Helix-sense-selective anionic polymerization of (S)-2’-methyloxy-2-vinyl-1,1’-binaphthyl

Ye Hui Chen; Li Wen Yang; Nian Fa Yang; Zhu Sheng Yang

Macromolecular Research, Vol.22, No.11, 1152-1155, November, 2014

DOI10.1007/s13233-014-2181-z Export Citation

Helix-sense-selective anionic polymerization of (S)-2’-methyloxy-2-vinyl-1,1’-binaphthyl

Ye Hui Chen, Li Wen Yang, Nian Fa Yang^†, and Zhu Sheng Yang

Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, Hunan, 411105, P. R. China

E-mail:

(S)-2'-Methyloxy-2-vinyl-1,1'-binaphthyl,2([α]25 589=-59.0°), underwent helix-sense-selective anionic polymerization to obtain a helical polymer ([α]25 589=+182.0°) with an excess screw sense.

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[6] Gomar-Nadal E, Veciana J, Rovira C, Amabilino DB, Adv. Mater., 17(17), 2095 (2005)

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