x mol% 칼시아-안정화 지르코니아 나노분말의 수열합성 및 구조적 특성평가

류제혁; 문정인; 박연경; Tuan Dung Nguyen; 송정환; 김택남; Je-Hyeok Ryu; Jung-In Moon; Yeon-Kyung Park; Nguyen Tuan Dung; Jeong-Hwan Song; Taik-Nam Kim

Korean Journal of Materials Research, Vol.22, No.5, 220-226, May, 2012

DOI10.3740/MRSK.2012.22.5.220 Export Citation

x mol% 칼시아-안정화 지르코니아 나노분말의 수열합성 및 구조적 특성평가

Hydrothermal Synthesis and Structural Characterization of x mol% Calcia-Stabilized ZrO2 Nanopowders

류제혁, 문정인, 박연경, Tuan Dung Nguyen, 송정환¹, 김택남^{1, †}

배재대학교 대학원 재료공학과
¹배재대학교 정보전자소재공학과

Je-Hyeok Ryu, Jung-In Moon, Yeon-Kyung Park, Nguyen Tuan Dung, Jeong-Hwan Song¹, and Taik-Nam Kim^{1, †}

Department of Materials Science and Engineering, Graduate School of PaiChai University, Daejeon 302-735, Korea
¹Department of Information and Electronic Materials Engineering, PaiChai University, Daejeon 302-735, Korea

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Pure zirconia and x mol% calcia partially stabilized zirconia (x = 1.5, 3, and 8) nanopowders were synthesized by hydrothermal method with various reaction temperatures for 24 hrs. The precipitated precursor of pure zirconia and x mol% calcia doped zirconia was prepared by adding NH4OH to starting solutions; resulting sample was then put into an autoclave reactor. The optimal experimental conditions, such as reaction temperatures and times and amounts of stabilizer CaO, were carefully studied. The synthesized ZrO2 and x mol% CaO-ZrO2 (x = 1.5, 3, and 8) powders were characterized by XRD, SEM, TG-DTA, and Raman spectroscopy. When the hydrothermal temperature was as low as 160oC, pure ZrO2 and x mol% CaOZrO2 (x = 1.5 and 3) powders were identified as a mixture of monoclinic and tetragonal phases. However, a stable tetragonal phase of zirconia was observed in the 8 mol% calcia doped zirconia nanopowder at hydrothermal temperature above 160oC. To observe the phase transition, the 3 mol% CaO-ZrO2 and 8 mol% CaO-ZrO2 nanopowders were heat treated from 600 to 1000oC for 2h. The 3 mol% CaO-ZrO2 heat treated at above 1000oC was found to undergo a complete phase transition from mixture phase to monoclinic phase. However, the 8 mol% calcia doped zirconia appeared in the stable tetragonal phase after heat treatment. The result of this study therefore should be considered as the preparation of 8 mol% CaO-ZrO2 nanopowders via the hydrothermal method.

Keywords:CaO-stabilized ZrO2;hydrothermal;nanopowder;tetragonal;raman

[References]

Schmidt T, Mennig M, Schmidt H, J. Am. Ceram. Soc., 90(5), 1401 (2007)
Jossen R, Mueller R, Pratsinis, SE, Watson M, Akhtar MK, Nanotechnology, 16, S609 (2005)
Pebler AR, J. Mater. Res., 5, 680 (1990)
Kaspar J, Fornasiero P, J. Solid State Chem., 171, 19 (2003)
Mizutani Y, Hisada K, Ukai K, Sumi H, Yokoyama M, Nakamura Y, Yamamoto O, J. Alloy. Comp., 408(12), 518 (2006)
Lee JH, J. Mater. Sci., 38(21), 4247 (2003)
Mondal A, Ram S, J. Am. Ceram. Soc., 87(12), 2187 (2004)
Li Y, Chi W, Sampath S, Goland A, Herman H, Allen J, Ilavsky J, J. Am. Chem. Soc., 92(2), 491 (2009)
Garvie RC, J. Phys. Chem., 69, 1238 (1965)
Garvie RC, J. Phys. Chem., 82, 218 (1978)
Lee WE, Rainforth WM, Ceramic Microstructures:Property Control by Processing, p. 317., Chapman & Hall, London (1994). (1994)
Juarez RE, Lamas DG, Lascalea GE, Walsoe de Reca NE, Defect Diffus. Forum, 177-178, 1 (1999)
Zhou SX, Garnweitner G, Niederberger M, Antonietti M, Langmuir, 23(18), 9178 (2007)
Pang GS, Chen SG, Zhu YC, Palchik O, Koltypin Y, Zaban A, Gedanken A, J. Phys. Chem. B, 105(20), 4647 (2001)
Hirata Y, Nakamura M, Miyamoto M, Tanaka Y, Wang XH, J. Am. Ceram. Soc., 89(6), 1883 (2006)
Hung IM, Hung DT, Fung KZ, Hon MH, J. Eur. Ceram. Soc., 26, 2627 (2006)
Kumazawa H, Inoue T, Sada E, Chem. Eng. J. Biochem. Eng. J., 55, 93 (1991)
Juarez RE, Lamas DG, Lascalea GE, Walsoe de Reca NE, J. Eur. Ceram. Soc., 20, 133 (2000)
Pyda W, Haberko K, Bulko MM, J. Am. Ceram. Soc., 74(10), 2622 (1991)
Dechamps M, Djuricic B, Pickering S, J. Am. Ceram. Soc., 78(11), 2873 (1995)
Matsui K, Suzuki H, Ohgai M, Arashi H, J. Am. Ceram. Soc., 78(1), 146 (1995)
Wang J, Ee LS, Ng SC, Chew CH, Gan LM, Mater. Lett., 30, 119 (1997)
Song JH, Lee JH, Korean J. Mater. Res., 19(8), 412 (2009)
Kil HS, Hwag SH, Ryu JH, Lim DY, Cho SB, J. Ceram. Soc. Jpn., 120(2), 52 (2012)
Gogotsi Y, Domnich V, High-Pressure Surface Science and Engineering, p. 476-520, CRC Press, UK (2003). (2003)
Wulfman C, Sadoun M, de la Chapelle ML, IRBM, 31, 257 (2010)

