Effect of temporary network structure on linear and nonlinear viscoelasticity of polymer solutions

Kwang-Soo Cho; Jae-Woo Kim; Jung-Eun Bae; Ji-Ho Youk; Hyun-Jeong Jeon; Ki-Won Song

Korea-Australia Rheology Journal, Vol.27, No.2, 151-161, May, 2015

DOI10.1007/s13367-015-0015-y Export Citation

Effect of temporary network structure on linear and nonlinear viscoelasticity of polymer solutions

Kwang-Soo Cho^†, Jae-Woo Kim, Jung-Eun Bae, Ji-Ho Youk¹, Hyun-Jeong Jeon¹, and Ki-Won Song²

Department of Polymer Science and Engineering, School of Applied Chemical Engineering, Kyungpook National University, Daegu 702-701, Republic of Korea
¹Department of Advanced Fiber Engineering, Division of Nano-Systems, Inha University, Incheon 402-751, Republic of Korea
²Department of Organic Material Science and Engineering, Pusan National University, Pusan 609-735, Republic of Korea

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We investigated the effects of temporary network structures on linear and nonlinear viscoelasticity of polymer solutions by use of oscillatory shear (LAOS) flow. We tested two different types of polymer solutions: entanglement systems and ion complex systems. It was found that the entanglement network is difficult to show shear-thickening while network of ion complex gives rise to shear-thickening. The objectives of this paper are the test of strain-frequency superposition for various polymer solutions and to suggest a new method classifying complex fluids consisting temporary networks using LAOS data.

Keywords:large amplitude oscillatory shear;strain-frequency superposition;temporary network structure;shear-thinning fluids;shear-thickening fluids

[References]

Archer LA, Sanchez-Reyes J, Juliani, Macromolecules, 35(27), 10216 (2002)
Cho KS, Ahn KH, Lee SJ, J. Rheol., 49(3), 747 (2005)
Cho KS, Song KW, Chang GS, J. Rheol., 54(1), 27 (2010)
Doi M, 1995, Introduction to Polymer Physics, Oxford University Press. (1995)
Einaga Y, Osaki K, Kurata M, Kimura S, Tamura M, Polym. J., 2, 550 (1971)
Ewoldt RH, Hosoi AE, McKinley GH, J. Rheol., 52(6), 1427 (2008)
Fetters LJ, Lohse DJ, Richter D, Witten TA, Zirkel A, Macromolecules, 27(17), 4639 (1994)
Giacomin AJ, Oakley JG, J. Rheol., 36, 1529 (1992)
Hess A, Aksel N, Phys. Rev. E, 84, 051502 (2011)
Hyun K, Kim SH, Ahn KH, Lee SJ, J. Non-Newton. Fluid Mech., 107, 61 (2002)
Inoue T, Uematsu T, Yamashita Y, Osaki K, Macromolecules, 35(12), 4718 (2002)
Kapnistos M, Kirkwood KM, Ramirez J, Vlassopoulos D, Leal LG, J. Rheol., 53(5), 1133 (2009)
Kim H, Hyun K, Kim DJ, Cho KS, Korea-Aust. Rheol. J., 18(2), 91 (2006)
Larson RG, J. Rheol., 29, 823 (1985)
Lee JH, Driva P, Hadjichristidis N, Wright PJ, Rucker SP, Lohse DJ, Macromolecules, 42(4), 1392 (2009)
Lin HL, Liu YF, Yu TL, Liu WH, Rwei SP, Polymer, 46(15), 5541 (2005)
Marrucci G, Bhargava S, Cooper SL, Macromolecules, 26, 6483 (1993)
Osaki K, Nishizawa K, Kurata M, Macromolecules, 15, 1068 (1982)
Pellens L, Ahn KH, Lee SJ, Mewis J, J. Non-Newton. Fluid Mech., 121(2-3), 87 (2004)
Reimers MJ, Dealy JM, J. Rheol., 40(1), 167 (1996)
Rubinstein M, Colby R, 2003, Polymer Physics, Oxford University Press. (2003)
Tee TT, Dealy JM, Trans. Soc. Rheol., 19, 595 (1975)
Vaccaro A, Marrucci G, J. Non-Newton. Fluid Mech., 92(2-3), 261 (2000)
Watanabe H, Prog. Polym. Sci, 24, 1253 (1999)
Wilhelm M, Maring D, Spiess HW, Rheol. Acta, 37(4), 399 (1998)
Wilhelm M, Reinheimer P, Ortseifer M, Rheol. Acta, 38(4), 349 (1999)
Wyss HM, Miyazaki K, Mattsson J, Hu Z, Reichman DR, Weitz DA, Phys. Rev. Lett., 89, 238303 (2007)

