화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.31, 374-384, November, 2015
DOI10.1016/j.jiec.2015.07.012  Export Citation
Characterization of reactive amphiphilic montmorillonite nanogels and its application for removal of toxic cationic dye and heavy metals water pollutants
Ayman M. Atta1, 2, †, Hamad A. Al-Lohedan1, Z.A. ALOthman3, Ahmed A. Abdel-Khalek4, and Ahmed M. Tawfeek5, 4
  • 1Surfactants research chair, Chemistry Department, College of Science, King Saud University, Riyadh, Saudi Arabia
  • 2Petroleum Application Department, Egyptian Petroleum Research Institute, Cairo, Egypt
  • 3Chemistry Department, College of Science, King Saud University, Riyadh, Saudi Arabia
  • 4Chemistry Department, Faculty of Science, Beni Suef University, Beni Suef, Egypt
  • 5College of Science, King Saud University, Riyadh, Saudi Arabia
E-mail:
The present work aims to reduce the water surface tension using dispersed organophilic clay minerals to increase the adsorption water pollutants (organic and inorganic) into the clay galleries. Therefore, sodium montmorillonite (Na-MMT) was functionalized with amphphiles based on crosslinked nanogel polymers of N-isopropylacrylamide (NIPAm), sodium 2-acrylamido-2-methylpropane sulfonate (Na-AMPS), acrylamide (AAm) and acrylamidopropyl)trimethylammonium chloride solution (APTAC) using surfactant free technique. The chemical interactions between nanogels and Na-MMT and their chemical structure were confirmed by FTIR analysis. The intercalation and exfoliation of Na-MMT were confirmed by wide-angle X-ray diffraction. The morphology of Na-MMT nanogel composites was investigated by TEM analysis. The adsorption capacities of the prepared Na-MMT nanogels for methylene blue dye, cobalt and nickel cations from water were investigated. The data indicated that the Na-MMT nanogels reduced the surface tension of water and efficiently remove dye and metal ions from water.
Keywords:Sodium montmorillonite;Water purification;Nanogel;Methylene blue cationic dye;Heavy metal
  1. Jang SH, Jeong YG, Min BG, Lyoo WS, Lee SC, J. Hazard. Mater., 159(2-3), 294 (2008)
  2. Zhou L, Wang Y, Liu Z, Huang Q, J. Hazard. Mater., 161, 195 (2009)
  3. Zhou YT, Nie HL, Branford-White C, He ZY, Zhu LM, J. Colloid Interface Sci., 330(1), 29 (2009)
  4. Zhao L, Mitomo H, J. Appl. Polym. Sci., 110(3), 1388 (2008)
  5. Akkaya R, Ulusoy U, J. Hazard. Mater., 151(2-3), 380 (2008)
  6. Liu C, Bai R, Hong L, J. Colloid Interface Sci., 303(1), 99 (2006)
  7. Liu C, Bai R, Ly QS, Water Res., 42, 1511 (2008)
  8. Liu XW, Hu QY, Fang Z, Zhang XJ, Zhang BB, Langmuir, 25(1), 3 (2009)
  9. Pekel N, Sahiner N, Guven O, J. Appl. Polym. Sci., 81(10), 2324 (2001)
  10. Kasxgoz H, Durmusx A, Kasxgoz A, Polym. Adv. Technol., 19, 213 (2008)
  11. Sahiner N, Colloid Polym. Sci., 285, 283 (2006)
  12. Zhang QS, Zha LS, Ma JH, Liang BR, Macromol. Rapid Commun., 28(1), 116 (2007)
  13. Suprakas SR, Masami O, Prog. Polym. Sci, 28, 1539 (2003)
  14. Zhang Q, Li X, Zhao Y, Chen L, Appl. Clay Sci., 46, 346 (2009)
  15. Chen LF, Lang HW, Lu Y, Cui CH, Yu SH, Langmuir, 27(14), 8998 (2011)
  16. Xu MZ, Choi YS, Kim YK, Wang KH, Chung IJ, Polymer, 44(20), 6387 (2003)
  17. Bergaya F, Lagaly G, Appl. Clay Sci., 19, 1 (2001)
  18. Rao YQ, Pochan JM, Macromolecules, 40(2), 290 (2007)
