화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.34, 300-312, February, 2016
DOI10.1016/j.jiec.2015.11.024  Export Citation
Gas phase selective conversion of glycerol to acrolein over supported silicotungstic acid catalyst
Amin Talebian-Kiakalaieh, Nor Aishah Saidina Amin†, and Zaki Yamani Zakaria
  • Chemical Reaction Engineering Group (CREG), Faculty of Chemical Engineering, Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor, Malaysia
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Gas phase dehydration of glycerol to acrolein over a series of supported HSiW on ZrO2 and nano-sized g-Al2O3 catalyst has been investigated. The characterization results revealed that impregnation of g-Al2O3 nanoparticles increased the specific surface area, pore diameter, and thermal stability of the supported catalysts. The highest acrolein selectivity of 88.5% at 97.0% glycerol conversion was achieved over 0.5 g 30HZ-20A catalyst in 3 h at glycerol feed concentration of 10 wt%, temperature = 300 ?C and TOF = 136 h-1. The coke deposition has no significant effect on the activity of 30HZ-20A catalyst. Indeed, the catalyst was stable even after 40 h.
Keywords:Glycerol;Acrolein;Dehydration;Supported silicotungstic acid;Keggin anion
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