화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.30, 167-173, October, 2015
DOI10.1016/j.jiec.2015.05.018  Export Citation
Hybrid materials in the removal of diclofenac sodium from aqueous solutions: Batch and column studies
Diwakar Tiwari, C. Lalhriatpuia, and Seung-Mok Lee1, †
  • Department of Chemistry, School of Physical Sciences, Mizoram University, Aizawl 796004, India
  • 1Department of Environmental Engineering, Catholic Kwandong University, 522 Naegok-dong, Gangneung 210-701, Republic of Korea
E-mail:
Hybrid materials (AAS (Al-AMBA-sericite and AHS (Al-HDTMA-sericite)) was obtained and materials are characterized by XRD, SEM and IR analytical techniques. Hybrid materials were assessed for efficient removal of diclofenac from aqueous solutions. Increasing the diclofenac concentration (1.0 to 20.0 mg/L) and pH 2 to 7 favored greatly the removal of diclofenac by AAS and AHS. Background electrolyte concentrations from 0.0001 to 0.1 mol/L NaCl, insignificantly affected percent removal of diclofenac. The breakthrough results were fitted well to the Thomas equation and hence, loading capacity of diclofenac was found to be 0.561 and 1.056 mg/g for AAS and AHS, respectively.
Keywords:Microporous;Diclofenac sodium;Micro-pollutants;Hybrid materials;Decontamination
  1. Dai CM, Geissen SU, Zhang YL, Zhang YJ, Zhou XF, Environ. Pollut., 159, 1660 (2011)
  2. Heberer T, Toxicol. Lett., 131, 5 (2002)
  3. Mompelat S, Le BB, Thomas O, Environ. Int., 35, 803 (2009)
  4. Zhou XF, Dai CM, Zhang YL, Surampalli R, Zhang T, Environ. Monit. Assess., 173, 45 (2010)
  5. Al-Khateeb LA, Obaid AY, Asiri NA, Salam MA, J. Ind. Eng. Chem., 20(3), 916 (2014)
  6. Lienert J, Buerki T, Escher BI, Water Sci. Technol., 56(5), 87 (2007)
  7. Joss A, Keller E, Alder A, Gobel A, McArdell C, Ternes T, Siegrist H, Water Res., 39, 3139 (2005)
  8. Landry KA, Boyer TH, Water Res., 47, 6432 (2013)
  9. Zhang Y, Geissen SU, Gal C, Chemosphere, 73, 1151 (2008)
  10. Vogna D, Marotta R, Napolitano A, Andreozzi R, d’Ischia M, Water Res., 38, 414 (2004)
  11. Hartmann JB, Mau P, Witter U, Tuempling M, Hofmann W, Nietzschmann JE, Chemosphere, 70, 453 (2008)
  12. Martinez C, Canle M, Fernandez MI, Santaballa JA, Faria J, Appl. Catal. B: Environ., 107(1-2), 110 (2011)
  13. Haap T, Triebskorn R, Kohler HR, Chemosphere, 73, 353 (2008)
  14. Bort R, Ponsoda X, Jover R, Gomez-Lechon MJ, Castell RJV, J. Pharmacol. Exp. Ther., 288, 65 (1998)
  15. Oaks JLG, Virani M, Watson MZ, Meteyer RT, Rideout CU, Shivaprasad BA, Ahmed, S. Chaudhry, M.J.I. Arshad, M. Mahmood HL, Ali S, Khan AAA, Nature, 427, 630 (2004)
  16. Mehinto AC, Hill EM, Tyler CR, Environ. Sci. Technol., 44, 2176 (2010)
  17. Vergili I, J. Environ. Manage., 127, 177 (2013)
  18. Ikehata K, Naghashkar NJ, El-Din MG, Ozone-Sci. Eng., 28, 353 (2006)
  19. Kim SD, Cho J, Kim IS, Vanderford BJ, Snyder SA, Water Res., 41, 1013 (2007)
  20. Radjenovic J, Petrovic M, Ventura F, Barcelo D, Water Res., 42, 3601 (2008)
  21. Boleda MR, Galceran MT, Ventura F, Environ. Pollut., 159, 1584 (2011)
  22. Rigobello ES, DiBernardo Dantas A, DiBernardo Luiz Vieira EM, Chemosphere, 92, 184 (2013)
  23. Ghauch A, Abou Assi H, Baydoun H, Tuqan AM, Bejjani A, Chem. Eng. J., 172(2-3), 1033 (2011)