[Referenced By]

[1] Schmidt T, Mennig M, Schmidt H, J. Am. Ceram. Soc., 90(5), 1401 (2007)

[2] Jossen R, Mueller R, Pratsinis, SE, Watson M, Akhtar MK, Nanotechnology, 16, S609 (2005)

[3] Pebler AR, J. Mater. Res., 5, 680 (1990)

[4] Kaspar J, Fornasiero P, J. Solid State Chem., 171, 19 (2003)

[5] Mizutani Y, Hisada K, Ukai K, Sumi H, Yokoyama M, Nakamura Y, Yamamoto O, J. Alloy. Comp., 408(12), 518 (2006)

[6] Lee JH, J. Mater. Sci., 38(21), 4247 (2003)

[7] Mondal A, Ram S, J. Am. Ceram. Soc., 87(12), 2187 (2004)

[8] Li Y, Chi W, Sampath S, Goland A, Herman H, Allen J, Ilavsky J, J. Am. Chem. Soc., 92(2), 491 (2009)

[9] Garvie RC, J. Phys. Chem., 69, 1238 (1965)

[10] Garvie RC, J. Phys. Chem., 82, 218 (1978)

[11] Lee WE, Rainforth WM, Ceramic Microstructures:Property Control by Processing, p. 317., Chapman & Hall, London (1994). (1994)

[12] Juarez RE, Lamas DG, Lascalea GE, Walsoe de Reca NE, Defect Diffus. Forum, 177-178, 1 (1999)

[13] Zhou SX, Garnweitner G, Niederberger M, Antonietti M, Langmuir, 23(18), 9178 (2007)

[14] Pang GS, Chen SG, Zhu YC, Palchik O, Koltypin Y, Zaban A, Gedanken A, J. Phys. Chem. B, 105(20), 4647 (2001)

[15] Hirata Y, Nakamura M, Miyamoto M, Tanaka Y, Wang XH, J. Am. Ceram. Soc., 89(6), 1883 (2006)

[16] Hung IM, Hung DT, Fung KZ, Hon MH, J. Eur. Ceram. Soc., 26, 2627 (2006)

[17] Kumazawa H, Inoue T, Sada E, Chem. Eng. J. Biochem. Eng. J., 55, 93 (1991)

[18] Juarez RE, Lamas DG, Lascalea GE, Walsoe de Reca NE, J. Eur. Ceram. Soc., 20, 133 (2000)

[19] Pyda W, Haberko K, Bulko MM, J. Am. Ceram. Soc., 74(10), 2622 (1991)

[20] Dechamps M, Djuricic B, Pickering S, J. Am. Ceram. Soc., 78(11), 2873 (1995)

[21] Matsui K, Suzuki H, Ohgai M, Arashi H, J. Am. Ceram. Soc., 78(1), 146 (1995)

[22] Wang J, Ee LS, Ng SC, Chew CH, Gan LM, Mater. Lett., 30, 119 (1997)

[23] Song JH, Lee JH, Korean J. Mater. Res., 19(8), 412 (2009)

[24] Kil HS, Hwag SH, Ryu JH, Lim DY, Cho SB, J. Ceram. Soc. Jpn., 120(2), 52 (2012)

[25] Gogotsi Y, Domnich V, High-Pressure Surface Science and Engineering, p. 476-520, CRC Press, UK (2003). (2003)

[26] Wulfman C, Sadoun M, de la Chapelle ML, IRBM, 31, 257 (2010)