was carried out in the framework of the semiempirical (SE) and molecular dynamics (MD).

Keywords:Steel;Weight loss;Polarization;Acid corrosion;Acid inhibition

[References]

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Emregul KC, Atakol O, Mater. Chem. Phys., 82(1), 188 (2003)
Asan A, Kabasakaloglu M, Kalan MI, Kılıc Z, Corrosion Sci., 47, 1534 (2005)
Jacob KS, Parameswaran G, Corrosion Sci., 52, 224 (2010)
Tang Y, Yang X, Yang W, Chen Y, Wana R, Corrosion Sci., 52, 242 (2010)
Lowmunkhong P, Ungthararak D, Sutthivaiyakit P, Corrosion Sci., 52, 30 (2010)
Abdallah M, Corrosion Sci., 44, 717 (2002)
Hegazy MA, Corrosion Sci., 51, 2610 (2009)
Hasanov R, Bilge S, Bilgic S, Gece G, Kılıc Z, Corrosion Sci., 52, 984 (2010)
Chetouani A, Aouniti A, Hammouti B, Benchat N, Benhadda T, Kertit S, Corrosion Sci., 45, 1675 (2003)
Lgamri A, El-Makarim HA, Guebour A, Bachir AB, Aries L, Hajjaji SE, Prog. Org. Coat., 48, 63 (2003)
Agrawal YK, Talati JD, Shah MD, Desai MN, Shah NK, Corrosion Sci., 46, 633 (2004)
Shaban SM, Saied A, Tawfik SM, Abd-Elaal A, Aiad I, J. Ind. Eng. Chem., 19(6), 2004 (2013)
Xu B, Yang W, Liu Y, Yin X, Gong W, Chen Y, Corrosion Sci., 78, 260 (2014)
Arab ST, Noor EA, Corrosion, 49, 122 (1993)
Raspi LA, Nickel Corros., 49, 821 (1993)
Singh DN, Dey AK, Corrosion, 49, 594 (1993)
Banerjee G, Malhotra SN, Corrosion, 48, 10 (1992)
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Sastri VS, Perumareddi JR, Corrosion, 53, 671 (1996)
Pearson RG, Inorg. Chem., 27, 734 (1988)
Martinez S, Mater. Chem. Phys., 77, 97 (2002)
Barriga J, Coto B, Fernandez B, Tribol. Int., 40, 960 (2007)
Sun H, Ren P, Fried JR, Comput. Theor. Polym. Sci., 8, 229 (1998)
Tang LB, Mu GN, Liu GH, Corrosion Sci., 45, 2251 (2003)
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Mu GN, Li XH, Qu Q, Zhou J, Acta Chim. Sin., 62, 2386 (2004)
El-Sayed AA, Corros. Prev. Control, 43, 23 (1996)
Khaled KF, Electrochim. Acta, 53(9), 3484 (2008)
Curulla-Ferre D, Govender A, Bromfield TC, Niemantsverdriet JW, J. Phys. Chem. B, 110(28), 13897 (2006)
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[Referenced By]

[1] Aljourani J, Raeissi K, Golozar MA, Corrosion Sci., 51, 1836 (2009)

[2] Emregul KC, Atakol O, Mater. Chem. Phys., 82(1), 188 (2003)

[3] Asan A, Kabasakaloglu M, Kalan MI, Kılıc Z, Corrosion Sci., 47, 1534 (2005)

[4] Jacob KS, Parameswaran G, Corrosion Sci., 52, 224 (2010)

[5] Tang Y, Yang X, Yang W, Chen Y, Wana R, Corrosion Sci., 52, 242 (2010)

[6] Lowmunkhong P, Ungthararak D, Sutthivaiyakit P, Corrosion Sci., 52, 30 (2010)

[7] Abdallah M, Corrosion Sci., 44, 717 (2002)

[8] Hegazy MA, Corrosion Sci., 51, 2610 (2009)

[9] Hasanov R, Bilge S, Bilgic S, Gece G, Kılıc Z, Corrosion Sci., 52, 984 (2010)

[10] Chetouani A, Aouniti A, Hammouti B, Benchat N, Benhadda T, Kertit S, Corrosion Sci., 45, 1675 (2003)