[Referenced By]

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[1] Archer LA, Sanchez-Reyes J, Juliani, Macromolecules, 35(27), 10216 (2002)

[2] Cho KS, Ahn KH, Lee SJ, J. Rheol., 49(3), 747 (2005)

[3] Cho KS, Song KW, Chang GS, J. Rheol., 54(1), 27 (2010)

[4] Doi M, 1995, Introduction to Polymer Physics, Oxford University Press. (1995)

[5] Einaga Y, Osaki K, Kurata M, Kimura S, Tamura M, Polym. J., 2, 550 (1971)

[6] Ewoldt RH, Hosoi AE, McKinley GH, J. Rheol., 52(6), 1427 (2008)

[7] Fetters LJ, Lohse DJ, Richter D, Witten TA, Zirkel A, Macromolecules, 27(17), 4639 (1994)

[8] Giacomin AJ, Oakley JG, J. Rheol., 36, 1529 (1992)

[9] Hess A, Aksel N, Phys. Rev. E, 84, 051502 (2011)

[10] Hyun K, Kim SH, Ahn KH, Lee SJ, J. Non-Newton. Fluid Mech., 107, 61 (2002)

[11] Inoue T, Uematsu T, Yamashita Y, Osaki K, Macromolecules, 35(12), 4718 (2002)

[12] Kapnistos M, Kirkwood KM, Ramirez J, Vlassopoulos D, Leal LG, J. Rheol., 53(5), 1133 (2009)

[13] Kim H, Hyun K, Kim DJ, Cho KS, Korea-Aust. Rheol. J., 18(2), 91 (2006)

[14] Larson RG, J. Rheol., 29, 823 (1985)

[15] Lee JH, Driva P, Hadjichristidis N, Wright PJ, Rucker SP, Lohse DJ, Macromolecules, 42(4), 1392 (2009)

[16] Lin HL, Liu YF, Yu TL, Liu WH, Rwei SP, Polymer, 46(15), 5541 (2005)

[17] Marrucci G, Bhargava S, Cooper SL, Macromolecules, 26, 6483 (1993)

[18] Osaki K, Nishizawa K, Kurata M, Macromolecules, 15, 1068 (1982)

[19] Pellens L, Ahn KH, Lee SJ, Mewis J, J. Non-Newton. Fluid Mech., 121(2-3), 87 (2004)

[20] Reimers MJ, Dealy JM, J. Rheol., 40(1), 167 (1996)

[21] Rubinstein M, Colby R, 2003, Polymer Physics, Oxford University Press. (2003)

[22] Tee TT, Dealy JM, Trans. Soc. Rheol., 19, 595 (1975)

[23] Vaccaro A, Marrucci G, J. Non-Newton. Fluid Mech., 92(2-3), 261 (2000)

[24] Watanabe H, Prog. Polym. Sci, 24, 1253 (1999)

[25] Wilhelm M, Maring D, Spiess HW, Rheol. Acta, 37(4), 399 (1998)

[26] Wilhelm M, Reinheimer P, Ortseifer M, Rheol. Acta, 38(4), 349 (1999)

[27] Wyss HM, Miyazaki K, Mattsson J, Hu Z, Reichman DR, Weitz DA, Phys. Rev. Lett., 89, 238303 (2007)