화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.35, 146-152, March, 2016
DOI10.1016/j.jiec.2015.12.024  Export Citation
Electrospinning composite nanofibers of polyacrylonitrile/synthetic Na-montmorillonite
Sliman Almuhamed, Magali Bonne1, Nabyl Khenoussi, Jocelyne Brendle1, †, Laurence Schacher, Benedicte Lebeau1, and Dominique C. Adolphe
  • Laboratoire de Physique et Mecanique Textiles, EA 4365 UHA, Universite de Mulhouse, Universite de Strasbourg, ENSISA, 11 rue Alfred Werner, F-68093 Mulhouse Cedex, France
  • 1Pole Materiaux a Porosite Controlee (MPC), Institut de Science des Materiaux de Mulhouse (IS2M), UMR CNRS 7361, Universite de Haute Alsace, Universite de Strasbourg, 3b rue A. Werner, F-68093 Mulhouse Cedex, France
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Nonwovens of polymer/clay composite nanofibers (namely, polyacrylonitrile/Na-montmorillonite, PAN/Na-MMT) are produced by electrospinning a solution of PAN in dimethylformamide containing synthetic Na-MMT. The influence of both Na-MMT amount and applied voltage on the properties of electrospun composite nonwovens was studied. Scanning electron microscopy (SEM), X-ray diffraction (XRD) and thermogravimetric analysis (TGA-DTA) were used to evaluate the morphology, structure and thermal properties of composite nanofibers. SEM observations revealed that increasing the amount of Na-MMT in the solution or the applied voltage increases the average diameter of electrospun composite nanofibers. The prepared composite showed a higher thermal stability that the pristine PAN nanofibers. It was proven that the ion exchange properties of Na-MMT were maintained in the obtained composite.
Keywords:Electrospinning;Polyacrylonitrile;Montmorillonite;Composite nanofibers;Ion-substitution
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