High-temperature water-gas shift reaction over nanostructured Cr-free Fe2O3.Al2O3.CuO.MO (M: Ba, Ca, Mg and Sr) catalysts for hydrogen production

Fereshteh Meshkani; Mehran Rezaei

Journal of Industrial and Engineering Chemistry, Vol.30, 353-358, October, 2015

DOI10.1016/j.jiec.2015.05.039 Export Citation

High-temperature water-gas shift reaction over nanostructured Cr-free Fe2O3.Al2O3.CuO.MO (M: Ba, Ca, Mg and Sr) catalysts for hydrogen production

Fereshteh Meshkani¹, and Mehran Rezaei^{1, 2, †}

¹Catalyst and Advanced Materials Research Laboratory, Chemical Engineering Department, Faculty of Engineering, University of Kashan, Kashan, Iran
²Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, Iran

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In this paper the promotion of Fe2O3-Al2O3-CuO chromium free catalyst with Ba, Ca, Mg and Sr for hydrogen production via high temperature water gas shift reaction was studied. The catalysts were synthesized by coprecipitation method and characterization of the prepared catalysts were performed using X-ray diffraction (XRD), N2 adsorption (BET), temperature-programmed reduction (TPR) and transmission electron microscopy (TEM) techniques. The results revealed that addition of alkaline earth promoters decreased the BET surface area while improved CO conversion. Among the promoted catalysts, 9 wt% Ba promoted Fe2O3-Al2O3-CuOcatalyst exhibited higher BET surface area and catalytic activity.

Keywords:Cr-free catalyst;Nanostructure;Alkaline earth metals;Iron based;Water-gas shift

[References]

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Harada Y, Sunada K, Mashiko Y, Kaminoyama M, Nishi K, Misumi R, J. Chem. Eng. Jpn., 42(1), 1 (2009)
Jeong DW, Potdar HS, Roh HS, Catal. Lett., 142(4), 439 (2012)
Roh HS, Jeong DW, Kim KS, Eum IH, Koo KY, Yoon WL, Catal. Lett., 141(1), 95 (2011)
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Hutchings GJ, Copperthwaitet RG, Gottschalk FM, Hunter R, Mellor J, Orchard SW, Sangiorgio T, J. Catal., 137, 408 (1992)
Jeong DW, Potdar HS, Shim JO, Jang WJ, Roh HS, Int. J. Hydrog. Energy, 38(11), 4502 (2013)
Subramanian V, Potdar HS, Jeong DW, Shim JO, Jang WJ, Roh HS, Jung UH, Yoon WL, Catal. Lett., 142(9), 1075 (2012)
Thouchprasitchai N, Luengnaruemitchai A, Pongstabodee S, J. Ind. Eng. Chem., 19(5), 1483 (2013)
Meshkani F, Rezaei M, J. Ind. Eng. Chem., 20(5), 3297 (2014)
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Kung MC, Kung HH, Surf. Sci., 104, 253 (1981)
Keiski RL, Salmi T, Appl. Catal., 87, 185 (1992)
Sun Y, Hla SS, Duffy GJ, Cousins AJ, French D, Morpeth LD, Edwards JH, Roberts DG, Int. J. Hydrog. Energy, 36(1), 79 (2011)
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Persons RM, Grave ED, Bakker PMA, Vandenerghe RE, Phys. Rev. B, 47, 5894 (1993)
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De Araujo GC, Do Carmo Rangel M, Catal. Today, 62, 201 (2002)
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Meshkani F, Rezaei M, Renew. Energy, 74, 588 (2015)
Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T, Pure Appl. Chem., 57, 603 (1985)
Kruk M, Jaroniec M, Mater. Chem. Mater., 13, 3169 (2001)
Zhang LZ, Wang XQ, Millet JMM, Matter PH, Ozkan US, Appl. Catal. A: Gen., 351(1), 1 (2008)
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Boreskov GK, Catal. Proc. Inst. Catal. Acad. USSR, 2, 981 (1972)
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Rhodes C, Williams BP, King F, Hutchings GH, Catal. Commun., 3, 381 (2002)
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Wan HJ, Wu BS, Zhang CH, Xiang HW, Li YW, J. Mol. Catal. A-Chem., 283(1-2), 33 (2008)
Tu YJ, Chen YW, Ind. Eng. Chem. Res., 37(7), 2618 (1998)

[Referenced By]

[1] Semelsberger TA, Borup RL, Int. J. Hydrog. Energy, 30(4), 425 (2005)

[2] Harada Y, Sunada K, Mashiko Y, Kaminoyama M, Nishi K, Misumi R, J. Chem. Eng. Jpn., 42(1), 1 (2009)