[11] Lgamri A, El-Makarim HA, Guebour A, Bachir AB, Aries L, Hajjaji SE, Prog. Org. Coat., 48, 63 (2003)

[12] Agrawal YK, Talati JD, Shah MD, Desai MN, Shah NK, Corrosion Sci., 46, 633 (2004)

[13] Shaban SM, Saied A, Tawfik SM, Abd-Elaal A, Aiad I, J. Ind. Eng. Chem., 19(6), 2004 (2013)

[14] Xu B, Yang W, Liu Y, Yin X, Gong W, Chen Y, Corrosion Sci., 78, 260 (2014)

[15] Arab ST, Noor EA, Corrosion, 49, 122 (1993)

[16] Raspi LA, Nickel Corros., 49, 821 (1993)

[17] Singh DN, Dey AK, Corrosion, 49, 594 (1993)

[18] Banerjee G, Malhotra SN, Corrosion, 48, 10 (1992)

[19] Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Scalmani G, Barone V, Mennucci B, Petersson GA, Nakatsuji H, Caricato M, Li X, Hratchian HP, Izmaylov AF, Bloino J, Zheng G, Sonnenberg JL, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Vreven T, Montgomery JA, Peralta JE, Ogliaro F, Bearpark M, Heyd JJ, Brothers E, Kudin KN, Staroverov VN, Kobayashi R, Normand J, Raghavachari K, Rendell A, Burant JC, Iyengar SS, Tomasi J, Cossi M, Rega N, Millam JM, Klene M, Knox JE, Cross JB, Bakken V, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski JW, Martin RL, Morokuma K, Zakrzewski VG, Voth GA, Salvador P, Dannenberg JJ, Dapprich S, Daniels AD, Farkas O, Foresman JB, Ortiz JY, Cioslowski J, Fox DJ, Gaussian 09, Revision A.02, Gaussian, Inc., Wallingford, CT, 2009.

[20] Sastri VS, Perumareddi JR, Corrosion, 53, 671 (1996)

[21] Pearson RG, Inorg. Chem., 27, 734 (1988)

[22] Martinez S, Mater. Chem. Phys., 77, 97 (2002)

[23] Barriga J, Coto B, Fernandez B, Tribol. Int., 40, 960 (2007)

[24] Sun H, Ren P, Fried JR, Comput. Theor. Polym. Sci., 8, 229 (1998)

[25] Tang LB, Mu GN, Liu GH, Corrosion Sci., 45, 2251 (2003)

[26] Manjula P, Manonmani S, Jayaram P, Rajendran S, Anti-Corros. Methods Mater., 48, 319 (2001)

[27] Abd El Rehim SS, Ibrahim MAM, Khalid KF, Mater. Chem. Phys., 70(3), 268 (2001)

[28] Tang L, Li X, Si Y, Mu G, Liu GH, Mater. Chem. Phys., 95, 26 (2006)

[29] Umoren SA, Obot IB, Ebenso EE, E-J. Chem., 5, 355 (2008)

[30] Quartarone G, Battilana M, Bonaldo L, Tortato T, Corrosion Sci., 50, 3467 (2008)

[31] Hegazy MA, Ahmed HM, El-Tabei AS, Corrosion Sci., 53, 671 (2011)

[32] Finar L, 6th ed., Organic Chemistry, vol. 1, Longman, London, 1986.

[33] Mu GN, Li XH, Qu Q, Zhou J, Acta Chim. Sin., 62, 2386 (2004)

[34] El-Sayed AA, Corros. Prev. Control, 43, 23 (1996)

[35] Khaled KF, Electrochim. Acta, 53(9), 3484 (2008)

[36] Curulla-Ferre D, Govender A, Bromfield TC, Niemantsverdriet JW, J. Phys. Chem. B, 110(28), 13897 (2006)

[37] Jiang DE, Sumpter BG, Dai S, J. Am. Chem. Soc., 128(18), 6030 (2006)

[38] Combellas C, Delamar M, Kanoufi F, Pinson J, Podvorica FI, Chem. Mater., 17, 3968 (2005)