Design of a novel optical sensor for determination of trace amounts of copper by UV/vis spectrophotometry in the real samples

Eslam Pourbasheer; Somayeh Morsali; Alireza Banaei; Sajjad Aghabalazadeh; Mohammad Reza Ganjali; Parviz Norouzi

Journal of Industrial and Engineering Chemistry, Vol.26, 370-374, June, 2015

DOI10.1016/j.jiec.2014.12.011 Export Citation

Design of a novel optical sensor for determination of trace amounts of copper by UV/vis spectrophotometry in the real samples

Eslam Pourbasheer^{1, †}, Somayeh Morsali¹, Alireza Banaei¹, Sajjad Aghabalazadeh², Mohammad Reza Ganjali^{2, 3}, and Parviz Norouzi^{2, 3}

¹Department of Chemistry, Payame Noor University (PNU), PO Box, 19395-3697 Tehran, Iran
²Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, PO Box, 14155-6455 Tehran, Iran
³Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran

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The characterization of an optode is described for detection of copper(II) based on the immobilization of 6-bromo-3-(2-methyl-2,3-dihydrobenzo[d]thiazol-2-yl)-2H-chromen-2 one on a triacetylcellulose membrane. The effects of pH, indicator concentration and reaction time on the immobilization of ligand were studied. This optode can readily be regenerated using thiourea solutions and its response was reproducible and reversible (R.S.D. less than 2.7%). The Cu(II) could be determined in the range between 7.0 × 10-7 and 1.0 × 10-4 M with a detection limit of 2.5 × 10-7 M. The optical sensor was successfully applied for the determination of copper(II) in various real samples.

Keywords:Optical sensor;Triacetylcellulose membrane;Copper;6-Bromo-3-(2-methyl-2,3-dihydrobenzo[d]thiazol-2-yl)-2H-chromen-2 one

[References]

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Lu J, Zhang Z, Microchem J., 52, 315 (1995)
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[Referenced By]

[1] Bjorklund LB, Morrison GM, Anal. Chim. Acta, 343, 259 (1997)

[2] Muller T, van de Sluis B, Zhernakova A, van Binsbergen E, Janecke AR, Bavdekar A, Pandit A, Weirich-Schwaiger H, Witt H, Ellemunter H, Deutsch J, Denk H, Muller W, Sternlieb I, Tanner MS, Wijmenga C, J. Hepatol., 38, 164 (2003)

[3] Pinto JJ, Moreno C, Garcıa-Vargas M, Talanta, 64, 562 (2004)

[4] Jarvis I, Jarvis KE, Chem. Geol., 95, 1 (1992)

[5] Cassella RJ, Magalhaes OI, Couto MT, Lima ELS, Neves MAF, Coutinho FMB, Talanta, 67, 121 (2005)

[6] Mashhadizadeh MH, Pesteh M, Talakesh M, Sheikhshoaie I, Ardakani MM, Karimi MA, Spectroc. Acta Pt. B-Atom. Spectr., 63, 885 (2008)

[7] Vaughan AA, Narayanaswamy R, Sens. Actuators B-Chem., 51, 368 (1998)

[8] Mohadesi A, Taher MA, Talanta, 72, 95 (2007)

[9] Clark HA, Kopelman R, Tjalkens R, Philbert MA, Anal. Chem., 71, 4837 (1999)

[10] Peterson JI, Goldstein SR, Fitzgerald RV, Buckhold DK, Anal. Chem., 52, 864 (1980)

[11] Alizadeh K, Parooi R, Hashemi P, Rezaei B, Ganjali MR, J. Hazard. Mater., 186(2-3), 1794 (2011)

[12] Zare-Dorabei R, Norouzi P, Ganjali MR, J. Hazard. Mater., 171(1-3), 601 (2009)

[13] Gholivand MB, Niroomandi P, Yari A, Joshagan M, Anal. Chim. Acta, 538, 225 (2005)

[14] Safavi A, Bagheri M, Sens. Actuators B-Chem., 107, 53 (2005)

[15] Belmonte CJ, Talanta, 58(6), 1063 (2002)

[16] Madden J, Cardwell T, Cattrall R, Deady L, Anal. Chim. Acta, 319, 129 (1996)

[17] Sanchez-Pedreno C, Ortuno J, Albero M, Garcia M, de las Bayonas JG, Fresen. J. Anal. Chem., 366, 811 (2000)

[18] Steinberg IM, Lobnik A, Wolfbeis OS, Sens. Actuators B-Chem., 90, 230 (2003)

[19] Leelasattarathkul T, Liawruangrath S, Rayanakorn M, Liawruangrath B, Oungpipat W, Youngvises N, Talanta, 72, 126 (2007)

[20] Oehme I, Prokes B, Murkovic I, Werner T, Klimant I, Wolfbeis OS, Fresen. J. Anal. Chem., 350, 563 (1994)

[21] Mahendra N, Gangaiya P, Sotheeswaran S, Narayanswamy R, Sens. Actuators B-Chem., 81, 196 (2002)

[22] Mahendra N, Gangaiya P, Sotheeswaran S, Narayanaswamy R, Sens. Actuators B-Chem., 90, 118 (2003)

[23] Lu J, Zhang Z, Microchem J., 52, 315 (1995)

[24] Malcik N, Oktar O, Ozser ME, Caglar P, Bushby L, Vaughan A, Kuswandi B, Narayanaswamy R, Sens. Actuators B-Chem., 53, 211 (1998)

[25] Sands TJ, Cardwell TJ, Cattrall RW, Farrell JR, Iles PJ, Kolev SD, Sens. Actuators B-Chem., 85, 33 (2002)

[26] Amiet GR, Farrell JR, Iles PJ, Sands TJ, Aust. J. Chem., 54, 27 (2001)

[27] Mayr T, Klimant I, Wolfbeis OS, Werner T, Anal. Chim. Acta, 462, 1 (2002)

[28] Ervin AM, Ewing K, Lamontagne R, Aggarwal I, Rowley D, Appl. Opt., 32, 4287 (1993)

[29] Saari L, Seitz W, Anal. Chem., 56, 810 (1984)

[30] Bright FV, Poirier GE, Hieftje GM, Talanta, 35, 113 (1988)

[31] Tavallali H, Shaabanpur E, Vahdati P, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 89(1), 216 (2012)

[32] McDonagh C, Burke CS, MacCraith BD, Chem. Rev., 108(2), 400 (2008)

[33] Albero M, Ortuno J, Garcıa M, Pedreno CS, Exposito R, J. Pharm. Biomed. Anal., 29, 779 (2002)

[34] Scindia Y, Pandey A, Reddys A, Manohar S, Anal. Chim. Acta, 515, 311 (2004)

[35] Kostov Y, Tzonkov S, Yotova L, Krysteva M, Anal. Chim. Acta, 280, 15 (1993)

[36] Khoobi M, Ramazani A, Foroumadi A, Hamadi H, Hojjati Z, Shafiee A, J. Iran. Chem. Soc., 8, 1036 (2011)

[37] Jones TP, Porter MD, Anal. Chem., 60, 404 (1988)

[38] Alizadeh N, Moemeni A, Shamsipur M, Anal. Chim. Acta, 464, 187 (2002)

[39] Chamjangali M, Soltanpanah S, Goudarzi N, Sens. Actuators B-Chem., 138, 251 (2009)