화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.31, 343-351, November, 2015
DOI10.1016/j.jiec.2015.07.008  Export Citation
Enhanced capacitance of a nitrogen-containing carbon-based nanocomposite via noncovalent functionalization method
Nur Izzatie Hannah Razman, Salasiah Endud†, Zainab Ramli, Hendrik Oktendy Lintang1, Izan Izwan Misnon2, and Hanapi Mat3
  • Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia
  • 1Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia
  • 2Nanostructured Renewable Energy Materials Laboratory, Faculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, 26300 Kuantan, Pahang, Malaysia
  • 3Advanced Materials and Process Engineering Laboratory, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia
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Ordered carbon (OC) with large surface area was prepared via replication by using Santa Barbara Amorphous-15 as a template and sucrose as a carbon precursor. The prepared OC was then noncovalently functionalized with Basic Red 2 dye precursor (BR2) to obtain OC.BR2, a nitrogen-containing carbon-based nanocomposite with enhanced electrical properties. The functionalization was explained through adsorption isotherm, kinetic, and thermodynamic studies performed under variable conditions. The electrochemical performance test results demonstrated that the nanocomposite presents enhanced capacitance (48.4%) compared with the original OC, with maximum specific capacitance of 227 F g-1 at 0.5 A g-1 in 1 M KOH electrolyte.
Keywords:Basic dye;Capacitance;Functionalization;Ordered carbon;SBA-15
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