[3] Jeong DW, Potdar HS, Roh HS, Catal. Lett., 142(4), 439 (2012)

[4] Roh HS, Jeong DW, Kim KS, Eum IH, Koo KY, Yoon WL, Catal. Lett., 141(1), 95 (2011)

[5] Newsome DS, Catal. Rev.-Sci. Eng., 21, 275 (1980)

[6] Hutchings GJ, Copperthwaitet RG, Gottschalk FM, Hunter R, Mellor J, Orchard SW, Sangiorgio T, J. Catal., 137, 408 (1992)

[7] Jeong DW, Potdar HS, Shim JO, Jang WJ, Roh HS, Int. J. Hydrog. Energy, 38(11), 4502 (2013)

[8] Subramanian V, Potdar HS, Jeong DW, Shim JO, Jang WJ, Roh HS, Jung UH, Yoon WL, Catal. Lett., 142(9), 1075 (2012)

[9] Thouchprasitchai N, Luengnaruemitchai A, Pongstabodee S, J. Ind. Eng. Chem., 19(5), 1483 (2013)

[10] Meshkani F, Rezaei M, J. Ind. Eng. Chem., 20(5), 3297 (2014)

[11] Salehirad A, Khoshgouei MB, J. Ind. Eng. Chem., In press, doi:10.1016/j.jiec.2015.03.037.

[12] Galvita V, Sundmacher K, Chem. Eng. J., 134(1-3), 168 (2007)

[13] Domka F, Basinka A, Fieldcrow R, Surf. Technol., 18, 275 (1983)

[14] Kung MC, Kung HH, Surf. Sci., 104, 253 (1981)

[15] Keiski RL, Salmi T, Appl. Catal., 87, 185 (1992)

[16] Sun Y, Hla SS, Duffy GJ, Cousins AJ, French D, Morpeth LD, Edwards JH, Roberts DG, Int. J. Hydrog. Energy, 36(1), 79 (2011)

[17] Costa RCC, Lelis MFF, Oliveira LCA, Fabris JD, Ardisson JD, Rios RVA, Silva CN, Lago RM, Catal. Commun., 4, 525 (2003)

[18] Selim MS, Turky G, Shouman MA, El-Shobaky GA, Solid State Ion., 120(1-4), 173 (1999)

[19] Oliveira LCA, Fabris JD, Mussel WN, Hyperfine Interact., 3, 352 (1998)

[20] Lee MS, Lee JY, Lee DW, Moon DJ, Lee KY, Int. J. Hydrog. Energy, 37(15), 11218 (2012)

[21] Ramankutty CG, Sugunan S, Thomas B, J. Mol. Catal. A-Chem., 187(1), 105 (2002)

[22] Lahiri P, Sengupta K, J. Chem. Soc.-Faraday Trans., 91, 3489 (1995)

[23] Persons RM, Grave ED, Bakker PMA, Vandenerghe RE, Phys. Rev. B, 47, 5894 (1993)

[24] Rethwisch DG, Dumesic JA, Appl. Catal. A: Gen., 21, 97 (1986)

[25] Tsagaroyannis J, Haralambous KJ, Loizos Z, Mater. Lett., 28, 393 (1996)

[26] De Araujo GC, Do Carmo Rangel M, Catal. Today, 62, 201 (2002)

[27] Jeong DW, Jang WJ, Shim JO, Han WB, Jeon KW, Seo YC, Roh HS, Gu JH, Lim YT, J. Mater. Cycles Waste Manag., http://dx.doi.org/10.1007/s10163-014-0272-8. (2014)

[28] Meshkani F, Rezaei M, Renew. Energy, 74, 588 (2015)

[29] Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T, Pure Appl. Chem., 57, 603 (1985)

[30] Kruk M, Jaroniec M, Mater. Chem. Mater., 13, 3169 (2001)

[31] Zhang LZ, Wang XQ, Millet JMM, Matter PH, Ozkan US, Appl. Catal. A: Gen., 351(1), 1 (2008)

[32] Topssoe H, Boudart M, J. Catal., 31, 346 (1973)

[33] Boreskov GK, Catal. Proc. Inst. Catal. Acad. USSR, 2, 981 (1972)

[34] Lund CRF, Dumesic JA, J. Catal., 76, 93 (1982)

[35] Rhodes C, Williams BP, King F, Hutchings GH, Catal. Commun., 3, 381 (2002)

[36] Meshkani F, Rezaei M, Catal. Commun., 58, 26 (2015)

[37] Wan HJ, Wu BS, Zhang CH, Xiang HW, Li YW, J. Mol. Catal. A-Chem., 283(1-2), 33 (2008)

[38] Tu YJ, Chen YW, Ind. Eng. Chem. Res., 37(7), 2618 (1998)