  19. Kasgoz H, Durmus A, Kasgoz A, Polym. Adv. Technol., 19, 213 (2008)
  20. Atta AM, El-Mahdy GA, Al-Lohedan HA, Tawfeek AM, Sayed SR, Int. J. Electrochem. Sci., 10, 2377 (2015)
  21. Atta AM, El-Mahdy GA, Al-Lohedan HA, Tawfeek AM, Sayed SR, Digest J. Nanomater. Biostruct., 9, 531 (2014)
  22. Greesh N, Hartmann PC, Cloete V, Sanderson RD, J. Colloid Interface Sci., 319(1), 2 (2008)
  23. Liang L, Liu J, Gong XY, Langmuir, 16(25), 9895 (2000)
  24. Bignotti F, Sartore L, Penco M, Ramorino G, Peroni I, J. Appl. Polym. Sci., 93(4), 1964 (2004)
  25. Haraguchi K, Takehisa T, Fan S, Macromolecules, 35(27), 10162 (2002)
  26. Peng L, Kim SNH, Heo SB, Lee JH, Composites B, 39, 756 (2008)
  27. Kim JK, Ruhs PA, Fischer P, Hong JS, Rheol. Acta, 52(4), 327 (2013)
  28. Sahiner N, Godbey WT, McPherson GL, John VT, Colloid Polym. Sci., 284, 1121 (2006)
  29. Xi YF, Frost RL, He HP, J. Colloid Interface Sci., 305(1), 150 (2007)
  30. Ramoa SDAS, Barra GMO, Merlini C, Schreiner WH, Livi S, Soares BG, Appl. Clay Sci., 104, 160 (2015)
  31. Chen GM, Han BX, Yan HK, J. Colloid Interface Sci., 201(2), 158 (1998)
  32. Sahine N, Demir S, Yildiz S, Colloids Surf. A: Physicochem. Eng. Asp., 449, 87 (2014)
  33. Guillermic RM, Jalmes AS, Soft Matter., 9, 1344 (2013)
  34. Kim KS, Vincent B, Cosgrove T, J. Ind. Eng. Chem., 12(1), 91 (2006)
  35. Xionga W, Gaob X, Zhaoa Y, Xub H, Yang X, Colloids Surf. B: Biointerfaces, 84, 103 (2011)
  36. Xi Y, Martens W, He H, Frost RL, J. Therm. Anal. Calorim., 81, 91 (2005)
  37. Zheng H, Zhang Y, Peng ZL, Zhang YX, J. Appl. Polym. Sci., 92(1), 638 (2004)
  38. Choi YS, Ham HT, Chung IJ, Polymer, 44(26), 8147 (2003)
  39. Theng BKG, The Chemistry of Clay-Organic Reactions, Adam Hilger, London, 1974.
  40. Beall GW, Goss M, Appl. Clay Sci., 27, 179 (2004)
  41. Park JH, Jana SC, Macromolecules, 36(8), 2758 (2003)
  42. Morgan AB, Gilman JW, J. Appl. Polym. Sci., 87(8), 1329 (2003)
  43. Atta AM, Polym. Int., 63, 607 (2014)
  44. Dyab AKF, Atta AM, RSC Adv., 3(2013), 25662 (2013)
  45. Atta AM, Dyab AKF, Allohedan HA, Polym. Adv. Technol., 24, 986 (2013)
  46. Rosen MJ, Surfactants and Interfacial Phenomena, John Wiley, New York, NY, 1985p. 15.
  47. Ryou MG, Choudhury GR, Li W, Winters A, Yuan F, Liu R, Yang SH, Neuroscience, 301, 193 (2015)
  48. ROA L, Bazo AP, Salvadori DMF, Rech CM, Oliveira DP, Umbuzeiro GA, Mutat. Res. Genet. Toxicol. Environ. Mutagen., 626, 53 (2007)
  49. Rytwo G, Tropp D, Serban C, Appl. Clay Sci., 20, 273 (2002)
  50. Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
  51. Freundlich HMF, Z. Phys. Chem., 57, 385 (1906)
  52. Webi TW, Chakravort RK, AIChE J., 20, 228 (1974)
  53. McKay G, J. Chem. Technol. Biotechnol., 32, 759 (1982)
  54. Low KS, Lee CK, Bioresour. Technol., 61(2), 121 (1997)
  55. Wang SF, Shen L, Tong YJ, Chen L, Phang IY, Lim PQ, Li TX, Polym. Degrad. Stabil., 90, 123 (2005)
  56. Sondi I, Milat O, Pravdic V, J. Colloid Interface Sci., 189(1), 66 (1997)
  57. Kolodynska D, Chem. Eng. J., 165(3), 835 (2010)
  58. Gao BJ, Gao YC, Li YB, Chem. Eng. J., 158(3), 542 (2010)
  59. Setshedi KZ, Bhaumik M, Songwane S, Onyango MS, Maity A, Chem. Eng. J., 222, 186 (2013)
  60. Atta AM, Ismail HS, Elsaaed AM, J. Appl. Polym. Sci., 123(4), 2500 (2012)