Covalent organic frameworks (COFs) are crystalline porous materials bearing microporous or mesoporous pores. The type and size of pores play crucial roles in regulating the properties of COFs. In this work, a novel COF, which bears two different kinds of ordered pores with controllable sizes: one within microporous range (7.1 angstrom) and the other in mesoporous range (26.9 angstrom), has been constructed via one-step synthesis. The structure of the dual-pore COF was confirmed by PXRD investigation, nitrogen adsorptiondesorption study, and theoretical calculations.