황산제일철 용액의 오존 처리에 의한 산화철 합성

김삼중; 서동수; 엄태형; 송경섭; 노재승; Sam-Joong Kim; Dong-Soo Suhr; Tae-Hyoung Eom; Kyung-Sub Song; Jea-Seung Roh

Korean Journal of Materials Research, Vol.14, No.5, 353-357, May, 2004

DOI10.3740/MRSK.2004.14.5.353 Export Citation

황산제일철 용액의 오존 처리에 의한 산화철 합성

Synthesis of Iron Oxide Using Ferrous Sulfate by Ozone Treatment

김삼중^†, 서동수, 엄태형, 송경섭, 노재승

충남대학교 재료공학과

Sam-Joong Kim^†, Dong-Soo Suhr, Tae-Hyoung Eom, Kyung-Sub Song, and Jea-Seung Roh

Department of Materials Science and Engineering, Chungnam National University, Daejeon 305-764, Korea

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The influences of the ozone oxidation, reaction temperature and NaOH equivalent ratio on the iron oxide formation were studied with fixed ferrous sulfate concentration(0.5M FeSO4ㆍ7H2O). Geothite(α-FeOOH) and/or Magnetite (Fe3O4) were synthesized depending on the reaction conditions. The characteristics of the synthesized powders were evaluated by XRD, SEM and quantitative phase analysis. The synthetic conditions to get Goethite were quite different from the results of Kiyama's and the Goethite was conveniently synthesized at low temperature and at low NaOH equivalent ratio.

Keywords:ferrous sulfate;ozone;ozone oxidation;magnetite;goethite

[References]

Tamura Y, Chyo GS, Katsura I, Water Res., 13, 21 (1979)
Oh JH, Lee SH, Kang NK, Kim M, J. Kor. Inst. Met. Mater., 31(10), 1345 (1993)
Byun TB, Lee JY, Kim TH, Son JG, Kweon SW, J. Kor. Inst. Met. Mater., 30(8), 911 (1992)
Matsumoto K, Akiraka T, Hukai K, Nakatani S, Japan Patent Koukai, 56-17290 (1981) (1981)
Okamoto S, Konkasura I, Magnetic Ceramics, Shihoudou, Tokyo, (1985) (1985)
Oh JH, Prog. Chem. Chem. Indus., 24(11), 722 (1984)
Giessen AAVD, J. Phys. Chem. Solid, Pergamon Press, 28, 343 (1967)
'Advanced Technology of the Utilization of Ozon (New Edition)', Sansyuyobou
Kiyama M, Bull. Chem. Soc. Japan, 47, 1646 (1974)

[Referenced By]

[1] Tamura Y, Chyo GS, Katsura I, Water Res., 13, 21 (1979)

[2] Oh JH, Lee SH, Kang NK, Kim M, J. Kor. Inst. Met. Mater., 31(10), 1345 (1993)

[3] Byun TB, Lee JY, Kim TH, Son JG, Kweon SW, J. Kor. Inst. Met. Mater., 30(8), 911 (1992)

[4] Matsumoto K, Akiraka T, Hukai K, Nakatani S, Japan Patent Koukai, 56-17290 (1981) (1981)

[5] Okamoto S, Konkasura I, Magnetic Ceramics, Shihoudou, Tokyo, (1985) (1985)

[6] Oh JH, Prog. Chem. Chem. Indus., 24(11), 722 (1984)

[7] Giessen AAVD, J. Phys. Chem. Solid, Pergamon Press, 28, 343 (1967)

[8] 'Advanced Technology of the Utilization of Ozon (New Edition)', Sansyuyobou

[9] Kiyama M, Bull. Chem. Soc. Japan, 47, 1646 (1974)