Synthesis and preparation of alkyl-functionalized graphene oxide/polyimide nanocomposites

Do Hoon Lee; Hyeonuk Yeo; Gi Ryeong Kim; Seokhoon Ahn; Munju Goh; Bon-Cheol Ku; Joong Hee Lee; Byoungnam Park; Nam-Ho You

Macromolecular Research, Vol.22, No.12, 1344-1347, December, 2014

DOI10.1007/s13233-015-3016-2 Export Citation

Synthesis and preparation of alkyl-functionalized graphene oxide/polyimide nanocomposites

Do Hoon Lee^{1, 2}, Hyeonuk Yeo^{1, 3}, Gi Ryeong Kim⁴, Seokhoon Ahn⁴, Munju Goh^{1, 3}, Bon-Cheol Ku^{1, 3}, Joong Hee Lee², Byoungnam Park⁵, and Nam-Ho You^{1, 3, †}

¹Carbon Convergence Materials Research Center, Korea Institute of Science and Technology, Jeonbuk, 565-905, Korea
²Department of BIN fusion Technology & Department of Polymer and Nano Science and Technology, Chonbuk National University, Jeonbuk, 561-756, Korea
³, Korea
⁴Soft Inovation Materials Research Center, Korea Institute of Science and Technology, Jeonbuk, 565-905, Korea
⁵Department of Materials Science and Engineering, Hongik University, Seoul, 121-791, Korea

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A new method to prepare the alkyl-fucntionalized graphene oxide (A-GO)/polyimide composite was developed using non-covalent interfacial interaction via in situ polymerization. The A-GO/PI composites showed a 18% increase in tensile strength, and 45% improvement in modulus with a low content of A-GO (0.5wt%) due to strong interfacial interaction between A-GO and matrix polymer.

[References]

Miyasaka K, Watanabe K, Jojima E, Aida H, Sumita M, Ishikawa K, J. Mater. Sci., 17, 1610 (1982)
Qian D, Dickey EC, Andrews R, Rantell T, Appl. Phys. Lett., 76, 2868 (2000)
Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA, Nature, 438, 197 (2005)
Sumita M, Sakata K, Asai S, Miyasaka K, Nakagawa H, Polym. Bull., 25, 265 (1991)
Kumar S, Doshi H, Srinivasarao M, Park JO, Schiraldi DA, Polymer, 43(5), 1701 (2002)
Stankovich S, Dikin DA, Dommett GH, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS, Nature, 442, 282 (2006)
Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, Carbon, 45, 1558 (2007)
Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Ahn JH, Kim P, Choi JY, Hong BH, Nature, 457, 706 (2009)
Singh V, Joung D, Zhai L, Das S, Khondaker SI, Seal S, Prog. Mater. Sci., 56(8), 1178 (2011)
Chen D, Feng HB, Li JH, Chem. Rev., 112(11), 6027 (2012)
Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39, 228 (2010)
Park OK, Hwang JY, Goh M, Lee JH, Ku BC, You NH, Macromolecules, 46(9), 3505 (2013)
Wang G, Shen X, Wang B, Yao J, Park J, Carbon, 47, 1359 (2009)
Kim Y, Chang JH, Macromol. Res., 21(2), 228 (2013)
Kim JH, Lee JK, Kim YJ, Won JC, Choi KY, Macromol. Res., 10(5), 241 (2002)
You NH, Chueh CC, Liu CL, Ueda M, Chen WC, Macromolecules, 42(13), 4456 (2009)
Stephans LE, Myles A, Thomas RR, Langmuir, 16(10), 4706 (2000)
Zhu J, Lim J, Lee CH, Joh HI, Kim HC, Park B, You NH, Lee S, J. Appl. Polym. Sci., 131, 40177 (2014)
Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A, Sun Z, Sleasarev A, Alemany LB, Lu W, Tour JM, ACS Nano, 4, 4806 (2010)
in Annual Book of ASTM Standards, Section 8: Plastics, ASTM International, Philadelphia, pp 387-393.
Shim SH, Kim KT, Lee JU, Jo WH, ACS Appl. Mater. Interfaces, 4, 4184 (2012)
Hasegawa M, Matano T, Shindo Y, Sugimura T, Macromolecules, 29(24), 7897 (1996)
Yamada Y, Yasuda H, Murota K, Nakamura M, Sodesawa T, Sato S, J. Mater. Sci., 48(23), 8171 (2013)

[Referenced By]

[Related Articles]

[1] Miyasaka K, Watanabe K, Jojima E, Aida H, Sumita M, Ishikawa K, J. Mater. Sci., 17, 1610 (1982)

[2] Qian D, Dickey EC, Andrews R, Rantell T, Appl. Phys. Lett., 76, 2868 (2000)

[3] Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA, Nature, 438, 197 (2005)

[4] Sumita M, Sakata K, Asai S, Miyasaka K, Nakagawa H, Polym. Bull., 25, 265 (1991)

[5] Kumar S, Doshi H, Srinivasarao M, Park JO, Schiraldi DA, Polymer, 43(5), 1701 (2002)

[6] Stankovich S, Dikin DA, Dommett GH, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS, Nature, 442, 282 (2006)

[7] Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, Carbon, 45, 1558 (2007)

[8] Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Ahn JH, Kim P, Choi JY, Hong BH, Nature, 457, 706 (2009)

[9] Singh V, Joung D, Zhai L, Das S, Khondaker SI, Seal S, Prog. Mater. Sci., 56(8), 1178 (2011)

[10] Chen D, Feng HB, Li JH, Chem. Rev., 112(11), 6027 (2012)

[11] Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39, 228 (2010)

[12] Park OK, Hwang JY, Goh M, Lee JH, Ku BC, You NH, Macromolecules, 46(9), 3505 (2013)

[13] Wang G, Shen X, Wang B, Yao J, Park J, Carbon, 47, 1359 (2009)

[14] Kim Y, Chang JH, Macromol. Res., 21(2), 228 (2013)

[15] Kim JH, Lee JK, Kim YJ, Won JC, Choi KY, Macromol. Res., 10(5), 241 (2002)

[16] You NH, Chueh CC, Liu CL, Ueda M, Chen WC, Macromolecules, 42(13), 4456 (2009)

[17] Stephans LE, Myles A, Thomas RR, Langmuir, 16(10), 4706 (2000)

[18] Zhu J, Lim J, Lee CH, Joh HI, Kim HC, Park B, You NH, Lee S, J. Appl. Polym. Sci., 131, 40177 (2014)

[19] Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A, Sun Z, Sleasarev A, Alemany LB, Lu W, Tour JM, ACS Nano, 4, 4806 (2010)

[20] in Annual Book of ASTM Standards, Section 8: Plastics, ASTM International, Philadelphia, pp 387-393.

[21] Shim SH, Kim KT, Lee JU, Jo WH, ACS Appl. Mater. Interfaces, 4, 4184 (2012)

[22] Hasegawa M, Matano T, Shindo Y, Sugimura T, Macromolecules, 29(24), 7897 (1996)

[23] Yamada Y, Yasuda H, Murota K, Nakamura M, Sodesawa T, Sato S, J. Mater. Sci., 48(23), 8171 (2013)