  24. Sotelo JL, Rodriguez A, Alvarez S, Garcia J, Chem. Eng. Res. Des., 90(7), 967 (2012)
  25. Beltran FJ, Pocostales P, Alvarez P, Oropesa A, J. Hazard. Mater., 163(2-3), 768 (2009)
  26. Wei H, Deng S, Huang Q, Nie Y, Wang B, Huang J, Yu G, Water Res., 47, 4139 (2013)
  27. Suriyanon N, Punyapalakul P, Ngamcharussrivichai C, Chem. Eng. J., 214, 208 (2013)
  28. Antunes M, Esteves VI, Guegan R, Crespo JS, Fernandes AN, Giovanela M, Chem. Eng. J., 192, 114 (2012)
  29. Chen YG, He Y, Ye WM, Jia LY, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2014.12.006. (2014)
  30. Nguyen VN, Nguyen TDC, Dao TP, Tran HT, Nguyen DB, Ahn DH, J. Ind. Eng. Chem., 19(2), 640 (2013)
  31. Zhu LZ, Tian SL, Zhu HX, Shi Y, J. Colloid Interface Sci., 315(1), 191 (2007)
  32. Ma JF, Zhu LZ, J. Hazard. Mater., 136(3), 982 (2006)
  33. Yan LG, Shan MQ, Wen B, Zhang SZ, J. Colloid Interface Sci., 308(1), 11 (2007)
  34. Tiwari D, Lee SM, Chem. Eng. J., 204-206, 23 (2012)
  35. Uno H, Tamura K, Yamada H, Umeyama K, Hatta T, Moriyoshi Y, Appl. Clay Sci., 46, 81 (2009)
  36. Koh SM, Dixon JB, Appl. Clay Sci., 18, 111 (2001)
  37. Tiwari D, Kim W, Kim M, Prasad SK, Lee SM, Desalin. Water Treat., http://dx.doi.org/10.1080/19443994.2013.846562. (2014)
  38. Hung KC, Chen BH, Yu LE, Sep. Purif. Technol., 57(1), 1 (2007)
  39. Rivera-Utrilla J, Bautista-Toledo I, Ferro-Garcia MA, Moreno-Castilla C, J. Chem. Technol. Biotechnol., 76(12), 1209 (2001)
  40. Khormaei M, Nasernejad B, Edrisi M, Eslamzadeh T, J. Hazard. Mater., 149(2), 269 (2007)
  41. Lalhmunsiama, Lee SM, Tiwari D, Chem. Eng. J., 225, 128 (2013)
  42. Tiwari D, Lalmhunsiama, Lee SM, Pedosphere, 24, 731 (2014)
  43. Thomas HC, J. Am. Chem. Soc., 66, 1664 (1944)
  44. Lee SM, Tiwari D, Environ. Sci. Pollut. Res., 21, 407 (2014)
  45. Shih YJ, Shen YH, Appl. Clay Sci., 43, 282 (2009)
  46. Meloun M, Bordovska S, Galla L, J. Pharm. Biomed. Anal., 45, 552 (2007)
  47. Yang K, Xing BS, Chem. Rev., 110(10), 5989 (2010)
  48. Machida M, Aikawa M, Tatsumoto H, J. Hazard. Mater., 120(1-3), 271 (2005)
  49. Ofomaja AE, Unuabonah EI, Oladoja NA, Bioresour. Technol., 101(11), 3844 (2010)
  50. Gupta VK, Saini VK, Jain N, J. Colloid Interface Sci., 288(1), 55 (2005)
  51. Lee SM, Tiwari D, Choi KM, Yang JK, Chang YY, Lee HD, J. Chem. Eng. Data, 54(6), 1823 (2009)
  52. Mishra SP, Tiwari D, Prasad SK, Dubey RS, Mishra M, J. Radioanal. Nucl. Chem., 268, 191 (2006)
  53. Hayes KF, Papelis C, Leckie JO, J. Colloid Interface Sci., 125, 717 (1988)
  54. Arai Y, Elzinga EJ, Sparks DL, J. Colloid Interface Sci., 235(1), 80 (2001)
  55. Li Z, Burt T, Bowman RS, Environ. Sci. Technol., 34, 3756 (2000)
  56. Thanhmingliana, Tiwari D, Chem. Eng. J., 263, 364 (2015)
  57. Matheickal JT, Yu QM, Bioresour. Technol., 69(3), 223 (1999)
  58. Stylianou MA, Hadjiconstantinou MP, Inglezakis VJ, Moustakas KG, Loizidou MD, J. Hazard. Mater., 143(1-2), 575 (2007)
  59. Adak A, Bandyopadhyay M, Pal A, Dyes Pigment., 69, 245 (2006)
  60. Singh A, Kumar D, Gaur JP, Water Res., 46, 779 (2012)
  61. Roh H, Yu MR, Yakkala K, Koduru JR, Yang JK, Chang YY, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2014.11.034. (2014)