화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.29, 146-155, September, 2015
DOI10.1016/j.jiec.2015.03.028  Export Citation
Artemisia Mesatlantica essential oil as green inhibitor for carbon steel corrosion in 1 M HCl solution: Electrochemical and XPS investigations
K. Boumhara1, M. Tabyaoui1, C. Jama2, and F. Bentiss2, 3, †
  • 1Laboratoire des Materiaux, Nanoparticules et Environnement, Universite Mohamed V Agdal, Faculte des Sciences, 4 Av. Ibn Battouta B.P. 1014 RP, M-10000, Rabat, Morocco
  • 2UMET-PSI, CNRS UMR 8207, ENSCL, Universite Lille, 1, CS 90108, F-59652 Villeneuve d’Ascq Cedex, France
  • 3Laboratoire de Catalyse et de Corrosion des Materiaux (LCCM), Faculte des Sciences, Universite Chouaib Doukkali, B.P. 20, M-24000, El Jadida, Morocco
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The present work is devoted to the study of Artemisia Mesatlantica essential oil (AMEO) as green corrosion inhibitor to afford the protection of carbon steel in 1 M HCl medium at 30 8C. Weight loss measurements and electrochemical techniques (potentiodynamic polarization curves, and electro-chemical impedance spectroscopy) were coupled with Scanning Electron Microscopy (SEM) and X-Ray Photoelectron Spectroscopy (XPS) analyses to characterize the inhibitive properties of AMEO and to determine the chemical composition of the inhibitive film formed on the steel surface. AMEO acted as an efficient inhibitor against the carbon steel corrosion in 1 M HCl, and its inhibition efficiency increased with the inhibitor concentration reaching a value of up to 92% at 3 g/L. Polarization studies showed that the AMEO was a mixed-type inhibitor. Adsorption of AMEO on the steel surface in 1 M HCl solution followed Langmuir’s isotherm and the thermodynamic parameters were determined and discussed. The XPS studies showed that the inhibitive layer is composed of an iron oxide/hydroxide mixture where AMEO molecules are incorporated.
Keywords:Artemisia Mesatlantica;Carbon steel;HCl;Corrosion inhibition;Adsorption
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